Pressure-resistant impact-resistant PE pipe material and preparation method thereof
A technology of impact resistance and pipe materials, which is applied in the field of pressure-resistant and impact-resistant PE pipes and their preparation, and can solve the problems of poor compressive strength of PE pipes
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[0023] According to the present invention, the preparation method of the described coupled inorganic silica comprises:
[0024] Mix and grind sheet-like potassium aluminum silicate, dispersant, silane coupling agent and deionized water to obtain coupled inorganic silica. The mass percentage of the sheet potassium aluminum silicate, dispersant, silane coupling agent and deionized water is preferably 80:(1.5-2):(2.5-2):16. The diameter-thickness ratio of the sheet potassium aluminum silicate is (50-100); the specific surface area is (BET 10-50), and the oil absorption value is (DOP≤50). The present invention should strictly control the thickness of the sheet potassium aluminum silicate. When the diameter-thickness ratio, specific surface area and oil absorption value are too high or too low, the self-dispersion effect of inorganic nano-sheet silica and the dispersion effect in polyethylene matrix will be reduced.
[0025] According to the present invention, the grinding can be ...
Embodiment 1
[0033] Sheet-shaped potassium aluminum silicate (diameter-thickness ratio: 80, specific surface area: 20, oil absorption value: 30) after dedusting and impurity removal, take 80 parts of sheet-shaped potassium aluminum silicate, 2 parts of dispersant BYK163, silane coupling agent KH560 2 parts, 16 parts of deionized water, high-speed wet grinding for 10 hours, grinding until the particle size of the inorganic powder reaches 500nm, and spray drying to obtain the coupled inorganic silica (LS-0.5).
[0034] Take 80 parts of high-density polyethylene, 2.5 parts of heat stabilizer 1010, 5 parts of toughening agent POE, 0.5 parts of dispersant BYK163, 2 parts of paraffin, and 10 parts of coupled inorganic silica (LS-0.5). The twin-screw extruder melts and blends, extrudes, granulates, dries at 120°C, and then extrudes through a 175°C single-screw extruder to obtain PE pipes.
[0035] The pressure resistance and impact resistance mechanical properties of the prepared PE pipe were tes...
Embodiment 2
[0037] Sheet-shaped potassium aluminum silicate (diameter-thickness ratio of 80, specific surface area of 20, oil absorption value of 30) after dedusting and impurity removal, take 80 parts of sheet-shaped potassium aluminum silicate, 2 parts of dispersant BYK163, silane coupling agent KH560 2 parts, 16 parts of deionized water, high-speed wet grinding for 6 hours, grinding until the particle size of the inorganic powder reaches 2 μm, and spray drying to obtain the coupled inorganic silica (LS-2).
[0038] Take 80 parts of high-density polyethylene, 2.5 parts of heat stabilizer 1010, 5 parts of toughening agent POE, 0.5 parts of dispersant BYK163, 2 parts of paraffin, and 10 parts of coupled inorganic silica (LS-2). The twin-screw extruder melts and blends, extrudes, granulates, dries at 120°C, and then extrudes through a 175°C single-screw extruder to obtain PE pipes.
[0039] The pressure resistance and impact resistance mechanical properties of the prepared PE pipe were t...
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