An environment-friendly brake pad adopting copper-free microcrystalline friction materials is made from components including acrylic pulp, mullite ceramic fibers, brucite fibers, nano tin powder, zinc sulfide, brown aluminum oxide, antimony sulfide, cellulosic fibers, iron black, calcium carbonate whiskers, calcium sulfate whiskers, potassium titanate, crystalline flake graphite, calcined petroleum coke, flake aluminum powder, nitrile rubber powder, phenolic resin, nanometer manganese hydroxide and molybdenum disulfide. Through reasonable collocation of the multiple components, advantages of the various components given full play to the friction materials can be guaranteed. By the reasonable collocation of the new fiber materials, the defect of respect performance can be made up, and high performance can be produced due to mutual influenced action. The environment-friendly brake pad is good in resistance to high-temperature recession, long in service life, good in wear-resisting performance, stable in friction coefficient and environment friendly.