Environment-friendly precoated sand for high-strength castings and preparation method thereof

A coated sand, high-strength technology, applied in the direction of casting molding equipment, casting molds, manufacturing tools, etc., can solve the problems of large surface roughness, poor heat resistance, and easy collapse of the mold, and achieve a complete and compact shape, smooth surface, The effect of improving toughness

Inactive Publication Date: 2019-06-21
广西兰科资源再生利用有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Chinese patent CN108380814A discloses a regenerated coated sand for casting iron mold parts, including the following components in parts by weight: 100 parts of coated sand waste sand; phenolic resin, the amount of phenolic resin added is the amount of coated sand waste sand 1.0-1.4%; liquid silane, the amount of liquid silane added is 0.03-0.08% of the amount of coated sand waste sand; urotropine aqueous solution, the amount of urotropine added is 10-12% of the amount of phenolic resin , wherein, the weight ratio of urotropine and water is 1:4; calcium stearate, the addition amount of calcium stearate is 2-5% of the amount of phenolic resin, but its heat resistance is poor, easy to collapse , and the surface roughness of the mold made by it is relatively large, and it is easy to stick sand on the casting

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] (1) Prepare modified phenolic resin, which is prepared by polycondensation reaction. The specific method is: put molten phenol into a three-necked flask at low temperature, then add an appropriate amount of formaldehyde solution and modifier cardanol, and adjust the pH to 1.8 with hydrochloric acid Between -2, stop heating when the temperature rises slowly to 80°C, reflux reaction at this temperature for 60 minutes, then add an appropriate amount of hydrochloric acid dropwise, continue the reflux reaction, then vacuum dehydrate, add an appropriate amount of coupling agent, stir evenly, and then discharge to obtain Modified phenolic resin, spare.

[0033] (2) Weigh 500g of 50-mesh silica sand and 500g of 50-mesh pearl sand, mix the silica sand, pearl sand and refractory particles of ferric oxide evenly, preheat to 130°C, and quickly pour it into the sand mixer;

[0034] (3) Add 40g of modified phenolic resin and mix sand for 1min;

[0035] (4) Add 0.5g of calcium steara...

Embodiment 2

[0041] (1) To prepare modified phenolic resin, put molten phenol into a three-necked flask at low temperature, then add formaldehyde solution and cardanol, adjust the pH between 1.8-2 with hydrochloric acid, stop heating when the temperature rises slowly to 100°C, and Reflux at this temperature for 40 minutes, then add an appropriate amount of hydrochloric acid dropwise, continue the reflux reaction, vacuum dehydrate, add an appropriate amount of coupling agent, stir evenly, and then discharge to obtain a modified phenolic resin, which is ready for use.

[0042] (2) Weigh 500g of 140-mesh silica sand and 500g of 100-mesh pearl sand, mix the silica sand, pearl sand and refractory particles of iron tetroxide evenly, preheat to 150°C, and quickly pour it into the sand mixer;

[0043] (3) Add 80g of modified phenolic resin and mix sand for 1min;

[0044] (4) Add 5g of calcium stearate and mix with sand for 0.5min;

[0045] (5) When the sand temperature drops to 110°C, add urotrop...

Embodiment 3

[0050] (1) To prepare modified phenolic resin, put molten phenol into a three-necked flask at low temperature, then add formaldehyde aqueous solution and cardanol, adjust the pH between 1.8-2 with hydrochloric acid, stop heating when the temperature rises slowly to 90°C, and Reflux at this temperature for 50 minutes, then add an appropriate amount of hydrochloric acid dropwise, continue the reflux reaction, vacuum dehydrate, add an appropriate amount of coupling agent, stir evenly, and then discharge to obtain a modified phenolic resin, which is ready for use.

[0051] (2) Weigh 500g of 70-mesh silica sand and 500g of 70-mesh pearl sand, mix the silica sand, pearl sand and refractory particles of ferric oxide evenly, preheat to 140°C, and quickly pour it into the sand mixer;

[0052] (3) Add 60g of modified phenolic resin and mix sand for 1min;

[0053] (4) Add 4g of calcium stearate and mix with sand for 0.5min;

[0054] (5) When the sand temperature drops to 105°C, add urot...

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Abstract

The invention relates to environment-friendly precoated sand for high-strength castings and a preparation method thereof. The precoated sand comprises the following raw materials of, in parts by weight, 100 parts of raw sand, 4-8 parts of a binder, 1-2 parts of a curing agent, 0.1-1 part of a lubricant, and 0.1-0.5 part of a refractory particle, wherein the raw sand is a mixture of silica sand andceramic foundry sand, and the binder is modified phenolic resin. According to the method, the precoated sand raw sand are designed, the phenolic resin is modified, the refractory particles are added,the modified phenolic resin and the mixture of the silica sand and the ceramic foundry sand are fully mixed, so that the effect of the binder is effectively exerted; the ferroferric oxide refractoryparticles are mixed into the mixture of the silica sand and the ceramic foundry sand, the problem that the casting size is changed due to expansion in the casting process is inhibited, the precoated sand is fully ensured to be used at a higher temperature, the precoated sand has higher strength and better liquidity, the shape of the sand core can be ensure to be complete and compact, so that the surface of an inner cavity of the casting is smooth and free of burrs.

Description

technical field [0001] The invention relates to the field of coated sand materials, in particular to an environment-friendly coated sand for high-strength castings and a preparation method thereof. Background technique [0002] Resin-coated sand for foundry (referred to as coated sand) refers to the molding sand or core sand whose surface has been covered with a layer of solid resin film before molding and core making. Coated sand is generally made of foundry raw sand, thermoplastic phenolic resin, latent curing agent such as urotropine, and lubricant such as calcium stearate through a certain coating process. When the coated sand is heated, the resin coated on the surface of the sand grains melts, and under the action of the curing agent, the molten resin rapidly transforms from a linear structure into an infusible body structure, so that the coated sand is solidified and formed. [0003] Commonly used lamination processes include cold and thermal processes. The cold me...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22C1/22B22C1/02
Inventor 罗桂猛刘国媚
Owner 广西兰科资源再生利用有限公司
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