A kind of composition, preparation method and application in killing cell line
A composition, solution technology
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Embodiment 1
[0040] This example is one of the examples for the preparation of BP-PEG-T7 / 5-ALA NSs.
[0041] Step 1. Preparation of BP NSs: The black scales were prepared by a liquid phase exfoliation method; wherein, the liquid phase exfoliation method was as follows: the black scales were dissolved in NMP, ultrasonically vibrated intermittently for 6 h at an intensity of 200 W, and then continued to be ultrasonicated at 0°C for 8 h. After ultrasonication, the unstripped black scale crystals were removed, the supernatant was centrifuged, and the precipitate was collected as BP NSs. In this embodiment, the method of ultrasonic intermittent vibration is: after each interval of 5s, ultrasonication is applied for 1s; the method of removing the black scale crystals that have not been peeled off is: centrifuging at a speed of 6500rpm for 20min; The centrifugation time of the supernatant was 20 min.
[0042] Step 2. Preparation of T7-PEG-NH 2 : Mal-PEG-NH 2 The solution was mixed with T7-Cys ...
Embodiment 2
[0048] This example is one of the examples for the preparation of BP-PEG-T7 / 5-ALA NSs.
[0049] Step 1. Preparation of BP NSs: black scales were prepared by liquid phase exfoliation method; wherein, the liquid phase exfoliation method was as follows: black scales were dissolved in NMP, ultrasonically vibrated intermittently at 300W intensity for 5h, and then ultrasonicated at 0°C for 12h. After ultrasonication, the unstripped black scale crystals were removed, the supernatant was centrifuged, and the precipitate was collected as BP NSs. In this embodiment, the method of ultrasonic intermittent vibration is: after every interval of 2s, ultrasonication is applied for 2s; the method of removing the black scale crystals that have not been peeled off is: centrifuging at a speed of 6000rpm for 15min; The centrifugation time of the supernatant was 15 min.
[0050] Step 2. Preparation of T7-PEG-NH 2 : Mal-PEG-NH 2 The solution was mixed with T7-Cys solution, stirred, and dried to o...
Embodiment 3
[0056] This example is one of the examples for the preparation of BP-PEG-T7 / 5-ALA NSs.
[0057] Step 1. Preparation of BP NSs: Black scales were prepared by liquid phase exfoliation method; wherein, the liquid phase exfoliation method was as follows: black scales were dissolved in NMP, ultrasonically vibrated at 260W intensity for 8h intermittently, and then continued to ultrasonically sonicate at 0°C for 6h. After ultrasonication, the unstripped black scale crystals were removed, the supernatant was centrifuged, and the precipitate was collected as BP NSs. In this embodiment, the method of ultrasonic intermittent vibration is: after every interval of 4s, ultrasonication is applied for 4s; the method of removing the black scale crystals that have not been peeled off is: centrifuging at 8000rpm for 30min; The centrifugation time of the supernatant was 30 min.
[0058] Step 2. Preparation of T7-PEG-NH 2 : Mal-PEG-NH 2 The solution was mixed with T7-Cys solution, stirred, and ...
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