A kind of starch adhesive and preparation method thereof

A starch adhesive, starch technology, applied in the direction of starch-derived adhesives, adhesive additives, adhesive types, etc., can solve the problems of free formaldehyde release of wood-based panels, poor water-resistant bonding performance, etc., to meet the requirements of water-resistant Compatible with process requirements, good water resistance and bonding performance, and simple synthesis process

Active Publication Date: 2021-02-02
BEIJING FORESTRY UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The use of biomass adhesives to prepare wood-based panels can solve the problem of free formaldehyde release from wood-based panels, which is an important way to solve the problem. However, most biomass adhesives have poor water resistance and bonding performance, which limits their industrial application.

Method used

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  • A kind of starch adhesive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] This embodiment provides a method for preparing a soybean meal protein adhesive, and the adhesive is prepared according to the following weight ratio:

[0036] Modified starch 38 kg

[0037] Surface Modified Nanocellulose 1.0kg

[0038] Polyacrylamide 0.1kg

[0039] Self-made multifunctional epoxy compound 5.0kg

[0040] Sodium hydroxide solution 0.3kg

[0041] This embodiment also provides the preparation method of the above-mentioned adhesive, and the specific preparation steps are as follows:

[0042] (1) Weigh the components according to the weight ratio, add the surface-modified nanocellulose into the dispersion medium water, ultrasonicate for 15 minutes, and then add half the weight of modified starch, use a high-pressure homogenizer, under 30MPa pressure and 0.5MPa Under the action of emulsifying force, homogeneously emulsify for 20 minutes;

[0043] (2) Add the remaining modified starch to the mixture obtained in step (1), mix well, add crosslinking agent a...

Embodiment 2

[0045] This embodiment provides a method for preparing a soybean meal protein adhesive, and the adhesive is prepared according to the following weight ratio:

[0046]Modified starch 42kg

[0047] Surface Modified Nanocellulose 1.5 kg

[0048] Polyacrylamide 0.3kg

[0049] Self-made multifunctional epoxy compound 8.0kg

[0050] Sodium hydroxide solution 0.6kg

[0051] The preparation method of the adhesive described in this embodiment is the same as that in Example 1.

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Abstract

The invention discloses a starch adhesive and a preparation method thereof, comprising the following components in parts by weight: 38-42 parts by weight of a main agent, 60 parts by weight of dispersion medium water, 1-1.5 parts by weight of a reinforcing agent, and 0.1 parts by weight of a viscosity modifier. -0.3 parts by weight, 5-8 parts by weight of cross-linking agent, 0.3-0.6 parts by weight of catalyst; the starch adhesive is prepared by the following method: firstly weigh each component according to the weight ratio, add the reinforcing agent into the dispersion medium water, Ultrasonic for 15 minutes, then add half the weight of the main agent, use a high-pressure homogenizer, under the action of 30MPa pressure and 0.5MPa emulsifying force, homogenize and emulsify for 20 minutes; then add the remaining main agent to the obtained mixture. Then add the crosslinking agent and sodium hydroxide, react at 80°C for 30 minutes, and cool down to 30°C for discharging; the adhesive of the present invention is easy to form a crosslinking structure, the crosslinking density is large, the reaction temperature is low, and the performance of the prepared adhesive is stable and weak. The interface layer is obviously reduced, the cost is reduced, the dry / wet strength is good, and the product quality is steadily improved.

Description

technical field [0001] The invention relates to the field of plywood preparation, in particular to a starch adhesive and a preparation method thereof. Background technique [0002] my country's precious wood resources are relatively scarce, and artificial forest resources are abundant. Using artificial forest fast-growing wood to prepare wood-based panels through adhesives is the main raw material for furniture floors and interior decoration in the living environment. In 2017, the total output of my country's wood-based panels was 295 million cubic meters Rice, accounting for about 50% of the world's total output, of which more than 60% are plywood products. Based on the average production of 9 cubic meters of wood-based panels per ton of adhesive, the consumption of adhesives for plywood in my country in 2017 was about 18 million tons (solid content 50%), of which urea-formaldehyde resin and its modified products accounted for the total output of adhesives More than 90% of t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J103/04C09J11/08
CPCC08L2205/035C09J11/08C09J103/04C08L33/26C08L1/02
Inventor 高强张婕妤李玥李建章周文瑞龚珊珊
Owner BEIJING FORESTRY UNIVERSITY
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