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Segmented ore-forming process of magnesium sulfate subtype salt lake brine through natural evaporation of salt pan

A magnesium sulfate subtype, natural evaporation technology, applied in the direction of alkali metal sulfite/sulfate purification, alkali metal chloride, inorganic fertilizers, etc. Cost increase and other issues, to achieve the effect of simplifying the flotation process, improving the ratio of sulfur and potassium, and reducing the loss of brine

Active Publication Date: 2019-09-27
青海中信国安锂业发展有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This process can meet the requirements of magnesium sulfate subtype brine to produce potassium sulfate, but there is a problem of low efficiency
Due to the setting up of the Epsilon Salt Field in the drying and evaporation process of the salt field, the precipitation of the Epoxy Salt resulted in a decrease in the sulfate content in the brine, and the insufficient sulfur-potassium ratio in the sun-dried potash mixed salt ore had a great impact on the production of langbeinite ; In order to replenish the sulfate radical, the epsom salt that precipitates has to be added into the soft potash conversion section in the conversion process, resulting in increased production costs, which is economically unreasonable

Method used

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  • Segmented ore-forming process of magnesium sulfate subtype salt lake brine through natural evaporation of salt pan
  • Segmented ore-forming process of magnesium sulfate subtype salt lake brine through natural evaporation of salt pan
  • Segmented ore-forming process of magnesium sulfate subtype salt lake brine through natural evaporation of salt pan

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The raw material is taken from the underground brine brine pumping station in the Xitai Jinaier Salt Lake in Qaidam Basin, Qinghai in January 2018. It has the chemical composition shown in Table 1. From the composition analysis, the hydrochemical type of the brine system belongs to the magnesium sulfate subtype. Potassium ions composed of the brine Jenec J 2K =8.0, Mg Ion Jenec J Mg =68.81, sulfate ion Yenecke J SO4 =23.19, its brine composition point is located at 25℃K + 、Na + , Mg 2+ ∥Cl - , SO 4 2- -H 2 The Epsom salt region in the metastable phase diagram of the O quinary water-salt system.

[0035] Table 1: Chemical composition of brine from wells in Xitaijinel Salt Lake in January 2018

[0036]

[0037] (1) Take 213.86 liters of brine from a magnesium sulfate subtype salt lake well, and use a plastic basin for natural evaporation to precipitate sodium chloride. + ] to 24.243g·L -1 , [Mg 2+ ] is 67.825g·L -1 , [Cl - ] is 194.580g·L -1 , [SO 4 2-...

Embodiment 2

[0044] The raw material is taken from the brine pumping station in April 2018 in Xitaijiner Salt Lake, Qaidam Basin, Qinghai. It has the chemical composition shown in Table 3. From the composition analysis, the hydrochemical type of the brine system belongs to the magnesium sulfate subtype. Potassium ions composed of the brine Jenec J 2K =7.07, magnesium ion Jenecke J Mg =74.12, sulfate ion Yenecke J SO4 =18.82, its brine composition point is located at 25℃K + 、Na + , Mg 2+ ∥Cl - , SO 4 2- -H 2The Epsom salt region in the metastable phase diagram of the O quinary water-salt system. Compared with the method provided in Example 1, the main difference between this example is that the selected raw materials have different chemical compositions, and the adaptability of the method under different raw materials is mainly investigated.

[0045] Table 3: Chemical composition of brine from wells in Xitai Jinel Salt Lake in April 2018

[0046]

[0047] (1) Take 46.2 kg of br...

Embodiment 3

[0054] The raw material is taken from the underground brine brine pumping station in Xitaijiner Salt Lake, Qaidam Basin, Qinghai in October 2018. It has the chemical composition shown in Table 5. From the composition analysis, the water chemical type of the brine system belongs to the subtype of magnesium sulfate . Potassium ions composed of the brine Jenec J 2K =7.68, magnesium ion Jenecke J Mg =76.26, sulfate ion Yenecke J SO4 =16.07, its brine composition point is located at 25℃K + 、Na + , Mg 2+ ∥Cl - , SO 4 2- -H 2 The Epsom salt region in the metastable phase diagram of the O quinary water-salt system. Compared with the method provided in Example 2, the main difference between this example is that the selected raw materials have different chemical compositions, and the adaptability of the method under different raw materials is mainly investigated.

[0055] Table 5: Chemical composition of brine from wells in Xitai Jinel Salt Lake in October 2018

[0056]

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Abstract

The invention relates to a segmented ore-forming process of magnesium sulfate subtype salt lake brine through the natural evaporation of a salt pan. The process comprises the following steps: (1) introducing magnesium sulfate subtype brine exploited from a salt lake well into a sodium salt pond with a pump, naturally evaporating for dissolving out sodium chloride, introducing into a regulating tank when epsomite is close to saturation, and introducing into a potassium-mixed salt pond when a brine point reaches a condition that the epsomite is close to saturation and about to dissolve out; (2) continuing to naturally evaporate the brine obtained in step (1) in the potassium-mixed salt pond, introducing the brine into a carnallite pond when carnallite is close to saturation and about to dissolve out, dissolving out a potassium-mixed salt mine, and enabling the potassium-mixed salt mine to enter a potassium magnesium sulphate fertilizer workshop to produce a schoenite product; (3) continuing to naturally evaporate the brine obtained in step (2) in the carnallite pond, introducing into an old brine storage tank when the brine reaches an old brine point, dissolving out a carnallite mine, and enabling the carnallite mine to enter a potassium chloride workshop to produce a potassium chloride product. The invention has the advantages that the process is simple, the production cost is low, and sulfur-potassium ratio of the potassium-mixed salt mine is high.

Description

technical field [0001] The invention relates to the field of inorganic salt chemical industry, in particular to a staged mineralization process of natural evaporation of magnesium sulfate subtype salt lake brine and salt fields. Background technique [0002] According to the chemical composition of salt lake brine, salt lakes can be divided into three types: carbonate, sulfate and chloride. The most common distribution in China is the sulfate-type salt lake, and the number is also the largest. China's sulfate-type salt lake resources are mainly concentrated in Qinghai and Xinjiang, among which sulfate-type magnesium subtype salt lake resources are the main resources. Although the number is small, the area of ​​salt lakes accounts for 1 / 2 of the total area, and the resource reserves are large. An important brine raw material for the production of potassium sulfate. [0003] The technical process of producing potassium sulfate by using sulfate-type salt lake brine is as foll...

Claims

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Application Information

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IPC IPC(8): C05D1/02C01D3/06C01D5/16
CPCC01D3/06C01D5/16C01P2006/80C05D1/02
Inventor 李陇岗余明祥秦佳政权彩兄
Owner 青海中信国安锂业发展有限公司
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