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Ammonia electrolysis hydrogen production device

A hydrogen production device and ammonia gas technology, applied in the electrolysis process, electrolysis components, electrodes, etc., can solve the problems of resource waste and energy consumption, and achieve the effect of reducing waste and reducing heat energy loss

Active Publication Date: 2019-10-01
福大紫金氢能科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Therefore, the technical problem to be solved by the present invention is to overcome the waste of resources caused by the need for additional energy consumption when using solid electrolytes to electrolyze ammonia in the prior art, thereby providing an ammonia electrolysis ammonia production system

Method used

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  • Ammonia electrolysis hydrogen production device
  • Ammonia electrolysis hydrogen production device
  • Ammonia electrolysis hydrogen production device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] In this embodiment, the present invention provides an ammonia electrolysis hydrogen production device, which includes a hydrogen production component 1, such as figure 2 As shown, specifically:

[0057] A casing 102, along the flow direction of ammonia gas, the casing includes an ammonia distribution chamber 103, a combustion chamber 104 and a reaction chamber 105 in sequence;

[0058] 5 groups of hydrogen production units 101 arranged side by side in the reaction chamber, such as image 3 As shown, the hydrogen production unit 101 includes a battery body with an open end, the battery body has an inner cavity 1015 suitable for inserting an ammonia gas pipe 1011 into the battery body from the open end, and the ammonia gas pipe 1011 penetrates The combustion chamber 104 and the end of the ammonia supply pipe 1011 far away from the inner cavity 1015 communicates with the ammonia distribution chamber 103, so that the ammonia in the ammonia distribution chamber 103 enters the cor...

Embodiment 2

[0073] This embodiment provides a working method of the ammonia electrolysis hydrogen production device provided in Embodiment 1.

[0074] The ammonia gas from the ammonia storage tank 2 enters the ammonia distribution chamber 103 through the ammonia gas inlet 110 along the ammonia gas inlet 110, is distributed into the ammonia supply pipe 1011 of each hydrogen production unit 101, and then enters the inner cavity 1015 of each hydrogen production unit 101. Contact with the anode layer 1013; water flows out of the water tank 4, as the water inlet channel 10 passes through the second heat exchanger 7 to evaporate into water vapor, from the water vapor inlet 114 through the water vapor channel 107 from the water vapor outlet 116 Enter the reaction chamber 105 and contact the cathode layer 1014.

[0075] The following reactions occur in the reaction chamber 105:

[0076] Anode: 2NH 3 +3O 2- =N 2 +3H 2 O+6e -

[0077] Cathode: 3H 2 O+6e - =3H 2 +3O 2- .

[0078] Nitrogen and remaining ammo...

Embodiment 3

[0082] Compared with the embodiment 1, the other structure of this embodiment is completely the same. The only difference is that the ammonia supply pipe 1011 of the hydrogen production unit 101 is filled with an ammonia decomposition catalyst layer 1016, such as Figure 4 As shown, the material of the ammonia decomposition catalyst layer 1016 is Ru simple substance, and the carrier is alumina.

[0083] When this embodiment is working, the ammonia gas enters the ammonia supply pipe 1011 to contact the ammonia decomposition catalyst layer 1016, and part of the ammonia gas is decomposed into hydrogen and nitrogen in advance. After entering the cavity 1015, the hydrogen contacts the anode layer 1013 and contacts the cathode layer. The water vapor ion exchange of 1014, the anode layer 1013 generates water vapor, and the cathode layer 1014 generates hydrogen. The remaining hydrogen in the inner cavity 1015 enters the combustion chamber 104 together with the remaining ammonia, the water...

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Abstract

The invention discloses an ammonia electrolysis hydrogen production device, the ammonia electrolysis hydrogen production device comprises a shell and a plurality of hydrogen production units, whereinthe shell is internally divided into an ammonia distribution chamber, a combustion chamber and a reaction chamber, and the plurality of hydrogen production units are arranged in parallel in the reaction chamber. An air channel is arranged between the reaction chamber and the combustion chamber, and water vapor channels are arranged at the bottom and the side wall of the reaction chamber, so that introduced water vapor and air exchange heat with the reaction chamber and the combustion chamber through the long channels, excess heat in the reaction chamber and the combustion chamber is used for preheating the air, and energy waste is reduced. At the same time, residual nitrogen generated in the inner cavities of the hydrogen production units is mixed with the preheated air in the combustion chamber, by afterburning at a burner in the combustion chamber, heat is discharged, residual ammonia in tail gas is removed, and at the same time, ammonia gas in an ammonia supply pipe and an ammonia gas preparation chamber and the air in air inlet channel can be preheated to further reduce heat energy loss.

Description

Technical field [0001] The invention relates to the technical field of hydrogen preparation, in particular to an ammonia electrolysis hydrogen production device. Background technique [0002] Energy is the fundamental guarantee for the development of modern society and the cornerstone of human civilization. However, the existing fossil fuel-based energy system has not only brought us serious environmental pollution problems, but also fossil fuels are being exploited in large quantities and are facing exhaustion. Finding new energy sources that can replace fossil fuels is an important goal of energy development in all countries today. Hydrogen has attracted much attention as a clean energy carrier. The development and utilization of hydrogen energy must solve the source of hydrogen. The development of safe, efficient and economical hydrogen supply and hydrogen storage technologies is the basis for the realization of hydrogen energy utilization. There are two main sources of hydr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25B1/02C25B9/06C25B9/18C25B11/04C25B9/17
CPCC25B1/02C25B15/00C25B9/17C25B11/069C25B9/70Y02P20/129
Inventor 罗宇江莉龙陈崇启詹瑛瑛
Owner 福大紫金氢能科技股份有限公司