A kind of substituted bipyridine ferrous complex and its preparation method and application
A technology of ferrous bipyridyl and complexes, which is applied in the direction of iron organic compounds and iron group organic compounds without C-metal bonds, etc., can solve the problems of high catalyst cost and poor controllability of polymer microstructure, and achieve High molecular weight, excellent selectivity, and easy preparation
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0025] Embodiment 1: the synthesis of substituted bipyridyl ferrous complex 1.
[0026] The structural formula of the substituted bipyridine ferrous complex 1 described in this embodiment is: Prepared by the following method:
[0027] Add anhydrous FeCl to a 50 mL Schlenk bottle under argon atmosphere 2 (139.4mg, 1.1mmol), dissolved in 10mL of absolute ethanol at 60°C; then a solution of 5,5'-dimethyl-2,2'-bipyridine (202.7mg, 1.1mmol) in ethanol (10mL) Add dropwise to the system. React at 60°C for 1 hour. The orange-red complex was precipitated from the system, filtered, washed twice with cold ethanol, concentrated to remove the solvent, and vacuum-dried for 12 hours to obtain apricot-yellow solid product 1 with a yield of 78%.
[0028] Mass Spectrometry: C 12 h 12 Cl 2 FeN 2 : [M-Cl]+: theoretical value: 275.0033; measured value: 275.0038.
[0029] Elemental Analysis: C 12 h 12 Cl 2 FeN 2 : Theoretical value: C, 46.35%; H, 3.89%; N, 9.01%; Measured value: C, 46...
Embodiment 2
[0030] Embodiment 2: the synthesis of substituted bipyridyl ferrous complex 2.
[0031] The structural formula of the substituted bipyridyl ferrous complex 2 described in this embodiment is: Prepared by the following method:
[0032] Add anhydrous FeCl to a 50 mL Schlenk bottle under argon atmosphere 2 (139.4mg, 1.1mmol), dissolved in 10mL of absolute ethanol at 60°C; then 4,4'-Dimethyl-2,2'-dipyridine (202.7mg, 1.1mmol) in ethanol (10mL) Add dropwise to the system. React at 60°C for 1 hour. The brown-yellow complex was precipitated from the system, filtered, washed twice with cold ethanol, concentrated to remove the solvent, and vacuum-dried for 12 hours to obtain the orange-yellow solid product 2 with a yield of 74%.
[0033] Mass Spectrometry: C 12 h 12 Cl 2 FeN 2 :[M-Cl]+: theoretical value: 275.0033; measured value: 275.0040.
[0034] Elemental Analysis: C 12 h 12 Cl 2 FeN 2 : Theoretical value: C, 46.35%; H, 3.89%; N, 9.01%; Measured value: C, 46.85%; H, 3....
Embodiment 3
[0035] Embodiment 3: the synthesis of substituted bipyridyl iron complex 3.
[0036] The structural formula of the substituted bipyridine ferrous complex 3 described in this embodiment is: Prepared by the following method:
[0037] Add anhydrous FeCl to a 50 mL Schlenk bottle under argon atmosphere 2 (76.0mg, 0.6mmol), dissolved in 6mL of absolute ethanol at 60°C; The solution was added dropwise to the system. React at 60°C for 1 hour. The brown-red complex was precipitated from the system, filtered, washed twice with cold ethanol, concentrated to remove the solvent, and dried in vacuum for 12 hours to obtain dark red solid product 3 with a yield of 47%.
[0038] Mass Spectrometry: C 12 h 12 Cl 2 FeN 2 o 2 :[M-Cl]+: theoretical value: 306.9931; measured value: 306.9935.
[0039] Elemental Analysis: C 12 h 12 Cl 2 FeN 2 o 2 : Theoretical value: C, 42.02%; H, 3.53%; N, 8.17%; Measured value: C, 42.51%; H, 3.26%; N, 8.43%.
[0040] Embodiment 4: the synthesis of s...
PUM
| Property | Measurement | Unit |
|---|---|---|
| molecular weight distribution | aaaaa | aaaaa |
| molecular weight distribution | aaaaa | aaaaa |
| molecular weight distribution | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More