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Ice-surface oil-resistant non-slip shoe material and preparation method thereof

An oil-resistant and anti-slip technology, which is applied in the field of oil-resistant and anti-slip shoe materials on ice surfaces and its preparation field, can solve problems such as poor mechanical properties, and achieve the effects of low rolling resistance, good oil resistance and anti-slip performance, and low ash content.

Active Publication Date: 2019-10-11
WENZHOU YIHE SHOE MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The above-mentioned technical scheme mainly adopts high-damping butyl rubber and nitrile rubber to improve the anti-slip effect of the sole, but butyl rubber is difficult to be compatible with other rubbers such as nitrile when it is not chlorinated or brominated. Resulting in poor overall mechanical properties, needs to be improved

Method used

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  • Ice-surface oil-resistant non-slip shoe material and preparation method thereof
  • Ice-surface oil-resistant non-slip shoe material and preparation method thereof
  • Ice-surface oil-resistant non-slip shoe material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] A kind of oil-resistant anti-slip shoe material on ice, the raw material components are shown in Table 1 in parts by weight. The anti-aging agent adopts anti-aging agent RD, the accelerator A adopts accelerator DTDM, and the accelerator B adopts accelerator MBS. The preparation method of this oil-resistant non-slip shoe material comprises the following steps:

[0049] Step 1, mix the glass fiber and the solution prepared by silane coupling agent SI-69 evenly, dry at 100°C for 3 hours, and obtain the modified glass fiber for use;

[0050] Step 2, mix and stir laurane, anti-aging agent, vulcanization accelerator (that is, accelerator A+accelerator B), carbon disulfide and REG-4000 evenly to obtain a compounding agent for use;

[0051] Step 3, mix butyl rubber, cis-butadiene rubber, nitrile rubber, solution polystyrene butadiene rubber and carbon nine resin into the banbury mixer, mix and banbury for 5 minutes, then add white smoke and continue to mix and banbury for 3 mi...

Embodiment 2

[0057] The difference from Example 1 is that, in parts by weight, the raw material components are as shown in Table 1. The preparation method of oil-resistant non-slip shoe material comprises the following steps:

[0058] Step 1, mix the glass fiber with the solution prepared by the silane coupling agent SI-69 evenly, and dry it at 120°C for 4 hours to obtain the modified glass fiber for use;

[0059] Step 2, mix and stir laurane, anti-aging agent, vulcanization accelerator, carbon disulfide and REG-4000 evenly to obtain a compounding agent for later use;

[0060] Step 3, butyl rubber, butadiene rubber, nitrile rubber, solution polystyrene butadiene rubber and C9 resin are mixed and put into a banbury mixer for banburying, mixing and banburying for 10 minutes, then adding white smoke to continue mixing and banburying for 5 minutes, When the temperature reaches 125°C, the rubber masterbatch is obtained;

[0061] Step 4, uniformly mixing the rubber masterbatch, modified glass ...

Embodiment 3

[0065] The difference from Example 1 is that, in parts by weight, the raw material components are as shown in Table 1. The preparation method of oil-resistant non-slip shoe material comprises the following steps:

[0066] Step 1. Mix the glass fiber with the solution prepared by silane coupling agent SI-69 evenly, and dry it at 110°C for 3.5 hours to obtain the modified glass fiber for use;

[0067] Step 2, mix and stir laurane, anti-aging agent, vulcanization accelerator, carbon disulfide and REG-4000 evenly to obtain a compounding agent for later use;

[0068] Step 3, mix butyl rubber, cis-butadiene rubber, nitrile rubber, solution polystyrene butadiene rubber and carbon nine resin into the internal mixer for banburying, mix and banbury for 8 minutes, then add white smoke and continue to mix and banbury for 4 minutes, When the temperature reaches 120°C, the rubber masterbatch is obtained;

[0069] Step 4, uniformly mixing the rubber masterbatch, modified glass fiber, compo...

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Abstract

The invention discloses an ice-surface oil-resistant non-slip shoe material and a preparation method thereof, and relates to the technical field of shoe materials. The shoe material is prepared from butyl rubber, butadiene rubber, nitrile rubber, solution polymerized styrene-butadiene rubber, white smoke, zinc oxide, an anti-ageing agent, a plasticizer, a silane coupling agent and a vulcanizationaccelerator. The shoe material prepared through the formula is combined with the specific pattern of an outsole and integrally formed or adhered to the outsole, and the obtained sole has the advantages of being resistant to oil and slip, good in mechanical performance, free of fog return and the like. The anti-slip performance is excellent, and the shoe material is suitable for being used on the ice and snow ground.

Description

technical field [0001] The invention relates to the technical field of shoe materials, in particular to an oil-resistant and anti-slip shoe material on ice and a preparation method thereof. Background technique [0002] In an environment with thin ice, snow, ice water, and permafrost interfaces, when the soles are in contact with wet and smooth ground or ground with ice attached, ice water will adhere to the surface of the soles to form a water film, making pedestrians walk It is easy to cause slip and fall injuries. Therefore, the requirements for the anti-slip performance of the sole are higher in ice, wet and oily environments, and improving the anti-slip performance is also a key factor for ensuring safety and comfort. [0003] At present, the traditional shoe soles are mainly made of natural rubber and some synthetic rubber. Although they can achieve the basic wear-resistant and anti-skid effects of rubber outsoles, they cannot meet the anti-slip performance of special...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L9/02C08L23/22C08L9/00C08L9/06C08L57/02C08L71/02C08K13/06C08K9/06C08K7/14C08K3/22C08K5/378C08K5/47C08K5/3437A43B13/04
CPCA43B13/04C08K2003/2296C08L9/02C08L2201/08C08L2205/035C08L23/22C08L9/00C08L9/06C08L57/02C08L71/02C08K13/06C08K9/06C08K7/14C08K3/22C08K5/378C08K5/47C08K5/3437
Inventor 黄忠达刘晓清李树和郑元康梁云鸿
Owner WENZHOU YIHE SHOE MATERIAL CO LTD
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