Antioxidant coating as well as preparation method and application thereof

The technology of anti-oxidation coating and diboron trioxide is applied in alkali metal silicate coatings, coatings, devices for coating liquid on the surface, etc. To achieve the effect of reducing the preparation process, wide source of raw materials, and avoiding environmental pollution

Active Publication Date: 2019-10-15
CHINA ERZHONG GRP DEYANG HEAVY IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is still a big gap between the actual effect of anti-oxidation coatings and people's requirements.
Especially the anti-oxidation in the forging and heating process of large nuclear power forgings has not yet seen public information with good results. The anti-oxidation coatings used in the heat treatment process not only have many defects in effect, but also because the forging of large nuclear power forgings is a process that is repeated several times, Different from the simple heat treatment process, first of all, the surface area of ​​the forging that needs to be anti-oxidized is as high as tens of square meters. It is difficult to use the method of painting to meet the production requirements. At the same time, due to the large area, the usual heat treatment coating is expensive and requires multiple times. The second is that in addition to the first forging, the re-forged forgings need to be returned to the furnace and reheated to the forging temperature as soon as possible, so the surface temperature of the forgings coated with anti-oxidation coatings is relatively high, sometimes as high as nearly 1,000 degrees. The third is the surface condition of the forgings The difference is not only for the use of paint but also for

Method used

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  • Antioxidant coating as well as preparation method and application thereof
  • Antioxidant coating as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] Weigh 35 parts of colloidal graphite powder, 35 parts of sodium silicate, 12 parts of metal iron powder, 15 parts of metal aluminum powder, 5 parts of kaolin, 15 parts of mica powder, and 20 parts of diboron trioxide. All the above are parts by weight. Put it in a V-shaped mixer and mix it at high speed for 120 minutes to obtain the heat-treated anti-oxidation coating for carbon steel or alloy steel of the present invention.

[0045] Among them, the fineness of colloidal graphite powder is 320 mesh, the fineness of sodium silicate is 120 mesh, the fineness of diboron trioxide is 120 mesh, the fineness of kaolin and mica powder is 320 mesh, the fineness of metal iron powder is 400 mesh, The fineness of the metal aluminum powder is 320 mesh.

[0046] Coating process: The paint is coated on a 110-ton SA508 steel forging with a compressed air spraying device, the coating thickness is not less than 0.20mm, and the surface temperature of the forging is 80°C.

[0047] Heating...

Embodiment 2

[0049] Weigh 40 parts of colloidal graphite powder, 35 parts of sodium silicate, 15 parts of metal iron powder, 12 parts of metal aluminum powder, 10 parts of kaolin; 20 parts of mica powder and 21 parts of diboron trioxide. All the above are parts by weight; put it in a ball mill and mix it at high speed for 100 minutes to obtain the heat-treated anti-oxidation coating for carbon steel or alloy steel of the present invention.

[0050] Among them, the fineness of colloidal graphite powder is 320 mesh, the fineness of sodium silicate is 120 mesh, the fineness of diboron trioxide is 120 mesh, the fineness of kaolin and mica powder is 320 mesh, the fineness of metal iron powder is 400 mesh, The fineness of the metal aluminum powder is 320 mesh.

[0051] Coating process: The paint is coated on 80 tons of 18MND5 steel forgings with a high-pressure airless spraying device, the coating thickness is not less than 0.20mm, and the surface temperature of the forgings is 950°C.

[0052] ...

Embodiment 3

[0054] Weigh 40 parts of colloidal graphite powder, 30 parts of sodium silicate, 10 parts of metal iron powder, 10 parts of metal aluminum powder, 8 parts of kaolin; 15 parts of mica powder and 22 parts of diboron trioxide. All the above are parts by weight; place it in a VH high-efficiency mixer and mix it at high speed for 80 minutes to obtain the heat-treated anti-oxidation coating for carbon steel or alloy steel of the present invention.

[0055] Among them, the fineness of colloidal graphite powder is 320 mesh, the fineness of sodium silicate is 120 mesh, the fineness of diboron trioxide is 120 mesh, the fineness of kaolin and mica powder is 320 mesh, the fineness of metal iron powder is 400 mesh, The fineness of the metal aluminum powder is 320 mesh.

[0056] Coating process: The paint is coated on 95 tons of 18MND5 steel forgings with a high-voltage electrostatic spraying device, the coating thickness is not less than 0.20mm, and the surface temperature of the forgings ...

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Abstract

The invention relates to an antioxidant coating as well as a preparation method and application thereof and belongs to the technical fields of metal fabricating and coatings for the metal fabricating.The antioxidant coating is prepared from the following materials in parts by weight: 30 to 50 parts of colloidal graphite powder, 30 to 50 parts of sodium silicate, 10 to 20 parts of iron powder, 5 to 15 parts of aluminum powder, 5 to 18 parts of kaolin, 10 to 30 parts of mica powder and 18 to 35 parts of boron trioxide. The coating is all prepared from solid powder, is applied to the surface ofa nuclear power forging by a spraying method, and can provide convenient antioxidant protection for the nuclear power forging forged and heated at the temperature of 1200 DEG C or above; oxidation weight increase caused by long-time heating process is reduced by 95 percent or above.

Description

technical field [0001] The invention relates to an anti-oxidation paint and its preparation method and application, and belongs to the technical field of metal forging and the paint used therefor. Background technique [0002] Large-scale forgings such as nuclear power pressure vessels, evaporators, voltage stabilizer cylinders, and heads manufactured for nuclear power plants are made of medium and low alloy steel such as SA508 and 18MND5, which are severely oxidized at high temperatures during the forging heating process. How to protect them from being oxidized or oxidized as little as possible during the process, especially at the forging temperature of 1200°C and above, is the goal that the forging industry has been pursuing. The free energy of steel at 1200°C and above is reduced due to the oxidation reaction process, and the reduction increases with the increase of temperature; high temperature corrosion is very serious, which not only brings a lot of waste, but also br...

Claims

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Application Information

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IPC IPC(8): C09D1/02C09D1/00C09D7/61B05D1/02B05D1/04
CPCB05D1/02B05D1/04C09D1/00C09D1/02C09D7/61
Inventor 白敏沈国劬毛闯孙嫘陈新倬
Owner CHINA ERZHONG GRP DEYANG HEAVY IND
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