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Modified coated sand for selective laser sintering and preparation method thereof

A laser sintering and selective technology, applied in the direction of manufacturing tools, casting molding equipment, metal processing equipment, etc., can solve the problems of long curing time, poor environmental protection, low strength of sintered products, etc., and achieve short curing time and high product strength. Effect

Active Publication Date: 2021-01-08
ZHONGBEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the disadvantages of coated sand for SLS forming are that the resulting sintered product has low strength, long curing time, and poor environmental protection.

Method used

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  • Modified coated sand for selective laser sintering and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The modified coated sand for selective laser sintering and its preparation method are as follows:

[0026] (1) Add two-dimensional TiC to the RMgCl solution, the concentration of RMgCl solution is 10mol / L, and the temperature is 40°C; the weight ratio of two-dimensional TiC and RMgCl solution is 2:1, and then stir and mix evenly, the stirring time is 30min, and the rotation speed is 20r / min;

[0027] (2) Continue to add KH solution to RMgCl solution subsequently, the concentration of KH solution is 20mol / L, and solution temperature is 40 ℃; The mass ratio of KH solution and RMgCl solution is 2: 1, then stir and mix evenly, stirring time is 30min, The speed is 20r / min;

[0028] (3) Continue to add organosilane coupling agent and ethyl bromide subsequently, the weight ratio of organosilane coupling agent and RMgCl solution is 1: 2, the weight ratio of bromide ethane and RMgCl solution is 1: 2, then stir and mix evenly, The stirring time is 10min, and the rotating speed...

Embodiment 2

[0033] (1) Add two-dimensional TiC to the RMgCl solution, the concentration of RMgCl solution is 25mol / L, and the temperature is 55°C; the weight ratio of two-dimensional TiC and RMgCl solution is 2:1, and then stir and mix evenly, the stirring time is 30min, and the rotation speed is 20r / min;

[0034] (2) Continue to add KH solution to RMgCl solution subsequently, the concentration of KH solution is 30mol / L, and solution temperature is 50 ℃; The mass ratio of KH solution and RMgCl solution is 2: 1, then stir and mix evenly, stirring time is 30min, The speed is 20r / min;

[0035] (3) Continue to add organosilane coupling agent and ethyl bromide subsequently, the weight ratio of organosilane coupling agent and RMgCl solution is 1: 2, the weight ratio of bromide ethane and RMgCl solution is 1: 2, then stir and mix evenly, The stirring time is 10min, and the rotating speed is 20r / min;

[0036] (4) The obtained solution is filtered subsequently, and the obtained filter residue i...

Embodiment 3

[0040] (1) Add two-dimensional TiC to the RMgCl solution, the concentration of RMgCl solution is 20mol / L, and the temperature is 55°C; the weight ratio of two-dimensional TiC and RMgCl solution is 2:1, and then stir and mix evenly, the stirring time is 30min, and the rotation speed is 20r / min;

[0041](2) Continue to add KH solution to RMgCl solution subsequently, the concentration of KH solution is 30mol / L, and solution temperature is 50 ℃; The mass ratio of KH solution and RMgCl solution is 2: 1, then stir and mix evenly, stirring time is 30min, The speed is 20r / min;

[0042] (3) Continue to add organosilane coupling agent and ethyl bromide subsequently, the weight ratio of organosilane coupling agent and RMgCl solution is 1: 2, the weight ratio of bromide ethane and RMgCl solution is 1: 2, then stir and mix evenly, The stirring time is 10min, and the rotating speed is 20r / min;

[0043] (4) The resulting solution is filtered subsequently, and the resulting filter residue ...

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Abstract

The invention provides a kind of selective laser sintering modified precoated sand and a preparation method thereof. The precoated sand is formed by mixing modified two-dimensional TiC, graphene, sandgrains, urotropine, phenolic resin and calcium stearate in the weight ratio of (1-2):1-2:100:10-15:1-5:4-8. The preparation method comprises the steps of pouring the modified two-dimensional TiC, thegraphene and the sand grains into a sand mixer to be stirred and heated to 120-140 DEG C; adding the phenolic resin, mixing the sand for 60-100 s and reducing the temperature to 110 DEG C; and addinga urotropine aqueous solution and the calcium stearate, mixing the sand for 30 s and stirring the sand to a loose sand state. The modified precoated sand prepared through the method has the advantages of being friendly to environment, short in sintering and curing time and high in strength.

Description

technical field [0001] The invention relates to the technical field of new materials, in particular to a modified coated sand for selective laser sintering and a preparation method thereof. Background technique [0002] In the sand casting process, the preparation of the core box and pattern is crucial. The traditional preparation method has complex process, high cost and long period. Especially for sand molds for large and complex thin-walled castings, there are often multiple sand molds combined, and a slight error in the position and size of the castings will lead to low precision castings, poor surface quality, and a large amount of cutting, which not only wastes a lot of metal Materials, and increased processing costs, low work efficiency, poor economic effect. Selective laser sintering (SLS) technology is a kind of 3D printing technology. It has the characteristics of fast forming speed, high forming precision, short production cycle and low economic cost. The use of...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22C1/00B33Y70/10
CPCB22C1/00B33Y70/00
Inventor 白培康赵占勇吴利芸李忠华李晓峰王宇刘斌王建宏李玉新
Owner ZHONGBEI UNIV