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A kind of marine cement and preparation method thereof

A technology of marine cement and clinker, which is applied in the field of cement, can solve the problems of delayed ettringite formation in cement adaptability, no reduction in concrete shrinkage, and difficulty in adding amount, so as to increase durability, reduce water consumption, and cement Effect of Porosity Reduction

Active Publication Date: 2021-08-06
德州中科新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to solve the above problems, methods such as mixing expansion agent and fiber mixing have been used successively on the market, but the use of expansion agent especially requires concrete to be cured with water in the early stage, the conditions are harsh, and there are serious cement adaptability and delayed ettringite formation. In addition, there are difficulties in adjusting the amount of addition. If the amount is too small, the effect will not be achieved. If the amount is too large, the excess part may cause cracks to expand due to expansion. Therefore, the expansion agent is used for There is an uncertainty in the end result
The addition of fiber can only improve the crack resistance of concrete, but does not reduce the shrinkage of concrete. At the same time, the price of fiber is high, and there are compatibility problems with concrete, which greatly limits its promotion.

Method used

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  • A kind of marine cement and preparation method thereof
  • A kind of marine cement and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] Raw materials for preparing clinker account for 83% of limestone, 12% of iron ore, and 5% of clay ore.

[0052] The proportion of materials for preparing the clinker mixture is: 75% of clinker, 10% of gypsum, and 15% of Class II fly ash.

[0053] The proportion of materials for preparing cement is: mixed clinker 58%, ultrafine mineral powder 22%, silicon powder 8%, vitrified microbeads 12%, and the specific surface area of ​​ultrafine mineral powder is controlled to be 6000-8000cm 2 / g, the specific surface area of ​​silicon powder is 12000-13000cm 2 / g, the specific surface area of ​​vitrified microbeads is 18000-22000cm 2 / g, in ultrafine mineral powder, silicon powder and vitrified microspheres, the material in glass state accounts for 90wt%.

[0054] The above ratios are mass ratios.

[0055] Preparation of clinker: Limestone, iron ore and clay ore are calcined at 1250°C in a low-oxygen atmosphere to obtain clinker.

[0056] Pre-grinding of clinker: Put the abov...

Embodiment 2

[0059] Raw materials for preparing clinker account for 87% of limestone, 12% of iron ore, and 1% of clay ore.

[0060] The proportion of materials for preparing the clinker mixture is: clinker 68%, gypsum 17%, and II fly ash 15%.

[0061] The proportion of materials for preparing cement is: mixed clinker 64%, ultrafine mineral powder 18%, silica fume 7%, vitrified microbeads 11%, and the specific surface area of ​​ultrafine mineral powder is controlled to be 6000-8000cm 2 / g, the specific surface area of ​​silicon powder is 12000-13000cm 2 / g, the specific surface area of ​​vitrified microbeads is 18000-22000cm 2 / g, in ultrafine mineral powder, silicon powder and vitrified microspheres, the material in glass state accounts for 92wt%.

[0062] Preparation of clinker: Limestone, iron ore and clay ore are calcined at 1350°C in a low-oxygen atmosphere to obtain clinker.

[0063] Pre-grinding of clinker: Put the above-mentioned clinker, gypsum, and II fly ash into the cement mi...

Embodiment 3

[0066] Raw materials for preparing clinker account for 86% of limestone, 10% of iron ore, and 4% of clay ore.

[0067] The proportion of materials for preparing the clinker mixture is: clinker 69%, gypsum 11%, and primary fly ash 20%.

[0068] The proportion of materials for preparing cement is: mixed clinker 64%, ultrafine mineral powder 23%, silicon powder 5%, vitrified microbeads 8%, and the specific surface area of ​​ultrafine mineral powder is controlled to be 6000-8000cm 2 / g, the specific surface area of ​​silicon powder is 12000-13000cm 2 / g, the specific surface area of ​​vitrified microbeads is 18000-22000cm 2 / g, in the ultrafine mineral powder, silicon powder and vitrified microspheres, the material in the glass state accounts for 98%.

[0069] Preparation of clinker: Limestone, iron ore and clay ore are calcined at 1300°C in a low-oxygen atmosphere to obtain clinker.

[0070] Pre-grinding of clinker: put the above-mentioned clinker and gypsum into the cement mi...

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Abstract

The invention provides a marine cement and a preparation method thereof. Marine cement: mixed clinker 58%‑64%, superfine mineral powder 18%‑23%, silica fume 5%‑8%, and vitrified microbeads 8%‑12%; mixed clinker: clinker 68%‑ 78%, gypsum 14%‑17% and fly ash 17%‑22%; clinker: limestone 83%‑87%, iron ore 8%‑12% and clay ore 1%‑5%. The preparation method of marine cement: calcining limestone, iron ore and clay ore to obtain clinker, then adding gypsum and fly ash for grinding to obtain mixed clinker, mixing the mixed clinker with ultrafine mineral powder, silicon powder and vitrified The microbeads are mixed and homogenized to obtain marine cement. Marine cement can effectively reduce the cracks, capillary pores and gel pores of hardened cement-based materials, improve the fluidization effect, strength effect and durability effect of cement paste, and effectively reduce the corrosion from corrosive ions in seawater.

Description

technical field [0001] The invention relates to the field of cement, in particular to a marine cement and a preparation method thereof. Background technique [0002] Marine cement is mainly used in the preparation process of marine concrete and marine mortar and other materials. Concrete made of ordinary Portland cement has poor corrosion resistance, poor durability, and short concrete life due to the large heat release of cement, which is easy to cause cracks, large porosity of cement stone, and strong permeability. [0003] Concrete shrinkage is a phenomenon in which the volume of concrete shrinks after pouring and hardening, which not only reduces the structural strength, but also provides a channel for air and water to enter the concrete, making the concrete prone to carbonation corrosion and corrosion of steel bars in cold regions. Freeze-thaw cycles, which greatly reduce the durability of the concrete, shorten the life of the building. In recent years, high-performan...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B7/26C04B7/04
CPCC04B7/04C04B7/26Y02P40/10
Inventor 于小雷李延华王金虎杨斌焦汝强牛志成周志平
Owner 德州中科新材料有限公司