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A kind of three-dimensional anode electrode and its applied microbial fuel cell and starting method

A fuel cell, anode electrode technology, applied in biochemical fuel cells, fuel cells, battery electrodes, etc., can solve problems such as limiting electrochemical activity, difficulty in mutual contact, and increasing internal resistance of the system, and achieves a combination method that is simple and easy to implement and improve. Electrochemical activity, the effect of promoting system electricity production

Active Publication Date: 2021-06-08
TSINGHUA UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, for three-dimensional dispersed filled electrode particles, such as granular activated carbon, due to the large electrode area and small porosity, the surface of carbon particles is easily wrapped by biofilm, and it is difficult to contact each other, which affects electron transfer.
Although carbon brushes can integrate titanium rods and carbon fiber electrode materials to integrate the electrode surface into a whole to ensure electron transfer, the proportion of carbon fiber hairs filling the anode cavity is limited, and there are gaps with the cation exchange membrane, which ultimately increases the mass transfer resistance. , increase the internal resistance of the system and limit the electrochemical activity
The above problems have hindered the application and promotion of microbial fuel cells.

Method used

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  • A kind of three-dimensional anode electrode and its applied microbial fuel cell and starting method
  • A kind of three-dimensional anode electrode and its applied microbial fuel cell and starting method
  • A kind of three-dimensional anode electrode and its applied microbial fuel cell and starting method

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Embodiment

[0050] According to the size of the anode cavity (26cm x 6cm x 10cm), three-dimensional anode electrodes are made at a distance of 1cm, and the cross-sectional area of ​​each extension layer made of carbon fiber cloth is 10cm x 6cm. The area of ​​the base layer and the cation exchange membrane is 26cm x 6cm.

[0051] The granular activated carbon used in the cathode cavity is columnar, with a diameter range of 1.2-1.8 mm and a length range of 3-5 mm. 200-500 mesh metal mesh structure is selected for the metal mesh in contact with the filled granular activated carbon. The length of the metal titanium sheet is 20-30cm, and the width is 1-2cm, which is easy to adjust and deform, and closely contacts the metal mesh. Catholyte selects the potassium ferricyanide solution of 50mM (16.46g / L) for use.

[0052] The cation exchange membrane used to separate the anode cavity and the cathode cavity is an ion exchange membrane with sulfonic acid group as the main structural group, which c...

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Abstract

The invention discloses a three-dimensional anode electrode and a microbial fuel cell and a starting method thereof. The microbial fuel cell includes a pool body, a sewage pump, a catholyte pump and a catholyte tank. The cell body includes an anode cavity and a cathode cavity and a cation exchange membrane. A three-dimensional anode electrode including a three-dimensional layered base layer and several extension layers is arranged in the anode chamber, and the base layer is arranged close to the cation exchange membrane. Anode circuit lines are arranged between the extension layers. A catholyte circulation is formed between the catholyte tank and the cathode cavity. The cathode cavity is provided with a cathode electrode, and the cathode electrode is selected from carbon rods or carbon brushes or includes at least two metal meshes connected to each other through titanium sheets, and granular activated carbon is filled between the metal meshes. In the start-up process, anaerobic sludge is injected into the anode cavity to realize the inoculation, cultivation, enrichment and domestication of microorganisms in the base layer and extension layer, and realize electricity production. The three-dimensional anode electrode structure of the invention is beneficial to electron collection and transmission, and has the advantages of good electricity production effect, simple structure, convenient manufacture and the like.

Description

technical field [0001] The invention relates to a three-dimensional anode electrode, a microbial fuel cell and a starting method thereof, and belongs to the technical field of fuel cells. Background technique [0002] With the continuous development of society and economy, people's demand for traditional fossil fuels continues to increase. However, the limited use of fossil fuels and their limited storage have led to the continuous aggravation of the energy crisis. Therefore, people's demand for new energy is constantly pressing. At the same time, the aggravation of environmental pollution has also caused difficulties in people's daily life. How to find effective solutions to environmental pollution and convert pollutants into renewable energy will play an important role in solving the energy crisis. [0003] Microbial fuel cell technology (MFC) is a new technology that combines sewage treatment and biological electricity generation. This function of simultaneously realiz...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/96H01M4/86H01M8/16H01M8/04302
CPCH01M4/8621H01M4/8642H01M4/8673H01M4/96H01M8/16H01M2004/8684H01M2004/8689H01M8/04302Y02E60/50
Inventor 梁鹏罗帅黄霞
Owner TSINGHUA UNIV
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