Quaternary MAX phase reinforced NiAl-based high-temperature lubricating composite and preparation method thereof

A composite material and high-temperature technology, which is applied in the field of quaternary MAX phase-reinforced NiAl-based high-temperature lubricating composite materials and its preparation, to achieve the effects of increasing strength, improving wettability, and realizing high-temperature lubricating performance

Inactive Publication Date: 2019-11-15
XI AN JIAOTONG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The technical problem to be solved by the present invention is to provide a quaternary MAX phase reinforced NiAl-based high-temperature lubricating composite material and its preparation method in view of the above-mentioned deficiencies in the prior art, using Mo, Ti, Al, C powder in the high-temperature sintering process in situ reaction to generate a new type of quaternary Mo

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  • Quaternary MAX phase reinforced NiAl-based high-temperature lubricating composite and preparation method thereof
  • Quaternary MAX phase reinforced NiAl-based high-temperature lubricating composite and preparation method thereof
  • Quaternary MAX phase reinforced NiAl-based high-temperature lubricating composite and preparation method thereof

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preparation example Construction

[0031] The invention discloses a method for preparing a quaternary MAX phase-reinforced NiAl-based high-temperature lubricating composite material. Nanostructured mixed powder is prepared by high-energy ball milling, and a nanostructured composite material with uniform phase distribution is successfully prepared. Mo powder, Ti powder, Al Powder and C powder react in situ during high-temperature sintering to form a new quaternary MAX phase (Mo 2 TiAlC 2 ), the high-temperature lubricity of the composite material is achieved, and at the same time, the wettability between the MAX phase and the NiAl matrix is ​​effectively improved, and the strength of the composite material is effectively improved. Specific steps are as follows:

[0032] S1. Mixed powder ratio and ball milling

[0033] The powder is weighed according to the composition design ratio of the composite material. In the raw material powder, NiAl is 75-90wt%, and the remaining powder is 10-25wt%. The remaining powder...

Embodiment 1

[0042] The NiAl material was prepared by hot pressing sintering technology, and the weighed powder was loaded into a graphite grinding tool. Before powder loading, a layer of graphite paper is laid on the wall of the graphite grinding tool to prevent the powder from sticking to the graphite grinding tool during the sintering process. The NiAl material prepared by hot pressing and sintering is dense and uniform. The microhardness of the composite material is 251.6HV, and the friction coefficient is 0.78( figure 2 ), the wear rate is 7.3×10 -5 mm 3 / Nm, such as figure 2 shown.

Embodiment 2

[0044] Preparation of homogeneously mixed nanostructured NiAl, Ti, Al and C powders by high energy ball milling

[0045] The powder weighed in proportion is put into a zirconia ball mill jar for high-energy ball milling to prepare a uniformly mixed nanostructure mixed powder, and then the mixed powder is loaded into a graphite mill. Before powder loading, a layer of graphite paper is laid on the wall of the graphite grinding tool to prevent the powder from sticking to the graphite grinding tool during the sintering process. The mixed powder with nanostructure has the effect of fine-grain strengthening, which can effectively improve the strength of composite materials. The Ti, Al and C powder added to the composite material can react in situ to form Ti during the high temperature vacuum sintering process 3 AlC 2 Phase, which has excellent high-temperature lubricating properties, can realize the high-temperature lubricating properties of composite materials. At the same time,...

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Abstract

The invention discloses a quaternary MAX phase reinforced NiAl-based high-temperature lubricating composite and a preparation method thereof. The preparation method comprises the following steps of respectively weighing NiAl powders, Mo podwers, Ti powders, Al powders and C powders in proportion, and then putting the weighed powders into a high-energy ball mill for ball milling to prepare nano-structure mixed powders uniformly mixed; and putting the mixed powders into a graphite grinding tool for cold pressing treatment, and carrying out vacuum hot pressing sintering in a vacuum hot pressing sintering furnace after cold pressing is finished to obtain the NiAl-Mo2TiAlC2 composite. According to the quaternary MAX phase reinforced NiAl-based high-temperature lubricating composite and the preparation method thereof, a novel quaternary MAX phase (Mo2TiAlC2) is generated by the in-situ reaction of Mo, Ti, Al and C in the sintering process, so that the high-temperature lubricating performanceof the composite is achieved, and the wettability between the MAX phase and a NiAl matrix and the structure of the composite are effectively improved at the same time, therefore, the strength of thecomposite is effectively improved, and the excellent lubricating performance of the composite under the condition of higher temperature is achieved.

Description

technical field [0001] The invention belongs to the technical field of high-temperature high-strength lubricating composite materials, and in particular relates to a quaternary MAX phase-reinforced NiAl-based high-temperature lubricating composite material and a preparation method thereof. Background technique [0002] In recent years, my country's aerospace, nuclear industry and other high-tech industries have developed rapidly, and high-temperature moving parts in these fields also have serious friction and wear problems, which will seriously affect the reliability and stability of the entire equipment operation, and further affect The service life of the entire equipment. Therefore, it is urgent to use the basic knowledge of materials science and tribology theory to design and construct a high-temperature lubricating composite material with excellent friction and wear properties at higher temperatures to meet the rapid development of my country's aerospace, nuclear industr...

Claims

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Application Information

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IPC IPC(8): C22C32/00C22C1/05C22C1/10B22F9/04B22F3/02B22F3/10
CPCB22F3/02B22F3/1007B22F3/1039B22F9/04B22F2009/043B22F2999/00C22C1/058C22C32/0052B22F2201/20
Inventor 李博高义民李聪康云川郑巧玲赵四勇
Owner XI AN JIAOTONG UNIV
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