Polarizing film with added adhesive layer, polarizing film with added adhesive layer for in-cell liquid crystal panel, in-cell liquid crystal panel, and liquid crystal display device
An adhesive layer and liquid crystal panel technology, applied in the field of liquid crystal display devices and embedded liquid crystal panels, can solve the problems of unstable sensor electrode capacity, reduced sensitivity of touch panels, disturbance of electric field, etc., and achieve stable and good antistatic function , The effect of suppressing poor conduction and satisfying sensitivity
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Embodiment 1
[0171] (Preparation of Acrylic Polymer)
[0172] A monomer mixture containing 99 parts of butyl acrylate (BA) and 1 part of 4-hydroxybutyl acrylate (HBA) was placed in a four-necked flask equipped with a stirring blade, a thermometer, a nitrogen gas introduction tube, and a condenser. Further, 0.1 part of 2,2'-azobisisobutyronitrile as a polymerization initiator was added to 100 parts of the above-mentioned monomer mixture (solid content) together with 100 parts of ethyl acetate, and nitrogen gas was introduced while slowly stirring. After replacement, the temperature of the liquid in the flask was maintained at around 55° C., and a polymerization reaction was performed for 8 hours to prepare a solution of an acrylic polymer.
[0173] (Preparation of Adhesive Composition)
[0174] With respect to 100 parts of the solid content of the solution of the acrylic polymer obtained above, an ionic compound was blended in the amount (solid content, active ingredient) shown in Table 1,...
Embodiment 1~17、 comparative example 1~3
[0193]
[0194] On one side of the polarizing film obtained above, a tackifier layer and an adhesive layer were sequentially formed in combinations shown in Table 1 to prepare a polarizing film with an adhesive layer. In addition, in Examples 15-17, the anchor layer was used.
[0195] It should be noted that in Comparative Example 1, no monomer containing polar functional groups was used in the monomer components constituting the adhesive layer. In Comparative Examples 2 and 3, organic Anion cation salts are combined with inorganic cation anion salts (alkali metal salts).
[0196] The following evaluations were performed about the pressure-sensitive adhesive layer and the polarizing film with a pressure-sensitive adhesive layer obtained in the above-mentioned Examples and Comparative Examples. The evaluation results are shown in Table 2.
[0197]
[0198] (i) The surface resistance value of the tackifier layer was measured on the tackifier-side surface of the polarizing ...
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