Transfer-type photosensitive film, method for forming cured film pattern, cured film and touch panel
A photosensitive film and cured film technology, applied in the input/output process of data processing, instruments, electrical digital data processing, etc. The effect of height difference
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[0167] Hereinafter, although an Example and a comparative example demonstrate this invention more concretely, this invention is not limited to the following Example.
[0168] [Preparation of binder polymer solution]
Synthetic example A1
[0170] 85.7 parts by mass of 1-methoxy-2-propanol (manufactured by Daicel Chemical Industry Co., Ltd.) was charged in advance in the reaction vessel, and the temperature was raised to 80°C. On the other hand, 46 parts by mass of cyclohexyl methacrylate, 2 parts by mass of methyl methacrylate, 52 parts by mass of methacrylic acid, and 10 parts by mass of an azo-based polymerization initiator (manufactured by Wako Pure Chemical Industries, Ltd., V-601) were mixed to obtain a mixed solution. This mixed solution was dripped into the said reaction container of 80 degreeC over 2 hours under nitrogen atmosphere. After dripping, it was made to react for 4 hours, and the acrylic resin solution was obtained.
[0171] Next, 2.5 parts by mass of hydroquinone monomethyl ether and 8.4 parts by mass of tetraethylammonium bromide were added to the above-mentioned acrylic resin solution, and then 32 parts by mass of glycidyl methacrylate was added dropwise over 2 hours. After dropping, react...
Synthetic example A2
[0173] Add 62 parts by mass of propylene glycol monomethyl ether and 62 parts by mass of toluene to a flask equipped with a stirrer, a reflux cooler, an inert gas inlet, and a thermometer, raise the temperature to 80°C under a nitrogen atmosphere, and keep the reaction temperature at 80°C The compound shown in Table 1 and 1.5 parts by mass of 2,2'-azobis(isobutyronitrile) were uniformly added dropwise at ±2°C over 4 hours. After the dropwise addition, stirring was continued at 80° C.±2° C. for 6 hours to obtain binder polymer solution A2 (solid content: 45 mass %) having a weight average molecular weight of 30,000 and an acid value of 156.6 mgKOH / g.
[0174] 【Table 1】
[0175]
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