Composite carbon material and preparation method thereof, rubber composite material and tire

A composite carbon and rubber technology, which is applied in the field of composite materials, can solve the problems of reducing the low hysteresis performance of rubber, reducing rubber hysteresis performance, and difficulty in uniform dispersion, and achieves good low hysteresis, good dispersion performance, and a wide range of applications.

Active Publication Date: 2019-11-19
青岛黑猫新材料研究院有限公司
View PDF5 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This is mainly due to the fact that fillers such as carbon black, silica, and carbon nanotubes are mostly nano-sized, and their own agglomeration is very serious. It is difficult to achieve uniform dispersion by directly mixing them into the rubber matrix.
Uneven filler dispersion will directly affect the reinforcing effect of rubber, and it is also not conducive to reducing the hysteresis performance of rubber
Although it is also propos

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Composite carbon material and preparation method thereof, rubber composite material and tire
  • Composite carbon material and preparation method thereof, rubber composite material and tire
  • Composite carbon material and preparation method thereof, rubber composite material and tire

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0039] According to a first aspect of the present invention, a method for preparing a composite carbon material is provided, comprising the following steps:

[0040] (a) providing an emulsion formed by a reinforcing filler, a dispersant and water, the reinforcing filler comprising silica;

[0041] (b) mixing the raw material oil and the active agent, so that the obtained modified raw material oil is cracked, and the obtained cracked product is cooled to obtain the primary structure modified carbon black existing in the form of flue gas;

[0042] (c) Spraying the emulsion, and reacting the obtained emulsion in the form of atomized droplets with the primary structure-modified carbon black in the form of flue gas to obtain a composite carbon material.

[0043] In the preparation method of the composite carbon material provided by the present invention, the atomized liquid droplets formed after spraying the emulsion of a specific composition react with the primary structure modifi...

Embodiment approach

[0061] As an optional embodiment of the present invention, in step (a), the preparation method of the emulsion comprises the following steps:

[0062] Mix and emulsify the reinforcing filler, dispersant and water to obtain an emulsion;

[0063] Preferably, the mixing temperature in the preparation method of the emulsion is 20-100°C; typical but non-limiting mixing temperatures are 20°C, 30°C, 40°C, 50°C, 60°C, 70°C, 80°C, 90°C °C or 100 °C.

[0064] More preferably, in step (a), the preparation method of emulsion comprises the following steps:

[0065] The reinforcing filler, dispersant and water are mixed in a mixer, and the temperature during mixing is controlled at 20-100°C. After mixing evenly, the mixed solution is placed in an emulsifier with shearing and grinding functions for emulsification to obtain emulsion.

[0066] Through the specific limitation of the preparation method of the emulsion, the reinforcing filler and water can be completely fused.

[0067] As an ...

Embodiment 1

[0102] This embodiment provides a method for preparing a composite carbon material, comprising the following steps:

[0103] (a) providing an emulsion of reinforcing fillers, dispersants and water;

[0104] Mix the reinforcing filler, dispersant and water in a mixer. The mixer has stirring and heating functions. The temperature is controlled at 50°C. After mixing evenly, the mixed liquid enters an emulsifier with shearing and grinding functions for emulsification , to obtain an emulsion;

[0105] The reinforcing filler is white carbon black, and the mass fraction of the reinforcing filler in the emulsion is 5%; the dispersant is a silicon-boron coupling agent, purchased from Qingdao Siwei Chemical Co., Ltd., the brand is BF-1, and the dispersant is in the emulsion The mass fraction in is 0.5%;

[0106] (b) Feedstock oil and active agent are added in the storage tank according to the mass ratio of 100:2, and the obtained modified feedstock oil is transported to the crude oil ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention provides a composite carbon material and a preparation method thereof, a rubber composite material and a tire, and relates to the technical field of carbon materials. According to the composite carbon material preparation method, an emulsifying liquid with a specific composition is sprayed to form atomized liquid droplets, the atomized liquid droplets react with primary structurally-modified carbon black existing in the form of flue gas, and by using a reinforcing filler and surface characteristics of the primary structurally-modified carbon black, the reinforcing filler reacts with and links to the primary structurally-modified carbon black to form the integration so as to obtain the composite carbon material. According to the present invention, the preparation method has simple and convenient operation, and is suitable for industrial-scale production, and the prepared composite carbon material has good low-hysteresis property. The present invention further provides a composite carbon material, which is prepared by using the composite carbon material preparation method, can meet the low-hysteresis performance requirement and the requirements of large-scale tire mixing, can be filled into different types of rubbers, is not limited to specific rubber latex, and has wide application range.

Description

technical field [0001] The invention relates to the technical field of composite materials, in particular to a composite carbon material and a preparation method thereof, a rubber composite material and a tire. Background technique [0002] In the past ten years, since the introduction of tire labels by the European Union, the domestic tire industry has vigorously developed green tires in response to the development of the industry. The general requirements of green tires are energy saving, safety, and durability, which are specifically reflected in the driving performance of low rolling resistance, high wet skid resistance, and high wear resistance. These three functions influence each other and restrict each other, and they are vividly called the "devil's triangle" function. In response to the advocacy of green tires and adapting to industry competition, upstream filler companies for tires are also striving to introduce low-hysteresis fillers. [0003] At present, from t...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08K9/06C08K3/36C08K3/04C08L9/06C08L9/00
CPCC08K3/04C08K3/36C08K9/06C08L9/06C08L9/00
Inventor 王宏安鲁
Owner 青岛黑猫新材料研究院有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap