Drag reducer, and preparation method and application thereof

A technology of drag reducing agent and coating agent, applied in chemical instruments and methods, mechanical equipment, other chemical processes, etc., can solve problems such as adverse effects, clumping of drag reducing polymer particles, unfavorable application, etc., to reduce settling and sticking. junction, improve dispersion performance, and achieve the effect of drag reduction effect

Active Publication Date: 2019-12-17
广东粤首新科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, to achieve drag reduction, the surfactant content must reach a critical concentration, and the dosage is relatively large
In addition, the surfactant must be mixed evenly in the fluid to achieve a good drag reduction effect. This is another problem with the addition method for crude oil pipeline transportation, which is very uneconomical
[0006] At present, drag reducer products are basically a suspension of high-grade α-olefin polymer powder particles dispersed in a carrier solution, but it has disadvantages such as poor dispersion, poor stability, and easy delamination, and even clusters of drag-reducing polymer particles , agglomeration, which brings a lot of inconvenience to the field application of drag reducer
The current solution is often to add functional additives such as dispersants, emulsifiers, viscosity modifiers, and scale inhibitors to the system. The introduction of these additives can change the interface properties between the surface of α-olefin polymer powder particles and the carrier, and increase its The force of action with the carrier solution, that is, to slow down the sedimentation and delamination of the α-olefin polymer powder particles and the carrier solution; so that a more stable drag reducer can be obtained, and the commonly used dispersant is stearate (such as magnesium salt , sodium salt, calcium salt), although its introduction can solve the dispersibility problem of drag reducer, but it introduces metal ions or other substances into the original or refined oil, which is not conducive to its subsequent application or has adverse effects

Method used

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  • Drag reducer, and preparation method and application thereof
  • Drag reducer, and preparation method and application thereof
  • Drag reducer, and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0044] The preparation method of the present invention will be further described in detail in conjunction with specific examples below. It should be understood that the following examples are only for illustrating and explaining the present invention, and should not be construed as limiting the protection scope of the present invention. All technologies realized based on the above contents of the present invention are covered within the scope of protection intended by the present invention.

[0045] The experimental methods used in the following examples are conventional methods unless otherwise specified; the reagents and materials used in the following examples can be obtained from commercial sources unless otherwise specified.

[0046] The performance parameter of the crude oil selected in the present embodiment is as follows:

[0047] crude oil name Viscosity, 50℃, mm 2 / s

[0048] Judging from the oil species tested in this test, sulfur-containing oils have ...

Embodiment 1

[0050] Take the following components by the following parts by mass: (a) α-olefin polymer; 25 parts by mass; (b) carrier component; 100 parts by mass; wherein, (1) oleic acid triglyceride; 30 parts by mass (2) linoleic acid triglyceride; 55 mass parts; (3) palmitic acid triglyceride; 9 mass parts; (4) linoleic acid triglyceride; 6 mass parts;

[0051] Among them, the α-olefin polymer is purchased from Innospec Limited, and its intrinsic viscosity (IV) is 27-29 dl / g. The remaining components can also be obtained from conventional commercial channels in the art.

[0052] The above-mentioned α-olefin polymer is frozen by liquid nitrogen for low-temperature grinding to obtain powder particles with an average particle size of 80-100 mesh. Place the powder particles in the room air and return to ambient temperature for use.

[0053] The above mixture was stirred at high speed with compressed air to prepare drag reducer 1.

[0054] Carry out performance test to described drag redu...

Embodiment 2-7

[0061] The preparation method of drag reducer 2-7 is the same as that of Example 1, and the differences are listed in Table 1.

[0062] Table 1 is the component content and stability data of the drag reducer described in Examples 1-7

[0063]

[0064]

[0065] The drag reducers prepared in the above-mentioned Examples 1-7 are all applicable to crude oil, and an additional coating agent has been added in the examples of Examples 5-7, which has a good effect on the engine during the use of oil products. The drag reducing agent of embodiment 5-7 is also particularly suitable for the drag reducing effect of refined oil. Those skilled in the art can understand that if a special content of coating agent is added to the drag reducer of Examples 1-5, it can also be applied to the drag reduction of finished oil.

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Abstract

The invention provides a drag reducer, and a preparation method and an application thereof. The drag reducer has a high drag reduction efficiency; the carrier component of the drag reducer can effectively avoid the phenomena of breakage and the like of the macromolecular chain of an alpha-olefin polymer in the use process; and glyceryl trioleate and glyceryl trilinoleate also added to the drag reducer as carriers can assist in achieving the drag reduction effect, and the carriers also avoid the phenomena of layering or caking of the drag reducer in the storage process, so the blocking phenomenon is avoided. The drag reducer is a green and environmentally-friendly drag reducer, and the added carrier components are mild reagents, so compared with other drag reducers, the prepared drag reducer has no pungent smell, and is popular with operators. Moreover, the drag reducer has a wide application range, is suitable for crude oils and mixed crude oils with various densities, and is also suitable for product oils with high requirements for additives.

Description

technical field [0001] The invention belongs to the technical field of crude oil or refined oil additives, and in particular relates to a drag reducer suitable for crude oil or refined oil system and its preparation method and application. Background technique [0002] At present, people's oil exploration has entered a golden age, and the normal operation of many fields related to life is inseparable from the supply of crude oil or product oil, but the areas that can produce these crude oil or product oil are often located in remote areas. For crude oil Or the long-distance pipeline transportation of refined oil has become an indispensable link in its development process. Long-distance transportation has led to the emergence of drag reducers, which are chemical agents used to reduce fluid flow resistance, generally a long-chain polymer. After the drag reducer is added to the pipeline, the drag reducer is uniformly dispersed in the fluid in a continuous phase, forming an ela...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/00F17D1/17
CPCC09K3/00F17D1/17
Inventor 付海明傅小川
Owner 广东粤首新科技有限公司
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