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Preparing method of graphene thermoelectricity fibers with interphase types p and n

A graphene fiber, graphene technology, applied in the direction of carbon fiber, fiber processing, fiber chemical characteristics, etc., can solve the problems of poor flexibility, continuity and mechanical properties, unfavorable portable wearable device application, single and other problems, and achieve low preparation cost. , good flexibility, simple preparation process

Inactive Publication Date: 2019-12-20
JIANGXI SCI & TECH NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, traditional thermoelectric devices are made of a single p-type or n-type graphene fiber, and there is currently no continuous and complete preparation method for p-type and n-type graphene fibers
The continuous materials between p-type and n-type phases are usually connected by solder or adhesive, which has poor flexibility, continuity and mechanical properties, which is not conducive to the application in portable wearable devices.

Method used

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  • Preparing method of graphene thermoelectricity fibers with interphase types p and n
  • Preparing method of graphene thermoelectricity fibers with interphase types p and n
  • Preparing method of graphene thermoelectricity fibers with interphase types p and n

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Embodiment 1

[0028] Such as figure 1 Shown, a kind of preparation method of the graphene thermoelectric fiber of p-type and n-type phase, comprises the following steps:

[0029] (1) graphite is prepared into graphene oxide dispersion liquid by modified Hummers method, wherein, the particle size of graphite is 200 orders, and the concentration of the graphene oxide dispersion liquid obtained is 6mg / ml;

[0030] (2) Take the above 2ml graphene oxide dispersion in a clean reagent bottle, add 0.03g of vitamin C to mix with it, shake fully, put the reagent bottle into an ultrasonic instrument and ultrasonically 10min to make the solution evenly dispersed, and then transfer the dispersion to In a polytetrafluoroethylene tube, place it in an oven and react at 60°C for 1 hour to obtain graphene fibers;

[0031] (3) the graphene fiber of step (2) gained is dried at room temperature 30min, then rolled on the foam, half soaked in the dopant solution polyethyleneimine aqueous solution, the concentrat...

Embodiment 2

[0039] A preparation method of a p-type and n-type interphase graphene thermoelectric fiber, comprising the following steps:

[0040] (1) graphite is prepared into graphene oxide dispersion liquid by modified Hummers method, wherein, the particle size of graphite is 200 orders, and the concentration of the graphene oxide dispersion liquid obtained is 6mg / ml;

[0041] (2) Take the above 2ml graphene oxide dispersion in a clean reagent bottle, add 0.06g of vitamin C to mix it, shake fully, put the reagent bottle into an ultrasonic instrument and ultrasonically 10min to make the solution evenly dispersed, and then transfer the dispersion to In a polytetrafluoroethylene tube, place it in an oven and react for 2 hours at 80°C to obtain graphene fibers;

[0042] (3) The graphene fiber obtained in step (2) is dried at room temperature for 30min, then rolled on the foam, and half of it is soaked in the dopant solution polyethoxyethyleneimine aqueous solution, and the concentration of ...

Embodiment 3

[0045] A preparation method of a p-type and n-type interphase graphene thermoelectric fiber, comprising the following steps:

[0046] (1) graphite is prepared into graphene oxide dispersion liquid by modified Hummers method, wherein, the particle size of graphite is 200 orders, and the concentration of the graphene oxide dispersion liquid obtained is 6mg / ml;

[0047] (2) Take the above 2ml graphene oxide dispersion in a clean reagent bottle, add 0.04g of vitamin C to mix it, shake it fully, put the reagent bottle into an ultrasonic instrument and ultrasonically for 10min to make the solution evenly dispersed, and then transfer the dispersion to In a polytetrafluoroethylene tube, place it in an oven and react for 1 hour at 80°C to obtain graphene fibers;

[0048](3) Dry the graphene fiber obtained in step (2) at room temperature for 30 minutes, then roll it on the foam, and half soak it in the dopant solution, the dopant solution is polyethyleneimine aqueous solution and polyet...

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Abstract

The invention discloses a preparing method of graphene thermoelectricity fibers with interphase types p and n, and belongs to the technical field of preparation of graphene fibers. The preparing method comprises the following steps of (1) preparing graphite into a graphene oxide dispersion liquid through chemical synthesis; (2) preparing the graphene oxide dispersion liquid into graphene fibers through chemical reduction; (3) preparing the graphene fibers with interphase types p and n into the thermoelectricity fibers interphase types p and n through doping. According to the preparing method,the graphene thermoelectricity fibers with good continuity of interphase types p and n can be obtained without the use of any binder, the graphene thermoelectricity fibers have good flexibility, continuity and mechanical performance, and application of the fibers in portable wearable equipment is facilitated; the method is simple in preparing process, a high temperature is not needed, the preparing cost is low, the preparing scale of the thermoelectricity fibers can be controlled according to actual production and living demands, and the preparing method has important significance in the development of the wearable electronic equipment.

Description

technical field [0001] The invention belongs to the technical field of graphene fiber preparation, in particular to a preparation method of p-type and n-type graphene thermoelectric fibers. Background technique [0002] In recent years, electronic products and smart textiles are developing towards wearable and miniaturized products. In the process, the demand for energy supply systems for portable electronic products is increasing. The current energy supply system mainly focuses on batteries, generators, and supercapacitors. However, batteries need to be replaced or recharged constantly, while traditional generators need to rely on mechanical motion to generate electricity, while supercapacitors have the disadvantages of low energy density, high price, and the need for repeated charging, so these energy supply systems are not suitable for tiny wearable electronic devices. Thermoelectric materials and wearable thermoelectric devices based on their assembly are very suitable...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M15/61D01F9/12D06M101/40
CPCD01F9/12D06M15/61D06M2101/40
Inventor 蒋丰兴徐景坤林元城刘聪聪刘佩佩刘京王晓东
Owner JIANGXI SCI & TECH NORMAL UNIV
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