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High-rigidity high-toughness low-density polypropylene composition and preparation method thereof

A low-density polypropylene and composition technology, which is applied in the field of high-rigidity, high-toughness, low-density polypropylene composition and its preparation, can solve the problems of extruder rupture density, design requirements, and high price, and achieves low raw material cost and high production cost. The effect of simple process, high rigidity and toughness

Inactive Publication Date: 2020-01-07
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the prior art, traditional mineral-filled modified polypropylene materials are widely used in interior and exterior parts of automobiles, such as traditional instrument panels, door panels, and pillars, which use PP+EPDM-T20 materials with a density of 1.04-1.07g / cm 3 , has become increasingly unable to meet the automotive industry's requirements for lightweight materials
The traditional method of reducing density is to reduce the content of filler minerals. Although this method can reduce the density of the material, the rigidity and strength of the material cannot meet the actual performance design requirements of the material.
[0005] The patent number is CN 106750948A, which discloses a low-density, high-rigidity polypropylene composite material and its preparation method. The high-rigidity and low-density polypropylene composite material is prepared by using homopolypropylene, chopped carbon fibers, glass beads, and toughening agents. , but because of its pressure resistance and other problems, the hollow glass microspheres will cause problems such as rupture in the extruder, which will affect the density reduction effect. In addition, the high prices of glass microspheres and chopped carbon fibers will affect their popularization and use.

Method used

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  • High-rigidity high-toughness low-density polypropylene composition and preparation method thereof
  • High-rigidity high-toughness low-density polypropylene composition and preparation method thereof
  • High-rigidity high-toughness low-density polypropylene composition and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Take the raw materials by weighing the components and proportioning ratio (parts by weight) in Table 1

[0032] The raw materials were mixed in a high-speed mixer for 5 minutes and mixed evenly, and the mixed blend was extruded and granulated through a twin-screw extruder to obtain a composition. The temperature of each zone of the extruder from the feeding section to the head temperature was 150°C, 170°C, 175°C, 175°C, 175°C, 180°C, 180°C, 180°C, 180°C, 185°C, the length-to-diameter ratio of the extrusion screw is 40, and the rotation speed of the extrusion screw is 350 rpm. The prepared mixture was subjected to a performance test, and the test results are shown in Table 2.

Embodiment 2

[0034] Take the raw materials by weighing the components and proportioning ratio (parts by weight) in Table 1

[0035] Mix each raw material in a high-speed mixer for 10 minutes to mix evenly, extrude the mixed blend through a twin-screw extruder to obtain a composition, and the temperature of each zone of the extruder from the feeding section to the head temperature is sequentially 170°C, 185°C, 185°C, 185°C, 185°C, 190°C, 195°C, 195°C, 195°C, 200°C, the length-to-diameter ratio of the extrusion screw is 36, and the rotation speed of the extrusion screw is 350 rpm. The prepared mixture was subjected to a performance test, and the test results are shown in Table 2.

Embodiment 3

[0037] Take the raw materials by weighing the components and proportioning ratio (parts by weight) in Table 1

[0038] Mix each raw material in a high-speed mixer for 15 minutes and mix evenly. The mixed blend is extruded and granulated by a twin-screw extruder to obtain a composition. The temperature of each zone of the extruder is from the feeding section to the head temperature. 150°C, 170°C, 175°C, 175°C, 175°C, 180°C, 180°C, 180°C, 180°C, 195°C, the length-to-diameter ratio of the extrusion screw is 40, and the rotation speed of the extrusion screw is 350 rpm. The prepared mixture was subjected to a performance test, and the test results are shown in Table 2.

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Abstract

The invention discloses a high-rigidity, high-toughness and low-density polypropylene composition and a preparation method thereof. The high-rigidity, high-toughness and low-density polypropylene composition is prepared from 71-78 parts by weight of polypropylene, 8-12 parts by weight of whiskers, 14-17 parts by weight of a toughening agent, 0.2-0.5 part by weight of an antioxidant and 0.2-0.5 part by weight of other assistants through mixing, extrusion and granulation. According to the preparation method of the high-rigidity, high-toughness and low-density polypropylene composition, high-crystallinity co-polypropylene is used as a base material; whisker with a certain length-diameter ratio is used for enhancing modification; it is ensured that the prepared composition has high strength; meanwhile, the impact strength of the composition is improved with the toughening agent with a high melt index; the prepared polypropylene has high rigidity and high toughness, and the addition amountof the whiskers is only 8-12%, so that the density of the product is controlled at 0.96 g / cm<3> and is 8-10% lower than the density of the conventional PP+EPDM-T20, the lightweight purpose is achieved; the polypropylene composition disclosed by the invention is simple in preparation process, simple and convenient to operate and relatively low in raw material cost.

Description

technical field [0001] The invention relates to the field of polymer material modification, in particular to a high-rigidity, high-toughness, low-density polypropylene composition and a preparation method thereof. Background technique [0002] Polypropylene has the advantages of good mechanical properties, non-toxicity, low relative density, heat resistance, chemical resistance, easy processing and molding, and low price. Through processing and modification, it can endow the resin with outstanding physical and mechanical properties, and thus replace some engineering plastics. In recent years, great progress has been made in the engineering of general-purpose plastics, and it is the fastest growing among the five general-purpose synthetic resins. The most active variety in the development of new varieties. [0003] With the rapid development of science and technology, the major OEMs in the automobile industry have new changes in the requirements for materials, especially in ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/14C08L23/08C08K7/08
CPCC08L23/14
Inventor 杨桂生廖雄兵朱敏姚晨光计娉婷赵鑫
Owner HEFEI GENIUS NEW MATERIALS
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