Fused ring organic compound and application thereof
A technology of organic compounds and fused rings, which is applied in the field of organic electroluminescence to achieve excellent device performance, improve efficiency and lifespan
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[0237] The thickness of a functional layer formed by the above-mentioned preparation method is 5 nm-1000 nm.
[0238] The present invention also relates to the application of the above-mentioned fused-ring organic compound or mixture in organic electronic devices.
[0239] The present invention further relates to an organic electronic device comprising a fused-ring organic compound or polymer or mixture as described above.
[0240] The organic electronic device can be selected from, but not limited to, organic light emitting diodes (OLED), organic photovoltaic cells (OPV), organic light emitting cells (OLEEC), organic field effect transistors (OFET), organic light emitting field effect transistors, organic Lasers, organic spintronic devices, organic sensors and organic plasmon emission diodes (Organic Plasmon Emitting Diode), etc., particularly preferably organic electroluminescent devices, such as OLED, OLEEC, organic light emitting field effect tubes.
[0241] In some particularly p...
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[0256] 1. Synthesis of compounds
[0257]
[0258] Comp-1 and Comp-2 synthesis:
[0259]
[0260] Synthesis Example 1
[0261] Synthesis of Intermediate 2: Compound 1 (15g, 61mmol), o-nitrophenylboronic acid 1 (10.7g, 64mmol), potassium carbonate 1 (25g, 180mmol), tetrakis (triphenylphosphine) palladium (2.1g, 1.8 mmol) was dissolved in a mixed solution of about 200 mL of toluene and 90 mL of water, replaced with nitrogen, and refluxed for 24 h. After the reaction solution was cooled to room temperature, the organic layer was separated and extracted with ethyl acetate. The organic layer was mixed and dried over anhydrous sodium sulfate. After concentration, it was separated by a chromatography column to obtain a yellow solid with a yield of 70%.
[0262] Synthesis of Intermediate 3: Compound 2 (10 g, 7.8 mmol) was placed in 70 mL of triethyl phosphite and stirred at 170°C. After the reaction is complete, the solvent is removed under reduced pressure, and a light yellow solid is obta...
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