Method for measuring content of ferulylphenethylamine in C. f r u t e s c e n s, and quality detection method
A technology of feruloyl phenethylamine and feruloyl p-hydroxyphenylethylamine, which is applied in the field of chromatographic detection, can solve the problems affecting the safety of clinical medication of jiu feng, the development and utilization of jiu feng, and the complexity of components, and achieves good results. Specificity, fast speed, good effect
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Embodiment 1
[0046] 1. Obtain the linear equation of N-trans-feruloyl p-hydroxyphenethylamine reference substance
[0047] S1. Take 0.2, 0.4, 0.8, 1.6, and 2.4 mL of N-trans-feruloyl p-hydroxyphenethylamine reference substance solution with a mass concentration of 1.0 mg / mL, place them in 10 mL volumetric flasks, and add methanol The solution was dissolved and diluted to the mark and shaken evenly to obtain N-trans-feruloyl p-hydroxyphenethylamine reference substance solutions with different concentrations.
[0048] S2, carry out chromatographic analysis to the N-trans feruloyl p-hydroxyphenylethylamine reference substance solution of different concentrations respectively, and record the chromatogram of the N-trans feruloyl p-hydroxyphenethylamine reference substance solution of different concentrations obtained Peak area. Chromatographic conditions: chromatographic column: 4.6×250mm, 5μm particle size, Agilent TC-C18 chromatographic column; detection wavelength: 317nm; injection volume: ...
Embodiment 2
[0061] One, investigate the specificity of the chromatographic conditions in embodiment 1
[0062] Accurately draw N-trans-feruloyl p-hydroxyphenethylamine reference substance solution, test solution, and negative control solution respectively 10 μ L, inject liquid chromatograph, use the chromatographic conditions in the embodiment 1 to carry out chromatographic analysis, the results are shown in Figure 5-7 As shown, the results show that: N-trans-feruloyl p-hydroxyphenethylamine in the nine-layer wind test product is consistent with the retention time of the N-trans-feruloyl p-hydroxyphenethylamine reference substance chromatographic peak, and coexists with other Component separation degree is 1.58 (greater than 1.5), and theoretical plate number is 7798 (greater than 3000), and main peak and impurity peak reach baseline separation, and negative control sample does not have chromatographic peak interference at corresponding position, illustrates that in the nine-layer wind of...
Embodiment 3
[0092] 1. Obtain the linear equation of N-trans-feruloyl-5'-methoxy-6'-hydroxyphenethylamine reference substance
[0093] S1. Take 0.2, 0.4, 0.8 and 1.6 mL of N-trans-feruloyl-5'-methoxy-6'-hydroxyphenethylamine reference substance solution with a mass concentration of 1.0 mg / mL, and put them in In a 10mL volumetric flask, add methanol solution to dissolve and dilute to the mark and shake well to obtain different concentrations of N-trans-feruloyl-5'-methoxy-6'-hydroxyphenethylamine reference substance solutions.
[0094] S2. Perform chromatographic analysis on different concentrations of N-trans-feruloyl-5'-methoxy-6'-hydroxyphenethylamine reference solution respectively, and record the obtained N-trans-feruloyl in different concentrations -The chromatographic peak area of the 5'-methoxy-6'-hydroxyphenethylamine reference substance solution. Chromatographic conditions: chromatographic column: 4.6×250mm, 5μm particle size, Agilent TC-C18 chromatographic column; detection wave...
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