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Graphene-containing wear-resistant rubber and plastic foam shoe material and preparation method thereof

A rubber and plastic foaming and graphene technology, applied in the field of rubber and plastic foaming materials, can solve the problems of easy hardening and poor wear resistance

Inactive Publication Date: 2020-01-24
CHENDU NEW KELI CHEM SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] Aiming at the problems that the current EVA-based shoe material is easy to harden at low temperature and has poor wear resistance, the present invention proposes a preparation method of graphene wear-resistant rubber-plastic foamed shoe material

Method used

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  • Graphene-containing wear-resistant rubber and plastic foam shoe material and preparation method thereof
  • Graphene-containing wear-resistant rubber and plastic foam shoe material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] (1) Mix 500g of graphene and 100g of aluminum powder evenly to obtain a mixed powder, then smelt and mix the mixed powder at a high temperature of 660°C under the protection of argon, and then spray the mixed powder with a spray Machine spraying to obtain flake nano-scale graphene / aluminum powder below 100nm;

[0038] (2) Mix 10kg of polycarbonate diol with 5Kg of 4,4'-diphenylmethane diisocyanate and 40g of stannous octoate, and then add 0.5kg of flake nano-scale graphene / aluminum powder prepared in step (1) and 100g of sodium hexametaphosphate dispersant, stirred and reacted at 80-90°C to obtain a graphene / aluminum-containing polycarbonate polyurethane elastomer;

[0039] (3) Combine 8Kg of graphene / aluminum-containing polycarbonate polyurethane elastomer obtained in step (2) with 80kg of EVA, 8Kg of NR rubber, 5kg of calcium carbonate inorganic filler, 1.5Kg of stearic acid lubricant, 2.5Kg of sulfur, and 0.3Kg of AC Foaming agent, 0.9Kg4.4'-bis(α.α-dimethylbenzyl) ...

Embodiment 2

[0042] (1) Mix 500g of graphene and 100g of aluminum powder evenly to obtain a mixed powder, then smelt and mix the mixed powder at a high temperature of 670°C under the protection of argon, and then spray the mixed powder with a spray Machine spraying to obtain flake nano-scale graphene / aluminum powder below 100nm;

[0043] (2) Mix 10kg of polycarbonate diol with 5Kg of 4,4'-diphenylmethane diisocyanate and 40g of stannous octoate, and then add 0.8kg of flake nanoscale graphene / aluminum powder prepared in step (1) and 100g of sodium hexametaphosphate dispersant, stirred and reacted at 90-100°C to obtain a polycarbonate polyurethane elastomer containing graphene / aluminum;

[0044] (3) Combine 12Kg of graphene / aluminum-containing polycarbonate polyurethane elastomer obtained in step (2) with 90kgEVA, 9KgNR rubber, 5kg calcium carbonate inorganic filler, 1.5Kg stearic acid lubricant, 2.5Kg sulfur, 0.3KgAC Foaming agent, 0.9Kg4.4'-bis(α.α-dimethylbenzyl) diphenylamine anti-aging...

Embodiment 3

[0047] (1) Mix 500g graphene and 100g aluminum powder evenly to obtain a mixed powder, then melt the mixed powder at a high temperature of 680°C under the protection of argon and mix evenly, and then spray the mixed powder evenly after high-temperature melting and mixing Machine spraying to obtain flake nano-scale graphene / aluminum powder below 100nm;

[0048] (2) Mix 10kg of polycarbonate diol with 5Kg of 4,4'-diphenylmethane diisocyanate and 40g of stannous octoate, and then add 1.0kg of flake nano-scale graphene / aluminum powder prepared in step (1) and 100g of sodium hexametaphosphate dispersant, stirred and reacted at 90~95°C to obtain a polycarbonate polyurethane elastomer containing graphene / aluminum;

[0049] (3) Combine 12Kg of graphene / aluminum-containing polycarbonate polyurethane elastomer obtained in step (2) with 100kgEVA, 10KgNR rubber, 5kg calcium carbonate inorganic filler, 1.5Kg stearic acid lubricant, 2.5Kg sulfur, 0.3KgAC Foaming agent, 0.9Kg4.4'-bis(α.α-di...

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Abstract

The invention relates to the field of rubber and plastic foam materials, and concretely relates to a wear-resistant rubber and plastic foam shoe material and a preparation method thereof. The preparation method comprises the following steps: graphene and aluminum powder are mixed according to a mass ratio of 5:1, and the obtained mixture is smelted and mixed evenly at a high temperature of 660-680DEG C, and then is sprayed to obtain flaky nanoscale graphene / aluminum powder; polycarbonate diol is uniformly mixed with 4,4'-diphenylmethane diisocyanate and stannous octoate, then graphene / aluminum powder and sodium hexametaphosphate are added, and the obtained mixture is stirred and reacted at 80-100 DEG C so as to obtain a polyurethane elastomer; the polyurethane elastomer is mixed with EVA,NR rubber, an inorganic filler, a lubricant, sulfur, an AC foaming agent and an anti-aging agent in an internal mixer at 90-100 DEG C for 4-6 min, and then a sheet is discharged; and the sheet is cut, is implanted in a mold pressing machine and is foamed at 170-200 DEG C for 180-240 s to obtain the graphene-containing wear-resistant rubber and plastic foam shoe material. The shoe material has good low-temperature wear resistance.

Description

technical field [0001] The invention relates to the field of rubber and plastic foam materials, in particular to a wear-resistant rubber and plastic foam shoe material and a preparation method, in particular to a low-temperature wear-resistant ethylene-vinyl acetate copolymer foam shoe material and a preparation method. Background technique [0002] Foaming materials are obtained by adding catalysts, foam stabilizers, foaming agents and other auxiliary materials to plastics and other raw materials, and through physical foaming or cross-linking foaming, a large number of fine foams appear in plastics and other raw materials. The volume of plastic and other raw materials increases after foaming, and the density decreases, and the obtained foamed material has functions such as cushioning, shock absorption, and heat preservation. Ethylene-vinyl acetate copolymer (EVA) foaming material has excellent flexibility, elasticity and chemical corrosion resistance, and is gradually accep...

Claims

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Application Information

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IPC IPC(8): C08J9/10C08L23/08C08L75/04C08L7/00C08K13/06C08K9/12C08K3/08C08K3/04A43B1/10A43B13/04
CPCA43B1/10A43B13/04C08J9/0061C08J9/0066C08J9/009C08J9/0095C08J9/103C08J2203/04C08J2323/08C08J2407/00C08J2475/04
Inventor 陈庆昝航曾军堂
Owner CHENDU NEW KELI CHEM SCI CO LTD
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