Master batch capable of adjusting melt index of PE and preparation method thereof

A melt index and masterbatch technology, which is applied in the field of PE melt index adjustment masterbatch and its preparation, can solve the problems of inability to effectively adjust the melt index of PE materials, poor adaptability of melt index regulators, increase product costs, etc., and meet the temperature requirements The effect of low cost, simple preparation method and large application range

Active Publication Date: 2020-02-11
广讯检测(广东)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of the deficiencies of the above-mentioned prior art, the object of the present invention is to provide a PE melt index adjusting masterbatch and its preparation method, aiming at solving the problem that existing melt index adjusters cannot effectively adjust the melt index of PE material, so that in In the production process, it is easy to cause stacking and self-flowing phenomenon, which increases the cost of the product, and the problem of poor adaptability of the existing melt index regulator

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] A preferred masterbatch for adjusting PE melt index, said masterbatch includes: 10 parts of EVA resin, 50 parts of 1,4-bis-tert-butylperoxycumene, polyethylene grafted maleate 12.5 parts of acid anhydride, 22.5 parts of calcium carbonate, 5 parts of 95 degree Fischer-Tropsch wax, 0.1 part of surfactant.

[0043] The preparation method of the above-mentioned PE melt index adjustment masterbatch comprises the steps of:

[0044] Step S1. Take calcium carbonate and surfactant according to the proportion, stir and mix to obtain modified calcium carbonate;

[0045] Step S2. Take EVA resin, 1,4-bis-tert-butylperoxycumene, polyethylene-grafted maleic anhydride, 95-degree Fischer-Tropsch wax and modified calcium carbonate according to the proportion, stir and mix at a high speed, got the mixture;

[0046] Step S3. The mixture is granulated by a granulator to obtain a masterbatch for adjusting the PE melt index.

Embodiment 2

[0048] A masterbatch for adjusting PE melt index, said masterbatch includes in parts by weight: 8 parts of EVA resin, 45 parts of 1,4-bis-tert-butylperoxycumene, 15 parts of polyethylene grafted maleic anhydride part, 20 parts of talcum powder, 4 parts of 95 degree Fischer-Tropsch wax, 0.1 part of surfactant.

[0049] Its preparation method is identical with embodiment 1.

Embodiment 3

[0051] A masterbatch for adjusting PE melt index, said masterbatch includes in parts by weight: 12 parts of EVA resin, 55 parts of 1,4-bis-tert-butylperoxycumene, 10 parts of polyethylene grafted maleic anhydride part, 25 parts of mica powder, 6 parts of 95 degree Fischer-Tropsch wax, 0.2 part of surfactant.

[0052] Its preparation method is identical with embodiment 1.

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Abstract

The invention discloses a master batch capable of adjusting the melt index of PE and a preparation method thereof. The master batch comprises the following components in parts by weight: 8 to 12 partsof EVA resin, 45 to 55 parts of 1,4-bis (tert-butylperoxy)isopropyl benzene, 10 to 15 parts of polyethylene grafted maleic anhydride, 20 to 25 parts of an inorganic dispersing agent, 4 to 6 parts ofFischer-Tropsch wax and 0.1 to 0.2 part of a surfactant. The preparation method comprises the following steps: modification of the inorganic dispersing agent; mixing of all the material components ata high speed; and granulating. According to the invention, the master batch has an excellent melt index adjusting function, can effectively reduce the melt index of a PE material, avoids the phenomenaof extrusion stacking and formation of a large-caliber PE pipe with a thick upper part and a thin lower part caused by self-flowing drooping due to a too high melt index, is free of the phenomenon ofexcessive crosslinking, allows a product to maintain thermoplasticity, and has good applicability and a wide application range; and the preparation method is simple in process, free of heating and easy to implement.

Description

technical field [0001] The invention relates to the technical field of plastic processing and modification, in particular to a masterbatch for adjusting PE melt index and a preparation method thereof. Background technique [0002] The melt index of PE material is a value that reflects its processing fluidity. The higher the melt index, the better its processing fluidity, and vice versa. Usually, in PE pipe extrusion process, PE industrial blue and white barrel production process, HDPE hollow type blow molding, HDPE film, HDPE wire drawing process, the melt index is required to be controlled in a suitable range, such as PE solid wall pipe (water supply pipe ), the melt index is required to be between 0.2-0.25g / 10min (190°C, 5kg), while the bellows is required to be controlled at 0.8-1.0±0.1g / 10min (190°C, 5kg). When the melt index is too low, then Difficult to process, but the melt index is too high, prone to stacking, resulting in increased weight and cost, especially for l...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/08C08L51/06C08L91/06C08K5/14C08K3/26C08K3/34C08J3/22
CPCC08J3/226C08J2323/06C08J2423/08C08J2451/06C08J2491/06C08K5/14C08K2003/265C08K3/34C08K3/346
Inventor 黄永忠刘继武徐风飞黄俊
Owner 广讯检测(广东)有限公司
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