Acrylamide particle hydrogel fire extinguishing agent

A technology of acrylamide and hydrogel, which is applied in the direction of fire prevention equipment, etc., can solve the problems of unfavorable fire extinguishing application, high preparation cost, low dissolution rate, etc., and achieve the effect of preventing fire from spreading and expanding, reducing fire loss, and simple preparation method

Inactive Publication Date: 2020-02-21
JIANGXI SCI & TECH NORMAL UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] (1) Low dissolution rate
Most hydrogel fire extinguishing additives have a low dissolution rate in water, and some even need to be stirred to achieve a solution, which may lose the best time to extinguish the fire and cause more serious disasters;
[0006] (2) poor adhesion
When polymer additives are added to a large amount of water, the formed hydrogel particles have poor adhesion and strong fluidity, similar to water, and cannot effectively adhere to the fire point, and cannot play the role of fire extinguishing and fire resistance, and cannot achieve effective fire extinguishing ;
[0007] (3) Low water retention rate
The currently developed hydrogel fire extinguishing particles have relatively strict water quality requirements in the actual application process, and the metal ions and organic pollutants in the water will have a greater impact on the quality of the hydrogel, which is not conducive to the actual fire extinguishing application;
[0009] (5) poor mechanical properties
Some of the existing hydrogel fire extinguishing granule products are mostly used to spray on the surface of the burning material and become granular. The formed hydrogel isolation layer has poor mechanical properties and is easy to be destroyed in the continuous spraying process, resulting in heat insulation, fire extinguishing and fire resistance. The burning effect is greatly reduced, and even re-ignition occurs;
[0010] (6) It is easy to cause device blockage
The "hydrogel" added in the fire extinguishing process is mostly granular and has a solid nature. It is easy to cause blockage of the device when sprayed through the existing standard fire extinguishing device, and it is difficult to promote it in actual fire extinguishing applications;
[0011] (7) Higher cost
A variety of hydrogel fire extinguishing additives currently developed are mainly water-soluble polymers. In addition, the addition of additives such as tackifiers and adhesion promoters will inevitably increase the preparation cost.

Method used

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  • Acrylamide particle hydrogel fire extinguishing agent
  • Acrylamide particle hydrogel fire extinguishing agent
  • Acrylamide particle hydrogel fire extinguishing agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] An acrylamide granular hydrogel fire extinguishing agent, prepared from the following raw material components: A. Acrylamide, B. Crosslinking agent: N, N'-methylenebisacrylamide, C. Initiator: over Ammonium sulfate, D. catalyst: tetramethylethylenediamine, E. water;

[0042] Its preparation method comprises the following steps:

[0043] (1) Add component A to deionized water to obtain solution I, the mass fraction of A in solution I is 10wt%;

[0044] (2) B component, C component and D component are added in the above-mentioned solution I respectively, obtain solution II, the mass fraction of B in solution II is 0.002wt%, the mass fraction of C is 0.0015wt%, the mass fraction of D The mass fraction is 0.0002wt%;

[0045](3) Polymerize the above solution II under certain conditions, the reaction temperature is 50-70°C, the time is 1-2 hours, and then dried at 80-100°C to obtain a dry gel;

[0046] (4) disperse the above-mentioned dried gel into particles with a diamet...

Embodiment 2

[0049] An acrylamide granular hydrogel fire extinguishing agent, prepared from the following raw material components: A. Acrylamide, B. Crosslinking agent: N, N'-methylenebismethacrylamide, C. Initiator : Potassium persulfate, D. Catalyst: N, N-dimethyl-1,3-propanediamine, E. water;

[0050] Its preparation method comprises the following steps:

[0051] (1) Add component A to deionized water to obtain solution I, the mass fraction of A in solution I is 20wt%;

[0052] (2) B component, C component and D component are added in the above-mentioned solution I respectively, obtain solution II, the mass fraction of B in the solution II is 0.0002wt%, the mass fraction of C is 0.0002wt%, the mass fraction of D is The mass fraction is 0.0001wt%;

[0053] (3) Polymerize the above solution II under certain conditions, the reaction temperature is 50-70°C, the time is 1-2 hours, and then dried at 80-100°C to obtain a dry gel;

[0054] (4) disperse the above-mentioned dried gel into part...

Embodiment 3

[0057] An acrylamide granular hydrogel fire extinguishing agent, prepared from the following raw material components: A. Acrylamide, B. Crosslinking agent: N, N'-methylenebismethacrylamide, C. Initiator : Sodium Persulfate, D. Catalyst: Tetramethylethylenediamine, E. Water;

[0058] Its preparation method comprises the following steps:

[0059] (1) Add component A to tap water to obtain solution I, and the mass fraction of A in solution I is 15wt%;

[0060] (2) B component, C component and D component are added in the above-mentioned solution I respectively, obtain solution II, the mass fraction of B in solution II is 0.0011wt%, the mass fraction of C is 0.0009wt%, the mass fraction of D The mass fraction is 0.00015wt%;

[0061] (3) Polymerize the above solution II under certain conditions, the reaction temperature is 50-70°C, the time is 1-2 hours, and then dried at 80-100°C to obtain a dry gel;

[0062] (4) disperse the above-mentioned dried gel into particles with a diam...

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Abstract

The invention discloses an acrylamide particle hydrogel fire extinguishing agent, and belongs to the technical field of fire extinguishing agent production. The hydrogel fire extinguishing agent is prepared from acrylamide, a cross-linking agent, an initiator, a catalyst and water; the cross-linking agent is any one of N,N'-methylenebisacrylamide and N,N'-methylenebismethacrylamide; the initiatoris any one of ammonium persulfate, potassium persulfate and sodium persulfate; and the catalyst is any one of tetramethylethylenediamine and N,N-dimethyl-1,3-propanediamine. The prepared hydrogel fireextinguishing agent has the advantages of good solubility, suitableness for various water qualities, cheap production raw materials, high water-retaining property, high adhesion and high mechanical properties, and can be simply and conveniently operated in practical application.

Description

technical field [0001] The invention belongs to the technical field of fire extinguishing agent production, and in particular relates to an acrylamide granular hydrogel fire extinguishing agent. Background technique [0002] The fire is sudden, the fire extinguishing process is complicated, and the consequences are serious, posing a high threat to the safety of people's lives and property, economic development and social stability. Reasonable selection of fire extinguishing agents and fire extinguishing methods can greatly reduce casualties, property losses and ecological resource damage caused by fire. At present, the most important fire extinguishing materials are water-based and a series of chemical reagent fire extinguishing agents. Water has a high specific heat capacity and is widely used in fire fighting. However, water has strong fluidity and is difficult to adhere to the surface of burning objects. Moreover, it is easy to evaporate at high temperature, which has ca...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/56C08F222/38A62D1/00
CPCA62D1/0064C08F220/56C08F222/385
Inventor 卢宝阳薛羽徐景坤张凯朱秀凯渐南南
Owner JIANGXI SCI & TECH NORMAL UNIV
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