Preparation method of flame-retardant UV-moisture dual-curing polyurethane acrylate conformal coating

A polyurethane acrylate, dual-curing technology, used in polyurea/polyurethane coatings, anti-corrosion coatings, fire-resistant coatings, etc., can solve the problems of flammable and explosive solvents, induced occupational diseases, irritation, etc., and achieve excellent electrical insulation performance, excellent resistance. The effect of burning characteristics and fast curing speed

Active Publication Date: 2020-03-17
SHENZHEN NEWOLL NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main problems of solvent-based polyurethane conformal coatings are: 1) Some solvents volatilize into the air, which will cause irritation, and long-term exposure may induce occupational diseases; 2) Some solvents have a strong pungent smell, which affects the working environment and reduces work efficiency; 3 ) Some solvents are toxic and harmful solvents, which will pollute the environment. Environmental protection policy requirements are becoming more and more stringent, and they are facing policy pressure; 4) Some solvents are flammable and explosive, and there are great safety hazards in the process of production, transportation, and storage
However, ultraviolet light is a necessary condition for UV curing. When ultraviolet light is blocked and cannot penetrate the conformal coating, these conformal coatings will remain unreacted and uncured, causing the phenomenon that the shadow area of ​​the circuit board is not dry. At the same time, Unreacted and uncured wet conformal coating may chemically migrate to adjacent cured areas, thereby weakening the performance of the cured area conformal coating over time, increasing the reliability risk of the circuit board

Method used

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  • Preparation method of flame-retardant UV-moisture dual-curing polyurethane acrylate conformal coating
  • Preparation method of flame-retardant UV-moisture dual-curing polyurethane acrylate conformal coating
  • Preparation method of flame-retardant UV-moisture dual-curing polyurethane acrylate conformal coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0066] Table 1 lists six composition examples of the preparation method of the flame-retardant UV-moisture dual-curing polyurethane acrylate conformal paint of the present invention. Among them, PUA1 is a polyurethane acrylate prepolymer containing allyl groups at both ends; PUA2 is a polyurethane acrylate prepolymer containing phosphate compounds containing allyl groups at both ends; PUA3 is a polyurethane acrylate prepolymer containing allyl groups at both ends. PUA4 is a polyurethane acrylate prepolymer containing an isocyanate group at one end and an allyl group at one end; PUA5 is a polyurethane acrylate prepolymer containing an isocyanate group at one end and an allyl group at one end. PUA6 is a polyurethane acrylate prepolymer containing polyolefin groups containing isocyanate groups at one end and allyl groups at one end.

[0067]

[0068]

[0069] Table 1 Preparation method of flame-retardant UV-moisture dual-curing polyurethane acrylate conformal paint

[0070...

Embodiment 2

[0072] Table 2 is the performance test results of the preparation method of the flame-retardant UV-moisture dual-curing polyurethane acrylate conformal paint corresponding to Table 1.

[0073]

[0074] Table 2 Performance test results of the preparation method of flame-retardant UV-moisture dual-curing polyurethane acrylate conformal paint

Embodiment 3

[0076] A method for preparing a flame-retardant UV-moisture dual-curing polyurethane acrylate conformal paint of the present invention can be further cured by moisture in the shadow area of ​​a circuit board. In order to test the moisture curing performance, 500 micron films were prepared and placed under the conditions of 25°C, 50%RH. As shown in Table 3, the film cured on the third day.

[0077] Moisture cured 500 micron thick film at 25°C, 50% RH first day wet the next day wet third day solidified fourth day solidified

[0078] Table 3 moisture curing situation

[0079] From the above examples, it can be concluded that by using UV-moisture dual-curing urethane acrylate resin containing phosphate compounds as the base material, using a low-odor and low-irritation reactive diluent, together with a photoinitiator, to prepare a flame-retardant UV -The preparation method of moisture dual-curing polyurethane acrylate conformal paint, w...

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Abstract

The invention discloses a preparation method of flame-retardant UV-moisture dual-curing polyurethane acrylate conformal coating. The method comprises the steps of: taking UV-moisture dual-curing polyurethane acrylate resin containing a phosphate ester compound as a base material, and adopting a low-odor and low-irritation reactive diluents matched with a photoinitiator to prepare a flame-retardantUV-moisture dual-curing polyurethane acrylate conformal coating. The flame-retardant UV-moisture dual-curing polyurethane acrylate conformal coating does not contain a volatile organic solvent, has aflash point higher than 61 DEG C, has low odor, is a non-hazardous chemical three-proofing paint, and can be stored and transported according to conventional chemicals; a UV and moisture dual-curingmechanism is adopted, so that the curing speed is high, and the efficiency is high; and the coating film of the flame-retardant UV-moisture dual-curing polyurethane acrylate conformal coating has highwear resistance, high salt spray resistance, high damp-heat resistance, high acid and alkali resistance and an excellent electrical insulation performance, and can be widely applied to the high-corrosion-resistance fields of power supply frequency conversion, automotive electronics, industrial control, communication, household appliances, military industry and the like.

Description

technical field [0001] The invention relates to the field of conformal paint for circuit boards in the electronics industry, in particular to a method for preparing a flame-retardant UV-moisture dual-curing polyurethane acrylate conformal paint. Background technique [0002] Conformal paint is a special formula coating material, which can be widely used in the protection of electronic and electrical equipment circuit boards. Apply the conformal paint on the surface of the circuit board to form a transparent protective film, which can protect the circuit board from damage in the environment of humidity, mold, salt spray, chemical corrosion, high dust, vibration, etc., and improve the circuit quality. The reliability of the board increases the safety factor of the entire electronic component. In terms of chemical composition, conformal coatings can be divided into three main categories: silicone conformal coatings, acrylic conformal coatings and polyurethane conformal coating...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D5/18C09D5/08
CPCC08L2201/02C08L2205/025C08L2205/035C09D5/08C09D5/18C09D175/14C08L75/14
Inventor 朱伟
Owner SHENZHEN NEWOLL NEW MATERIAL CO LTD
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