Micron-nano plugging anti-sloughing drilling fluid, and preparation method and application thereof
A technology of plugging and anti-slumping, nano plugging agent, applied in the field of drilling fluid, can solve the problems of unsatisfactory plugging and anti-slumping effect, poor dispersion stability, easy agglomeration of drilling fluid, etc., to prevent hydraulic tipping and spalling effects, Improve the strength and maintain the stability of the well wall
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preparation example Construction
[0040] According to the present invention, the preparation method of described nano plugging agent comprises:
[0041] (1) The nano-carbon powder and nitric acid are heated to reflux and then cooled, centrifuged, washed and filtered to obtain sample S1;
[0042] (2) Mix the sample S1 with concentrated nitric acid and concentrated sulfuric acid, carry out the first ultrasonic wave, and then perform centrifugal separation and washing treatment to obtain the sample S2;
[0043] (3) In the presence of an antifoaming agent, the sample S2 is dissolved in a dispersant for the second ultrasonic treatment, water washing, centrifugation and drying to obtain a sample S3;
[0044] (4) Grinding the sample S3 to obtain a nano-blocking agent.
[0045] According to the present invention, the nano-blocking agent is a surface-modified nano-carbon powder, black spherical powder particles, an average particle diameter of 30-85nm, preferably 35.3-75.2nm, and a surface hydrophilic material; in the...
preparation example 1
[0073] This preparation example is to illustrate the preparation method of the nano-blocking agent (surface-modified nano-carbon powder) of the present invention.
[0074] Take 0.5 parts by weight of nano-carbon powder, add it to 100 parts by volume of nitric acid with a concentration of 2.4mol / L, heat to 40°C and reflux for 20h, and after cooling to room temperature, perform centrifugation three times at a speed of 4000r / min. Rinse with deionized water several times to neutrality and then filter with a microporous membrane to obtain sample A1;
[0075]Take 0.1 parts by weight of sample A1, add concentrated nitric acid and concentrated sulfuric acid with a total volume of 100mL in turn, wherein the volume ratio of concentrated sulfuric acid and concentrated nitric acid is 2.5:1, mix well and then ultrasonicate for 4h under 1000W power, at a speed of 4000r / min After three times of centrifugation and repeated washing with deionized water to neutrality, sample A2 was obtained;
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preparation example 2
[0079] This preparation example is to illustrate the preparation method of the nano plugging agent of the present invention.
[0080] Take 1.5 parts by weight of nano-carbon powder, add it to 100 parts by volume of nitric acid with a concentration of 2.6 mol / L, heat to 50°C and reflux for 24 hours, and after cooling to room temperature, perform centrifugation for 4 times at a speed of 5000r / min. After washing with deionized water several times to neutrality, filter with a microporous membrane to obtain sample B1.
[0081] Take 0.3 parts by weight of sample B1, add concentrated nitric acid and concentrated sulfuric acid with a total volume of 100mL in turn, wherein the volume ratio of concentrated sulfuric acid and concentrated nitric acid is 3:1, mix well, and ultrasonicate for 5 hours at a power of 1250W at a speed of 5000r / min Carry out 4 times of centrifugation, wash with deionized water several times to neutrality, and obtain sample B2;
[0082] Fully dissolve the sample ...
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