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Method for preparing microcrystalline glass ceramic composite bricks from waste glass

A technology for glass-ceramics and waste glass, applied in glass manufacturing equipment, glass molding, manufacturing tools, etc., can solve the problems of high sales price, low qualified rate of finished products, high production cost, and achieve uniform and dense overall structure. , excellent mechanical properties, the effect of improving melting properties

Inactive Publication Date: 2020-04-17
安徽锵信网络科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the current production process, there are problems such as low qualified rate of finished products, etc., resulting in high production costs and poor toughness, resulting in high sales prices, thus affecting its application.

Method used

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  • Method for preparing microcrystalline glass ceramic composite bricks from waste glass

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A method for preparing glass-ceramic composite bricks by using waste glass:

[0030]The iron tailings are subjected to wet ball milling. During ball milling, the weight ratio of balls:iron tailings:hydrogen peroxide:water is 85:22:3:50, ground to a particle size of 0.05-0.1mm, and dried at 60°C to obtain iron The tailings powder is ready for use, and the waste glass is crushed and ball-milled to a particle size of 1-5 μm to obtain the waste glass powder, and the iron tailings powder, waste glass powder, soda ash, titanium dioxide, zirconium dioxide, calcium fluoride, and three Chromium oxide is mixed with a crystal nucleating agent composed of a mass ratio of 45:8:5:1 and placed on a planetary ball mill to grind and mix for 10 hours to obtain a mixture. The weight ratio of iron tailings powder, waste glass powder, soda ash, and crystal nucleating agent The ratio is 8:35:2:1, put the mixture into the crucible, place it in a silicon-molybdenum rod high-temperature lifting...

Embodiment 2

[0032] A method for preparing glass-ceramic composite bricks by using waste glass:

[0033] The iron tailings are subjected to wet ball milling. During ball milling, the weight ratio of balls:iron tailings:hydrogen peroxide:water is 100:20:3:58, ground to a particle size of 0.05-0.1mm, and dried at 50°C to obtain iron The tailings powder is ready for use, and the waste glass is crushed and ball-milled to a particle size of 1-5 μm to obtain the waste glass powder, and the iron tailings powder, waste glass powder, soda ash, titanium dioxide, zirconium dioxide, calcium fluoride, and three Chromium oxide is mixed with a crystal nucleating agent composed of a mass ratio of 48:7:10:1 and placed on a planetary ball mill to grind and mix for 11 hours to obtain a mixture. The weight ratio of iron tailings powder, waste glass powder, soda ash, and crystal nucleating agent The ratio is 8:35:1:1, put the mixture into the crucible, place it in a silicon-molybdenum rod high-temperature lift...

Embodiment 3

[0035] A method for preparing glass-ceramic composite bricks by using waste glass:

[0036] The iron tailings are subjected to wet ball milling. During ball milling, the weight ratio of balls:iron tailings:hydrogen peroxide:water is 90:25:3:55, ground to a particle size of 0.05-0.1mm, and dried at 60°C to obtain iron The tailings powder is ready for use, and the waste glass is crushed and ball-milled to a particle size of 1-5 μm to obtain the waste glass powder, and the iron tailings powder, waste glass powder, soda ash, titanium dioxide, zirconium dioxide, calcium fluoride, and three Chromium oxide is mixed with a crystal nucleating agent composed of a mass ratio of 42:8:7:1 and placed on a planetary ball mill for grinding and mixing for 12 hours to obtain a mixture. The weight ratio of iron tailings powder, waste glass powder, soda ash, and crystal nucleating agent The ratio is 6:35:2:1, put the mixture into the crucible, put it in a silicon-molybdenum rod high-temperature l...

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Abstract

The invention provides a method for preparing a microcrystalline glass ceramic composite bricks from waste glass, and relates to the field of building materials. The method comprises the following steps: preparing microcrystalline glass sheets; preparing nano ceramic sheets; preparing a middle layer powder; sequentially introducing the microcrystalline glass sheet, the middle layer powder, the nano ceramic sheet, the middle layer powder and the microcrystalline glass sheet into a mould, carrying out hot-pressing lamination in a hot-pressing furnace, wherein firstly, carrying out hot pressing at 800 to 850 DEG C and 6 to 8MPa for 5 to 10min, then carrying out hot pressing at 1180 to 1200 DEG C and 15 to 18MPa for 20 to 30min, and then carrying out pressure relieving, cooling, discharging, and demoulding to obtain the composite bricks. The microcrystalline glass ceramic composite bricks disclosed by the invention are excellent in various mechanical properties, good in chemical stability,high in surface gloss, and possesses wear resistance and frost resistance.

Description

technical field [0001] The invention relates to the field of building materials, in particular to a method for preparing a glass-ceramic composite brick by using waste glass. Background technique [0002] Glass-ceramic is also called microcrystalline jade or ceramic glass. It is an inorganic non-metallic material. It is synthetic glass, which is a new type of building material just developed by foreign countries. Its scientific name is glass crystal. Glass-ceramic looks very different from our usual glass. It has the dual characteristics of glass and ceramics. The atomic arrangement inside ordinary glass is irregular, which is one of the reasons why glass is fragile. Glass-ceramics, like ceramics, is composed of crystals, that is to say, its atomic arrangement is regular, so glass-ceramics has higher brightness than ceramics. [0003] Glass-ceramic composite board is also called composite micro-ceramic stone. Composite micro-ceramic stone is a new type of composite plate...

Claims

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Application Information

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IPC IPC(8): C03C10/00C03C6/02C03B19/02C03B32/02C04B35/14C04B35/622C03C14/00C04B37/04E04F13/075
CPCC03B19/02C03B32/02C03C10/0063C03C14/00C04B35/14C04B35/622C04B37/045C04B2235/3427C04B2235/3463C04B2235/442C04B2235/445C04B2235/447C04B2237/02E04F13/0875
Inventor 马成龙
Owner 安徽锵信网络科技有限公司
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