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Production method of low-sulfur marine fuel oil

A production method and fuel oil technology, applied in the petroleum industry, hydrocarbon oil treatment, hydrogenation process, etc., can solve the problems of unstable operation of the filter device, high liquid recovery loss, easy blockage of the filter, etc., and achieve long cycle operation, save production cost, and improve the effect of utilization value

Pending Publication Date: 2020-05-01
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The catalytic oil slurry obtained by catalytic cracking of heavy oil has the problems of high solid content and small particle size. When the catalytic oil slurry is treated by conventional filtration and other means, there will be high liquid yield loss, incomplete removal of catalyst powder, easy blockage of filter, and backwashing. Frequent and unstable operation of the filter device, therefore, most of the catalytic oil slurry can only be used as the feed of the coking unit at present, and at the same time, a large amount of low-value coke is produced by-product, and the value of the catalytic oil slurry cannot be fully utilized

Method used

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  • Production method of low-sulfur marine fuel oil

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Embodiment 1

[0047] Embodiment 1 uses catalytic oil slurry as a raw material, adopts the catalytic oil slurry treatment method of the present invention, and firstly mixes the catalytic oil slurry with the first auxiliary agent coal tar whole fraction, and the proportioning of the catalytic oil slurry and the first auxiliary agent is 17 : 1, the mixing treatment temperature and mixing treatment time of the catalytic oil slurry and the first auxiliary agent are 72°C and 1.2h respectively, remove part of the large particles, and then enter the hydrogenation pretreatment reactor together with the hydrogen for shallow hydrogenation Reaction to remove easily condensed coke substances, the reaction conditions of the hydrogenation pretreatment reactor are: reaction temperature 337°C, reaction pressure 6.5Mpa, volume space velocity 0.7h -1 , the volume ratio of hydrogen to oil is 600; then enter the hydrotreating reactor for deep depurification reaction, the reaction conditions of the hydrotreating ...

Embodiment 2

[0049] Embodiment 2 takes catalytic oil slurry as raw material, adopts the catalytic oil slurry processing method of the present invention, first catalytic oil slurry is mixed with the first auxiliary agent coal tar whole fraction and the second auxiliary agent tetrahydronaphthalene, and the catalytic oil slurry is mixed with the second auxiliary agent tetrahydronaphthalene. The ratio of the first auxiliary agent and the second auxiliary agent is 18:1 and 65:1 respectively, and the mixing treatment temperature and mixing treatment time of the catalytic oil slurry, the first auxiliary agent and the second auxiliary agent are 82°C and 1.5h respectively, Remove part of the large particles, and then enter the hydrotreating reactor together with hydrogen for deep impurity removal reaction. The reaction conditions of the hydrotreating reactor are: reaction temperature 389 ° C, reaction pressure 8.9Mpa, volume space velocity 1.2h -1 , The volume ratio of hydrogen to oil is 650, and th...

Embodiment 3

[0051] Embodiment 3 uses catalytic oil slurry as a raw material, adopts the catalytic oil slurry treatment method of the present invention, and mixes the catalytic oil slurry with the first auxiliary agent coal tar whole fraction, and the proportioning ratio of the catalytic oil slurry and the first auxiliary agent is respectively 21 : 1, the mixing treatment temperature and mixing treatment time of the catalytic oil slurry and the first auxiliary agent are respectively 87°C and 1.6h to remove part of the large particles, and then enter the hydrotreating reactor together with hydrogen for deep depurification reaction, The reaction conditions of the hydrotreating reactor are: reaction temperature 394°C, reaction pressure 9.3Mpa, volume space velocity 1.4h -1 , the volume ratio of hydrogen to oil is 700, and the hydrotreating reactor uses an ebullating bed reactor. The mixed system after the impurity removal reaction is respectively treated by the clarification unit and the forc...

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Abstract

The invention discloses a production method of a low-sulfur marine fuel oil. The production method comprises the following steps: mixing catalytic slurry oil with a first additive, carrying out settling separation after the mixing treatment, obtaining a first material and residues after the separation; introducing the first material into a hydro-processing unit, carrying out a hydrogenation reaction under the action of a hydro-processing catalyst and hydrogen, introducing a liquid-phase effluent obtained after the reaction into a clarification unit, subjecting clarified oil to solid-liquid separation to obtain purified oil slurry, and mixing the purified oil slurry with an inferior raw material (hydrogenation tail oil) to obtain the low-sulfur marine fuel oil. According to the method, thesolid content and the sulfur content of the catalytic slurry oil can be reduced, high-quality purified slurry oil is produced, and the high-quality purified slurry oil is blended with residual oil toproduce the insufficient low-sulfur marine fuel oil.

Description

technical field [0001] The invention belongs to the field of refining and chemical industry, and in particular relates to a process for producing low-sulfur marine fuel oil. Background technique [0002] The MAPPOL Convention provides detailed regulations on the control area of ​​sulfur content in fuel oil used by ships and the limit value and implementation time of fuel oil sulfur content. It should not exceed 0.5%; when navigating in emission control areas, the sulfur content of fuel oil used on board should not exceed 0.1%. Through investigation and research, it is found that if the requirements for the use of low-sulfur fuel oil in the MAPPOL Convention are strictly implemented, the annual demand for low-sulfur fuel oil will be about 3 million tons. High, there are almost no refineries in the world that can produce fuel oil with a sulfur content of 0.5% or even less than 0.1%. There is a large gap in the low-sulfur fuel oil market, and manufacturers have an urgent need ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G65/02
CPCC10G65/02C10G2300/201
Inventor 孟兆会杨涛葛海龙陈博姜来朱慧红
Owner CHINA PETROLEUM & CHEM CORP
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