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Long-acting uvioresistant hot-melt pressure-sensitive adhesive for non-asphalt-based polymer waterproof coiled material and preparation method thereof

A hot-melt pressure-sensitive adhesive, based polymer technology, used in non-polymer adhesive additives, adhesives, adhesive types, etc., can solve the problems of low temperature flexibility and peel strength of the coil, and cracks on the bonding surface. , to achieve the effect of long-term initial viscosity, good low temperature performance and low melt viscosity

Active Publication Date: 2020-05-12
YUZHONGQING WATERPROOF MATERIALS CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of the existing non-bitumen-based polymer waterproofing membranes on the market, after one or two months of sunlight exposure, cracks appear on the bonding surface, the low-temperature flexibility of the membranes and the peeling strength decrease, and the skin-type waterproofing effect is affected. The invention provides a long-acting anti-ultraviolet hot-melt pressure-sensitive adhesive for non-asphalt-based polymer waterproof coils and a preparation method thereof. The invention uses hydrogenated polystyrene-polyisoprene-polystyrene thermoplastic rubber (Styrene Ethylene Propylene Styreneblock copolymer, referred to as SEPS) as the basic skeleton material, supplemented with naphthenic oil, two kinds of polyisobutylene, terpene resin, hydrogenated C5 petroleum resin and other additives, the obtained hot-melt pressure-sensitive adhesive can meet the national standard requirements, At the same time, it is low-cost, and compared with other hot-melt pressure-sensitive adhesives on the market, the hot-melt pressure-sensitive adhesive has longer-lasting weather resistance and low-temperature bending performance, and the production process of pressure-sensitive adhesive is simple and easy, without special equipment and special processes , the preparation process is non-toxic and harmless

Method used

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  • Long-acting uvioresistant hot-melt pressure-sensitive adhesive for non-asphalt-based polymer waterproof coiled material and preparation method thereof
  • Long-acting uvioresistant hot-melt pressure-sensitive adhesive for non-asphalt-based polymer waterproof coiled material and preparation method thereof
  • Long-acting uvioresistant hot-melt pressure-sensitive adhesive for non-asphalt-based polymer waterproof coiled material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0039] A long-term anti-ultraviolet hot-melt pressure-sensitive adhesive for non-bitumen-based polymer waterproof membrane, the pressure-sensitive adhesive includes the following raw materials:

[0040] SEPS 20kg, naphthenic oil 17.5kg, first polyisobutene 20.2kg, second polyisobutene 8kg, terpene resin 25.1kg, hydrogenated C5 petroleum resin 20kg, nano zinc oxide 1kg, antioxidant 0.5kg, ultraviolet absorber 0.5 kg and light stabilizer 0.75kg;

[0041] Among them, the polystyrene content in SEPS is 13%, the diblock content is 30%, and the melt index is 22g / 10min (230°C, load 5kg);

[0042] Naphthenic oil is a water-white, clear and transparent viscous liquid with no peculiar smell, and its kinematic viscosity at 40°C is less than 154mm 2 / s, the pour point is less than -21°C;

[0043] The molecular weight of the first polyisobutylene is not greater than 1300, the viscosity at 100°C is 590Cst-690Cst, and the pour point is -10°C-10°C;

[0044] The second polyisobutene is medi...

Embodiment 2

[0058] A long-term anti-ultraviolet hot-melt pressure-sensitive adhesive for non-bitumen-based polymer waterproof membrane, the pressure-sensitive adhesive includes the following raw materials:

[0059] SEPS 33kg, naphthenic oil 19.1kg, first polyisobutene 32.2kg, second polyisobutene 5kg, terpene resin 28.5kg, hydrogenated C5 petroleum resin 14kg, nano zinc oxide 3kg, antioxidant 0.6kg, ultraviolet absorber 0.5 kg and light stabilizer 1kg;

[0060] Among them, the polystyrene content in SEPS is 13%, the diblock content is 30%, and the melt index is 22g / 10min (230°C, load 5kg);

[0061] Naphthenic oil is a water-white, clear and transparent viscous liquid with no peculiar smell, and its kinematic viscosity at 40°C is less than 154mm 2 / s, the pour point is less than -21°C;

[0062] The molecular weight of the first polyisobutylene is not greater than 1300, the viscosity at 100°C is 590Cst-690Cst, and the pour point is -10°C-10°C;

[0063] The second polyisobutene is medium ...

Embodiment 3

[0077] A long-term anti-ultraviolet hot-melt pressure-sensitive adhesive for non-bitumen-based polymer waterproof membrane, the pressure-sensitive adhesive includes the following raw materials:

[0078] SEPS 40kg, naphthenic oil 31kg, first polyisobutene 24.5kg, second polyisobutene 5.5kg, terpene resin 36.5kg, hydrogenated C5 petroleum resin 28kg, nano zinc oxide 5kg, antioxidant 0.75kg, ultraviolet absorber 0.7 kg and light stabilizer 1.5kg;

[0079] Among them, the polystyrene content in SEPS is 13%, the diblock content is 30%, and the melt index is 22g / 10min (230°C, load 5kg);

[0080] Naphthenic oil is a water-white, clear and transparent viscous liquid with no peculiar smell, and its kinematic viscosity at 40°C is less than 154mm 2 / s, the pour point is less than -21°C;

[0081] The molecular weight of the first polyisobutylene is not greater than 1300, the viscosity at 100°C is 590Cst-690Cst, and the pour point is -10°C-10°C;

[0082] The second polyisobutene is medi...

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Abstract

The invention relates to the technical field of waterproof coiled materials, specifically to a long-acting uvioresistant hot-melt pressure-sensitive adhesive for a non-asphalt-based macromolecular waterproof coiled material and a preparation method thereof. The pressure-sensitive adhesive comprises the following raw materials: SEPS, naphthenic oil, first polyisobutene, second polyisobutene, terpene resin, hydrogenated C5 petroleum resin, nanometer zinc oxide, an antioxidant, an ultraviolet light absorber and a light stabilizer. The preparation method comprises the following steps that: the naphthenic oil, the first polyisobutene, the second polyisobutene, the antioxidant, the ultraviolet light absorber and the light stabilizer are added into production equipment; then nitrogen is introduced; heating is started, and stirring and temperature rising are conducted; SEPS is added, and stirring under a heat-preserved condition is conducted; the terpene resin and the hydrogenated C5 petroleum resin are added, and stirring under a heat-preserved condition is conducted; and the nanometer zinc oxide is added, a vacuum degree is controlled, and stirring under a heat-preserved condition is conducted. The pressure-sensitive adhesive disclosed by the invention meets national standard requirements, is low in cost, has longer-acting weather resistance and low-temperature bending performance,is simple and feasible in preparation process, does not need special equipment and process, and is non-toxic and harmless.

Description

technical field [0001] The invention relates to the technical field of waterproof membranes, in particular to a long-acting anti-ultraviolet hot-melt pressure-sensitive adhesive for non-asphalt-based polymer waterproof membranes and a preparation method thereof. Background technique [0002] The non-bitumen-based polymer waterproof membrane was first invented by the American GRACE waterproof company and brought into the Chinese market. Subsequently, the country issued relevant standards in 2008 to vigorously promote the pre-paved waterproof membrane system and construction technology. a wide range of applications. [0003] After the non-asphalt-based polymer waterproof membrane is laid and fixed, it is necessary to bind steel bars, or the construction period is delayed and the concrete cannot be poured immediately, and it is likely to be exposed to sunlight for up to a month or even longer. Therefore, GB / T 23457-2017 "Pre-laid Waterproof Membrane" clearly stipulates that t...

Claims

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Application Information

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IPC IPC(8): C09J153/02C09J145/00C09J123/20C09J191/00C09J157/02C09J11/04C09J11/06
CPCC08K2003/2296C08K2201/011C08L2201/08C08L2205/025C08L2205/035C09J11/04C09J11/06C09J145/00C09J153/025C08L53/025C08L57/02C08L23/22C08L91/00C08K13/02C08K3/22C08K5/1345C08K5/526C08K5/3475C08K5/3435C08L45/00
Inventor 阮军陈品松田益
Owner YUZHONGQING WATERPROOF MATERIALS CO LTD