Room temperature curable zirconate-silica sol-gel pretreatment for metal substrates
A silica and sol technology, applied in metal material coating process, non-metallic elements, silicon compounds, etc., can solve complex problems
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[0032] Preparation of hybrid sol-gel:
[0033] Allows for stabilization of alkoxy zirconates in IPA with carboxylic acids or 2,4-pentanedione. The stabilized zirconate is then completely hydrolyzed by adding excess water. The formed zirconium sol-gel is then added with stirring, together with tetraalkylsilicate as the raw material for the inorganic silica gel. Zirconium-silica hybrid sol-gels are formed after complete hydrolysis of the silicate and formation of nanoparticles by partial condensation. The epoxy functional silane is allowed to hydrolyze in the sol-gel prior to coating.
[0034] Aluminum alloy AA2024-T3 (clad and / or bare) panels were wet ground for deoxidation. The plates were then rinsed with clean deionized water and wiped dry with acetone. It is then sprayed with a sol-gel pretreatment, epoxy / amine primer and / or acetoacetate acrylic / acrylate primer, and a urethane topcoat. After drying at room temperature for 3 hours, it can be pre-treated with a primer co...
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