Lanthanide series metal-organic framework material with excellent second harmonic performance and preparation method thereof
A second harmonic and lanthanide metal technology, applied in the field of lanthanide metal-organic framework materials and their preparation, can solve problems such as lack of theory and achieve excellent second harmonic performance
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0029] Utilizing terbium nitrate and hexyl[4-(carboxyphenyl)carbonyl]-3-oxane, a metal-organic framework material was synthesized by a solvothermal method. The specific synthetic route is as follows:
[0030] Dissolve 0.1 mmol of terbium nitrate and 0.1 mmol of hexyl[4-(carboxyphenyl)carbonyl]-3-oxane in 7 mL of DMF and 1 mL of H 2 O mixed solvent, then add 1mL HNO 3 aqueous solution (1M). The solution was packaged in a 20mL polytetrafluoroethylene reactor, and placed in an oven at 160°C for 72 hours. After cooling to room temperature and washing with DMF three times, a colorless needle-like metal-organic framework material Tb was obtained. 2 L(DMF) 2 ·(H 2 O) 5 (DMF) 3 .
Embodiment 2
[0032] Utilizing lanthanum nitrate and hexyl[4-(carboxyphenyl)carbonyl]-3-oxane, a metal-organic framework material was synthesized by a solvothermal method. The specific synthetic route is as follows:
[0033] Dissolve 0.1 mmol of lanthanum nitrate and 0.1 mmol of hexyl[4-(carboxyphenyl)carbonyl]-3-oxane in 7 mL of DMF and 1 mL of H 2 O mixed solvent, then add 1mL HNO 3 aqueous solution (1M). The solution was packaged in a 20mL polytetrafluoroethylene reactor, and placed in an oven at 160°C for 72 hours. After cooling to room temperature and washing 3 times with DMF, a colorless needle-like metal-organic framework La 2 L·(H 2 O) 5 (DMF) 5 .
[0034] Using the preparation method of the present invention, the corresponding MOFs materials were synthesized for eight kinds of lanthanide metals. It can be clearly seen from powder X-ray diffraction (PXRD) that La-Tb-MOFs are isomorphic. ( figure 1 ). To verify the differences in crystal structure, single crystal resolution ...
PUM
Property | Measurement | Unit |
---|---|---|
particle size | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com