28 results about "Phosphate crystals" patented technology

The invention discloses preparation and application of a nickel selenide / ferronickel phosphate crystal / amorphous heterogeneous catalyst, and relates to the technical field of electrochemistry. Selenizing the foamed nickel at low temperature in an inert atmosphere to generate a crystalline NiSex layer in situ; and by taking the obtained electrode as a working electrode, carrying out electrodeposition in a deposition solution containing nickel salt, ferric salt, hypophosphite and acetate by adopting a cyclic voltammetry method, so that amorphous NiFePOy is deposited on the surface of NiSex, and a NiSex / NiFePOy crystal / amorphous heterostructure nanosheet layer is constructed and is used for an alkaline medium urea oxidation reaction. The invention has the following beneficial effects: crystalline / amorphous interface coupling and a nanosheet self-supporting structure synergistically improve active sites and charge transfer capability, reduce energy consumption and improve current output; meanwhile, the electrode stability and durability are enhanced; the method has the advantages of low material cost, mild and simple process, suitableness for amplified preparation, and application potential of urea-assisted water electrolysis energy-saving hydrogen production.

According to the preparation method, iron ions and phosphate ions are in a high-temperature and high-pressure environment, seed crystal generation and growth are controlled by presetting a specific crystal form, a large number of microcrystals are prevented from being instantly formed, the crystal size is controllable, the crystallinity is high, the consistency is good, and the conversion rate and the crystallization quality of the anhydrous iron phosphate are improved. Anhydrous iron phosphate is directly synthesized, sintering, dehydration and crystallization are not needed, washing water is greatly reduced, energy consumption and waste discharge are reduced, the influence of sintering on product quality fluctuation and poor consistency is avoided, and the production cost is reduced; the crystallinity and the particle size of the final iron phosphate crystal are adjusted by regulating and controlling the seed crystal type, the particle size and the dosage of the seed crystal, the dropwise adding speed and the stirring rotating speed of the iron source and the phosphorus source and the temperature and pressure during reaction, and on the premise that the high crystallinity and the stable and high iron-phosphorus ratio are kept, the specific surface area is adjustable within the range of 5-15 m < 2 > / g, the D50 is adjustable within the range of 0.8-12 microns, and the tap density is adjustable within the range of 0.6-1.55 g / cm < 3 >. And different application requirements are met.

The application discloses a potassium dihydrogen phosphate solution cooling crystallization device and a use method thereof, and belongs to the technical field of crystallization devices. The device comprises a cooling cavity, a cooling pipe arranged at the central bottom of the cooling cavity, two turning plates, a push rod, a power source and two connecting rods. The two turning plates are respectively arranged at the two sides of the cooling pipe and are hingedly connected with the inner bottom of the cooling cavity. The two sides of the two turning plates are sealingly matched with the inner side wall of the cooling cavity. The one end of the connecting rod is connected with the other end of the turning plate. The power source is fixedly connected with the outer wall of the cooling cavity and is drivingly connected with the other end of the push rod. The two connecting rods are symmetrically fixedly connected with the inner top of the cooling cavity. The triangular cooling cavity is hingedly connected with the free end of the connecting rod, so that the longest side of the triangular cooling cavity is adjacent to the turning plate. The feeding port is arranged in the central top region of the cooling cavity. The application has the beneficial effects of improving the cooling effect, shortening the cooling time and improving the quality of the generated potassium dihydrogen phosphate crystal.

The present application relates to the technical field of crystal nondestructive testing, and particularly relates to a crystal defect nondestructive testing method and system based on pumped probe transient absorption spectrum, which comprises the following steps: detecting a target region of a crystal to be tested by using pump light and probe light; collecting a transient absorption image of the target region according to a preset time delay between the pump light and the probe light, and extracting a target risk region; focusing the pump light and the probe light, and performing point-by-point scanning on the target risk region by using the focused pump light and probe light; collecting three-dimensional transient absorption intensity distribution and defect dynamic evolution data of each scanning point in the target risk region under different time delays; performing correlation calibration based on the transient absorption image and the three-dimensional transient absorption intensity distribution to obtain defect parameters; and constructing a damage prediction model based on sample damage threshold data, and outputting damage threshold prediction results according to the defect parameters. The purpose is to realize nondestructive and rapid detection of internal defects of deuterated potassium dihydrogen phosphate crystals.

The invention provides a method for co-producing lithium hydroxide and lithium dihydrogen phosphate from crude lithium carbonate, which comprises the following steps: S1, pulping the crude lithium carbonate, mixing with a calcium-containing reagent, carrying out causticization reaction, and carrying out solid-liquid separation to obtain causticized liquid and causticized slag; s2, mixing a part of the causticized liquid with a first impurity removal agent and a second impurity removal agent for impurity removal, and after solid-liquid separation, taking a liquid phase to obtain a first impurity-removed liquid; and S3, mixing the first impurity-removed liquid with the remaining causticized liquid, performing resin impurity removal to obtain a second impurity-removed liquid, and performing evaporation concentration and solid-liquid separation on part of the second impurity-removed liquid in sequence to obtain lithium hydroxide crystals and lithium hydroxide mother liquor. And taking the residual second impurity-removed liquid in the step S3, and carrying out lithium precipitation and acidification to prepare lithium dihydrogen phosphate crystals. The problem of product singleness of lithium enterprises is solved.

The application provides a positive electrode material, a positive electrode sheet, a battery and an electric device, and relates to the technical field of batteries.The structure of the positive electrode material is a core-shell structure, the inner core of which is a layered oxide and the outer shell layer of which is a polyanion material.The layered oxide is a polycrystalline particle.The size of the sodium iron pyrophosphate phosphate crystal in at least one dimension is 2-20 nm, and the size of the sodium iron pyrophosphate phosphate crystal in at least one dimension is 500 nm-1 mu m.The positive electrode material provided by the application is coated on the surface of the layered oxide particle by using a polyanion material which can intercalate into the crystal gap of the polycrystalline particle, so as to inhibit the lattice distortion of the O3 phase layered oxide, and meanwhile, the charge and discharge capacity and the rate performance of the layered oxide are optimized.

A whitlockite preparation method includes: determining a size of the whitlockite crystal to be prepared; determining a first amount of a first cation other than calcium ion on the basis of the determined size of the crystal, wherein when the determined size of the whitlockite crystal is a first size, the first amount is determined to be a first value, wherein when the determined size is a second size larger than the first size, the first amount is determined to be a second value; mixing calcium ion and phosphate ion in order to prepare a first phosphate crystal, wherein the determined first amount of the cation other than calcium ion is also mixed therewith; mixing a second amount of cation other than calcium ion with phosphate ion to prepare a second phosphate crystal; and aging a solution containing the first phosphate crystal and the second phosphate crystal.

A sintered membrane is a ceramic article having a primary crystal phase including lithium-aluminum-titanium-phosphate crystals and a secondary crystal phase including anatase or lithium-titanium-oxyphosphate crystals. In aspects, the sintered membrane can have a closed porosity of less than or equal to 5%. In aspects, the primary crystal phase can be from 95% to 100% of a volume of the ceramic article, and the secondary crystal phase can be from greater than 0% to 5% of the volume of the ceramic article. In aspects, the sintered membrane can exhibit a total leaching of less than or equal to 5 parts-per-million in a Leaching Test. Methods of making a sintered membrane includes forming a green tape having lithium-aluminum-titanium-phosphate crystals and an additive including a titanium-containing powder or an aluminum-containing powder, where the green tape is heated to a first temperature from 600°C to 1200°C to form the sintered membrane.

The invention discloses a Fe (II)-based fluorine-containing phosphate crystal as well as a preparation method and application thereof. A fluorine-rich hydrothermal method based on an oxidation-reduction reaction is an effective path for preparing Fe (II)-based fluorophosphate. The structural formula of the Fe (II) group-containing fluorine-containing phosphate crystal is BaFePO4F, the Fe (II) group-containing fluorine-containing phosphate crystal is crystallized in an orthorhombic crystal system, and the space group is P212121. According to the invention, the Mssbauer spectrum of the BaFePO4F is analyzed, Fe is proved to be II valence, the analysis of the magnetic susceptibility and specific heat of the BaFePO4F also finds that the BaFePO4F has antiferromagnetic interaction, and the antiferromagnetic ordered temperature of the BaFePO4F is 13.5 K. The invention also discloses a preparation method of the BaFePO4F. The Fe (II)-based fluorine-containing phosphate is stable in physical and chemical properties and easy to process and preserve; reagents and raw materials adopted by the method have low toxicity to human bodies, the production period is short, and the cost is low.

The invention discloses a cylindrical light-transmitting frequency doubling device for generating tunable yellow light and a laser device, and belongs to the nonlinear optical technology, the cylindrical light-transmitting frequency doubling device comprises a rubidium titanyl phosphate crystal, the rubidium titanyl phosphate crystal is processed into a cylinder along the Y-axis direction, and the cylindrical surface of the cylinder is plated with a dual-waveband antireflection film of 1140-1180 nm and a dual-waveband antireflection film of 570-590 nm. By means of the cylindrical surface light-passing frequency doubling device, the comprehensive performance of the yellow light frequency doubling device can be improved.

The application relates to a kind of ferric phosphate and its preparation method and application, the preparation method comprises the following steps: (1) after nanocellulose is treated by corona discharge, mixed with water and organic acid, esterified nanocellulose dispersion is obtained;(2) the esterified nanocellulose dispersion is mixed with oily solvent, and emulsion is obtained by emulsification treatment;(3) iron salt solution is mixed with the emulsion, one-step stirring is carried out, phosphate solution is added, the pH of mixed solution is adjusted, two-step stirring is carried out, and the ferric phosphate is obtained by sintering.The charged nanocellulose is formed into emulsion ball, and metal cation is directionally adsorbed on the surface of nanocellulose, finally reacts with phosphate ion to obtain ferric phosphate crystal with good dispersity, and the breaking difficulty of agglomerated ferric phosphate is reduced.

The application provides a method for separating potassium and sodium in a phosphate mother liquor, comprising the following steps: firstly, potassium in the phosphate mother liquor containing potassium and sodium is precipitated from the phosphate mother liquor in the form of potassium dihydrogen phosphate to obtain a potassium-removed mother liquor; and then, sodium in the potassium-removed mother liquor is crystallized and separated to realize the separation of potassium and sodium; specifically, the method comprises the following steps: S1. potassium removal: adjusting the pH value of the phosphate mother liquor to 4.0-5.0, then cooling and crystallizing, and centrifugally separating to precipitate potassium dihydrogen phosphate crystals, and obtaining the potassium-removed mother liquor; S2. sodium removal: adjusting the pH value of the potassium-removed mother liquor to 7.5-8.5, then cooling and crystallizing, and centrifugally separating to precipitate ammonium sodium phosphate crystals, and obtaining the sodium-removed mother liquor; the separation method separates potassium and sodium in the mother liquor, removes sodium impurities in the system, purifies the mother liquor, improves the quality of the circulating mother liquor, ensures the normal operation of the production system, and achieves the purposes of improving the product quality and improving the production capacity.

The application provides a polishing method for large-diameter potassium dihydrogen phosphate crystal elements, which can realize fast convergence of crystal surface shape precision, and comprises the following steps: 1) configuring an oil-based polishing liquid; 2) pasting a vacuum adsorption pad on the surface of a substrate with the same size as the crystal element; 3) pasting a light-induced debonding protective tape on the back surface of the crystal element, adsorbing the crystal element on the vacuum adsorption pad, and mounting the crystal element on a tool of a machine tool; 4) performing fast polishing on the processed surface of the crystal element; 5) after the fast polishing is completed, lifting a workpiece disc, and taking the crystal element and the substrate off the polishing disc; and 6) performing fast polishing on the crystal element after turning over. The crystal element is processed by using the method of full-diameter polishing of a hard polishing disc, the full surface of the crystal element is in contact with the polishing tool at the same time in the polishing process, fast processing based on the rigid pair of research is realized, the crystal surface shape precision is fast converged, and the method can be widely applied to the processing of various specifications of optical elements.

The application provides a core-shell structure positive electrode material, a positive electrode, a battery and an electric device, and relates to the technical field of batteries.The core-shell structure positive electrode material has a layered oxide polycrystal particle in O3 phase as an inner core and a whisker-shaped sodium iron pyrophosphate phosphate crystal as an outer shell; and the whisker-shaped sodium iron pyrophosphate phosphate crystals located on the interface between the inner core and the outer shell are inclinedly embedded in the inner core.The outer shell material of the core-shell structure positive electrode material provided by the application is partially inclinedly inserted into the inner core to form an inclined pinning structure, which can improve the interface bonding strength of the outer shell and the inner core and improve the expansion inhibition effect of the outer shell on the inner core.

The present application relates to chemical technology field, and discloses a kind of two end tapering instant potassium dihydrogen phosphate crystal and preparation method thereof;The crystal X-ray powder diffraction diagram has 17 characteristic peaks at 2θ=16.8±0.2°, 23.1±0.2° and the like, and is formed by microcrystalline directional assembly;Preparation method is as follows: potassium dihydrogen phosphate is dissolved in water to form saturated solution at 50-80 ℃, one or more of iron chloride hexahydrate, iron sulfate, iron phosphate is added as inorganic salt ion additive, after filtering to remove insoluble matter, it is cooled to 0-30 ℃ crystallization under stirring, after filtration, it is washed with anhydrous ethanol, acetone or saturated potassium dihydrogen phosphate solution, and vacuum drying at 30-65 ℃ is obtained.The process is simple, energy consumption is low, and reproducibility is high, product purity is more than 99%, and the yield is more than 60%, and the mother liquor can be recycled.The solubility and dissolution rate of the obtained crystal are better than those of commercial products, and it is suitable for instant water-soluble fertilizer.

The invention relates to the technical field of crystal nondestructive testing, in particular to a crystal defect nondestructive testing method and system based on a pumping detection transient absorption spectrum, and the method comprises the following steps: detecting a target area of a crystal to be detected by utilizing pumping light and detection light; according to a preset time delay between the pump light and the probe light, collecting a transient absorption image of the target area, and extracting a target risk area; focusing the pump light and the probe light, and performing point-by-point scanning on the target risk area by using the focused pump light and probe light; acquiring three-dimensional transient absorption intensity distribution and defect dynamic evolution data of each scanning point in the target risk area under different time delays; performing correlation calibration based on the transient absorption image and the three-dimensional transient absorption intensity distribution to obtain defect parameters; and constructing a damage prediction model based on the sample damage threshold data, and outputting a damage threshold prediction result according to the defect parameters. The objective of the invention is to realize nondestructive and rapid detection of internal defects of the deuterated potassium dihydrogen phosphate crystal.

The application discloses a preparation method of high-activity nano alpha-alumina powder for artificial ceramic joints, and a product and application thereof. Firstly, aluminum hydroxide colloid is prepared through a precipitation reaction and is ground and refined into nano-sized particles, and then a layer of phosphate colloid is precipitated on the aluminum hydroxide colloid particles as a wrapping layer through the precipitation reaction; the twice precipitated colloid is calcined to obtain a precursor of a phosphate crystal wrapping gamma-alumina crystal; the precursor is calcined to make the wrapped gamma-alumina shrink and transform into nano-sized alpha-alumina; and finally, the phosphate wrapping layer is removed through strong acid decomposition, so that the alpha-alumina powder with a particle size of 20-200 nm is obtained. The application first realizes a new technical system of preparing nano alpha-alumina powder by separating aluminum hydroxide with phosphate wrapping, and the artificial ceramic joint made of the alpha-alumina powder has excellent water-heat aging resistance and biocompatibility, and fully meets the use requirements of medical artificial ceramic joints.

The application provides an industrial-grade monoammonium phosphate crystal and a preparation method thereof, and a ferric phosphate crystal, and belongs to the field of battery materials, wherein the industrial-grade monoammonium phosphate crystal is in a prismatic structure, the two ends of the prism are in a tetrahedral shape, the particle size is 500-700 mu m; in terms of mass percentage, the P2O5 content in the industrial-grade monoammonium phosphate crystal is greater than 61%, the N content is greater than 11.5%, and the F ion content is 50-150 mg / kg. The application uses wet-process phosphoric acid as a raw material, introduces phosphorite slurry, a defluorination agent and an ammonia-containing solution in sequence, respectively carries out desulfurization, defluorination and neutralization, and strictly controls various reaction process parameters, so that impurities are significantly reduced; the prepared product has regular particle morphology, uniform particle size distribution, and relatively high phosphorus and nitrogen content, a lithium ferric phosphate positive electrode material prepared from the precursor has good electrical properties; the preparation method has the advantages of simple operation, easy control of reaction, low cost and the like, and is suitable for large-scale industrial production.

The invention provides a method for enhancing sludge pyrolytic phosphorus conversion through cooperation of an oxidizing agent and persistent free radicals, which comprises the following steps: (1) directly and mechanically dehydrating sludge, or adding persulfate for hydrothermal reaction, or adding a compound conditioner of ferrous sulfate and hydrogen peroxide for reaction, and dehydrating to obtain sludge with the water content of less than 60%; (2) the dehydrated sludge is mixed with an oxidizing agent, the adding amount of the oxidizing agent is 2-25 mmol / g dry sludge, a pyrolytic reaction is conducted under the anoxic condition, and after the pyrolytic reaction is finished, phosphorus-rich biochar generated through pyrolysis is collected; and (3) oscillating and soaking the collected phosphorus-rich biochar with an oxalic acid solution, carrying out solid-liquid separation to obtain a phosphorus-rich solution, adjusting the pH value of the phosphorus-rich solution to 4.5-5, and separating out phosphate crystals. The method has the remarkable advantages of being short in treatment process, high in organic phosphorus conversion rate, high in phosphorus product utilization rate and the like, and has important significance on rapid reduction and resource utilization of the municipal sludge.

The present application belongs to the technical field of lithium ion battery cathode material recycling and regeneration, and discloses a method for regenerating high-value lithium manganese iron phosphate from retired lithium iron phosphate and application thereof. The retired lithium iron phosphate is soaked in water and subjected to oxidation control to construct pretreated lithium iron phosphate containing controllable lithium vacancies; manganese source and phosphorus source are added according to the stoichiometric ratio of the target product, and carbon source and lithium source are additionally added, and lithium manganese iron phosphate is obtained through high-temperature sintering. The present application pre-introduces controllable lithium vacancies in the regenerated precursor, utilizes the lithium vacancies to reduce the diffusion energy barrier of Mn²⁺ and drive its migration to the interior of the crystal lattice, and realizes atomic-level uniform solid solution of manganese and iron in the phosphate crystal lattice. The obtained material has a single olivine phase, a flat voltage platform and a high specific capacity, and the rate performance and cycle stability are significantly improved. The method has a short process, does not pollute strong acid and strong base, is compatible with the existing solid-phase production line, and realizes direct upgrading and regeneration of the retired lithium iron phosphate into high-value lithium manganese iron phosphate.

The application discloses a preparation method and application of a cocatalyst, and belongs to the technical field of catalytic material preparation. The preparation method of the cocatalyst comprises the following steps: 1) uniformly mixing a carrier, a pore-forming agent, a binder and water to obtain a slurry, and roasting the slurry after shaping to obtain a microsphere carrier; 2) mixing the microsphere carrier with a modifier, a mineralizer and water, and performing a crystallization reaction under sealed conditions to obtain a microsphere carrier loaded with rare earth phosphate crystals, and roasting to obtain the cocatalyst; the modifier is selected from rare earth salts or rare earth oxides, and the mineralizer is selected from phosphoric acid or ammonium phosphate. According to the preparation method, the rare earth phosphate crystals are generated on the microsphere carrier by using a crystal growth hydrothermal method, and the cocatalyst with high dispersion and strong stability of active part rare earth phosphate is obtained by roasting and solidification, so that the cocatalyst has excellent vanadium and sulfur capturing capacity, and can significantly improve the catalytic activity of a main catalyst in a catalytic cracking reaction.

The invention relates to a method to be used in various engineering fields such as automotive, aviation, and marine industries, for the effective and more environmentally friendly chemical removal of organic coatings (cataphoresis coating or electrostatic powder coating) from metal surfaces Moreover, the method does not damage the substrate or the phosphate crystals, thereby minimizing production downtime by eliminating the need for repeated pre-treatment steps and reducing scrap rates by enabling reuse of the substrate material. In addition, the stripping solution does not become contaminated during the process, allowing repeated use without generating waste. The organic coating swells in the developed solution and subsequently separates into a water bath. The dissolution of the organic coating in the water bath provides recycling potential and supports a zero-waste approach.

The invention relates to a device and a method for removing phosphorus from wastewater that is purified at least mechanically and then biologically, wherein the biological purification process consists of a first anaerobic process and a second aerobic process. A partial stream of the orthophosphate-containing bio-P sludge generated in the anaerobic process is fed to a first solid / liquid separation unit (42). The liquid separated in the first solid / liquid separation unit is fed to a first unit (60) in which phosphate precipitate sludge containing phosphate crystals and / or sparingly soluble phosphate salts is formed. After separation of the crystals and / or sparingly soluble phosphate salts, the liquid, or at least a portion thereof, is returned to the biological purification stage.

The present application relates to the field of environment-friendly biological mining technology, and particularly relates to Pseudomonas kunmingensis and application thereof. The present application provides a new Pseudomonas kunmingensis strain capable of recovering rare earth ions through extracellular mineralization of rare earth phosphate crystals, and the strain is genetically modified, which can provide new choices and ways for rare earth biological mining, utilization of rare earth-rich tailings and biosynthesis of rare earth nanoparticles. The strain provided by the present application has low culture cost, fast growth speed, simple adsorption conditions, and has adsorption capacity for various rare earth ions, and has good application prospect in rare earth microbial mining and tailings utilization.

The invention provides a preparation method and application of a nano-sub-nano composite mineral for deeply treating organic phosphorus and inorganic phosphorus in industrial wastewater, and belongs to the technical field of environmental functional materials. Iron-containing nano minerals, polyacrylonitrile fibers and rare earth nano minerals are used as raw materials, and the composite material is synthesized through the technologies of hydrogen reduction roasting, multi-element wet type ball milling, ultrasonic treatment, 3D printing and the like. After the 3D milli-sub-nano composite mineral is added into a water body, the sub-nano zero-valent rare earth composite mineral and the sub-nano zero-valent iron mineral on the surface and in pore channels of the 3D milli-sub-nano composite mineral can generate active oxygen free radicals to catalyze organic phosphorus to be efficiently converted into inorganic phosphorus. Meanwhile, stable phosphate crystals are rapidly formed through specific binding, the complex minerals can be protonated at low pH to adsorb and bind phosphorus ions through electrostatic force, the efficient phosphorus removal capacity is achieved, interference of different anions, cations and humic acid can be resisted, and a functional environmental engineering material is provided for advanced treatment of industrial wastewater.

This application provides a wastewater phosphorus high-value recovery device and its operation method, belonging to the field of wastewater treatment and resource recovery technology. The wastewater phosphorus high-value recovery device includes: a membrane separation unit for solid-liquid separation and phosphate concentration of phosphorus-containing wastewater; a crystallization unit including a crystallization tank group, a dosing module, a detection module, and a control console, wherein the dosing module is connected to the crystallization tank group, the detection module is located within the crystallization tank group, and the control console is electrically connected to both the dosing module and the detection module; the crystallization unit is used for graded crystallization of the phosphorus-containing wastewater treated by the membrane separation unit to recover phosphate crystals; and a high-value preparation unit including a grinding module, a drying module, and a calcination module connected in sequence, used to prepare the recovered phosphate crystals into phosphate products.

The invention discloses a preparation method and application of a graphite shell fully-coated FeCoCu phosphide nanoparticle electrocatalyst, and belongs to the technical field of metal electrocatalysts. According to the invention, ultrasonic, rotary evaporation and temperature programming processes are adopted. The characteristic that Fe and Co components induce carbon dissolution and precipitation in a high-temperature environment is utilized, a core-shell structure pre-product with alloy nanoparticles completely coated with a graphite shell is firstly constructed through high-temperature treatment, then the pre-product is encapsulated in a low-melting-point phosphate crystal through a dissolution and crystallization process, and low-temperature phosphating treatment is conducted. The FeCoCu phosphide nano-particle electrocatalyst coated with the graphite shell is prepared. The obtained electrocatalyst is high in stability in acid and high in electrocatalytic hydrogen evolution activity, is suitable for hydrogen evolution reaction in a strong acid environment (pH is smaller than 2), and shows single-cell performance close to that of a commercial platinum-carbon electrocatalyst in a proton exchange membrane electrolytic cell cathode.

This invention discloses a method and phosphating solution for improving the ductility and corrosion resistance of the phosphating film on online phosphating steel wire, comprising the following steps: S1, preparing a zinc-based phosphating solution; S2, maintaining process parameters; S3, online phosphating treatment; S4, drawing and forming; wherein, the concentration of nickel ions (Ni²⁺) is greater than 500 ppm, the concentration of zinc ions (Zn²⁺) is 8-12 g / L, the concentration of total phosphate (PO₄³⁻) is 25-35 g / L, and satisfies Zn²⁺:Ni²⁺=15-24:1 and PO₄³⁻:(Zn²⁺+Ni²⁺). The ratio is 2.0-2.5:1; the composite stabilizing system includes 0.3-0.8 g / L of organic amine stabilizer and 0.1-0.3 g / L of fluoride; this invention revolutionarily increases the nickel ion concentration in the zinc phosphating solution to over 500 ppm, breaking through the limitations of traditional low-nickel systems, promoting the formation of a Zn-Ni composite phosphate crystal film, and significantly enhancing the corrosion resistance of the steel wire by means of the dense Zn-Ni composite phosphating film structure and the precisely controlled ion ratio, effectively isolating the substrate from corrosive media such as air and moisture.