The invention provides a secondary battery negative electrode. The secondary battery negative electrode comprises metal foil and a compact metal phosphate film arranged on the surface of the metal foil; the metal foil serves as a negative current collector and an negative electrode active material at the same time and is made of any one of aluminum, copper, iron, tin, zinc, nickel, manganese, lead, antimony, cadmium and bismuth, or an alloy containing at least one of the metal elements; and the metal phosphate film is made of one or more of aluminum phosphate, copper phosphate, iron phosphate,tin phosphate, zinc phosphate, nickel phosphate, manganese phosphate, lead phosphate, antimony phosphate, cadmium phosphate and bismuth phosphate. According to the secondary battery negative electrode, the metal phosphate film which is electrically insulated and is provided with lithium ions capable of migrating is arranged on the surface of the metal foil; the metal phosphate film achieves the similar function of a solid electrolyte membrane; and the compatibility of the negative electrode and electrolyte is improved, and the charging and discharging efficiency of a battery, the cycling performance of the battery, the high-and-low temperature performance and the safety performance are improved. The invention further provides a preparation method of the secondary battery negative electrode and a secondary battery.