28 results about "Nickel phosphate" patented technology

The invention discloses a niobium-doped and carbon nanotube continuously coated lithium iron nickel phosphate material and a preparation method thereof, and belongs to the technical field of lithium ion battery positive electrode materials. The niobium source and the phosphorus source are added step by step, the concentration gradient distribution of the niobium element in the material is realized, and niobium is preferentially doped in the [100] crystal orientation through three-section temperature control sintering, so that the bulk phase conductivity and the lithium ion mobility are remarkably improved, and the capacity loss caused by excessive doping is avoided while the lattice structure is stabilized. In addition, the carbon nanotubes and the nitrogen-containing carbon source have a synergistic effect, Li-N-C covalent bonds are formed on the surface of the material, the interface stability is enhanced, the interface side reaction is effectively inhibited, and the surface conductivity is improved. According to the method, through double modification of doping and coating, the problems of low conductivity and poor cycling stability of the lithium iron nickel phosphate material are successfully solved, and the final product shows excellent rate capability and long cycle life.

The invention discloses a fire-resistant heat-insulating polyurethane microporous rubber and a preparation method and application thereof, and relates to the technical field of fireproof and heat-insulating materials. The fire-resistant heat-insulating polyurethane microporous rubber is prepared from component A and component B in a weight ratio of 100:(45-55); the component A includes the following components in weight percentage: 25-40% polyether polyol, 5-10% polyester polyol, 15-25% ceramic powder, 15-25% nickel aluminum phosphate, 12-31% flame retardant, 1.5-8.5% foaming agent, 0.5-1.5% foam stabilizer, and 0.05-0.2% catalyst; the component B is polymethylene polyphenyl polyisocyanate. The non-expansion ceramic flame retardant scheme adopted by the invention is conducive to the improvement and stabilization of the flame retardant grade of the polyurethane microporous rubber and the ceramic structural strength.

The present invention discloses a blue light blocking and privacy protection film and its preparation process, which relates to the technical field of blue light blocking and privacy protection films. The blue light blocking and privacy protection film includes a substrate layer and a functional layer compounded on the surface of the substrate layer; the thickness of the substrate layer is 80-100 μm, and the thickness of the functional layer is 100-120 μm; the substrate layer is prepared from a composite nylon resin containing nickel phosphate polymer; the functional layer is prepared from a functionalized carboxymethyl cellulose solution containing functional graphene flakes.

The present invention relates to ternary lithium nickel phosphate glasses and a process for their production. The invention also relates to the preparation and use of said glasses as active materials for positive electrodes, particularly in metal-ion batteries, as well as to said active materials and electrodes per se. (no figure)

The present invention relates to sodium nickel phosphate ternary glasses and to a process for their production. The invention also relates to the preparation and use of said glasses as active materials for positive electrodes, in particular metal-ion accumulators, as well as said active materials and electrodes per se. (no figure)

A positive electrode active material includes a plurality of lithium nickel phosphate nanoparticles having an olivine structure and having an exposed surface that is a {111} crystal plane. The positive electrode active material can be used in a positive electrode for an electrochemical cell.

The invention relates to a preparation method of lotus seedpod-based activated carbon with improved low-temperature adsorbability, which comprises the following steps: (S1) crushing lotus seedpod, washing with water, and drying to obtain lotus seedpod powder; (S2) the lotus seedpod powder is added into steeping liquor, steeping activation is conducted at the temperature of 80-100 DEG C in a closed state, and the steeping liquor is a mixed aqueous solution prepared from phosphoric acid, nickel-bipyridine complex salt and a non-ionic surface active agent according to the mass ratio of 100: (15-25): (1-3); after dipping activation is finished, adding a thiol reducing agent, and then performing freeze drying to obtain a precursor; and (S3) carbonizing, washing and drying the precursor in an inert atmosphere to obtain the lotus seedpod-based activated carbon with improved low-temperature adsorbability. The prepared lotus seedpod-based activated carbon overcomes the problems that active sites of a traditional material are easy to agglomerate and sensitive to temperature, shows excellent low-temperature adsorption characteristics, and is suitable for efficient adsorption of cadmium heavy metal ions in water in a low-temperature environment.

The invention belongs to the field of inorganic functional materials, and particularly relates to a basic nickel carbonate modified material and a preparation method thereof.The method comprises the steps that nickel nitrate hexahydrate is dissolved in deionized water, urea and cetyltrimethylammonium bromide are added, the mixture is heated and stirred mildly, and stirring is performed to obtain a basic nickel carbonate modified material; then adding a specially-made polyaminophenylboronic acid nickel complex and a cobalt-nickel phosphate ethanediamine hybrid material, performing ultrasonic dispersion to form a mixed solution, and then performing hydrothermal reaction, centrifugal washing and vacuum drying to obtain a final product. The two special modified compounds are respectively prepared through a coordination reaction regulated by ammonia water and a hybridization reaction under high-temperature and high-pressure conditions. The modified material prepared by the method has a unique microstructure and enhanced physical and chemical properties, shows excellent application prospects in the fields of electrochemical energy storage, electro-catalytic water and environmental remediation, and particularly, the comprehensive performance of the material is remarkably improved due to the high specific surface area, abundant active sites and a stable structure.

Provided is a water electrolysis catalyst with a core-shell structure, which has a vanadium-doped cobalt nitride (V—Co4N) core; and a cobalt-nickel phosphate (CoNiPOx, x is a natural number) shell.

The invention relates to the field of electrocatalyst catalytic energy conversion, and particularly discloses an oxygen-vacancy-enriched chromium ion doped nickel phosphate nanoflower as well as a preparation method and application thereof. The preparation method comprises the following steps: S1, dissolving nickel nitrate hexahydrate, chromic nitrate nonahydrate, urea, sodium tartrate and polyethylene glycol into water, and then carrying out heating reaction; s2, mixing the chromium ion doped nickel hydroxide nanoflowers prepared in the step S1 with sodium hypophosphite, uniformly dispersing the mixture in water, and then performing freeze drying and sealed calcination; and S3, carrying out plasma reaction on the chromium ion doped nickel phosphate nanoflower prepared in the step S2 under the condition of introducing inert discharge gas to obtain the oxygen vacancy-enriched chromium ion doped nickel phosphate nanoflower. The oxygen-vacancy-rich chromium ion doped nickel phosphate nanoflower has relatively high conductivity and surface activity, and can reduce overpotential, promote the kinetic process of water decomposition reaction, reduce energy loss and improve the efficiency of hydrogen production by electrolysis of water.

The invention relates to a preparation method of a 5V high-voltage positive electrode material, the chemical general formula of the positive electrode material can be expressed as LiaNibMndMePO4 / C, (a lithium nickel manganese phosphate carbon coated composite positive electrode material) and NibMndMePO4 (a lithium nickel manganese phosphate precursor), the positive electrode material is expressed by 'LNMP', and the precursor is expressed by 'NMP'. Through calculation, the theoretical specific capacity is about 168.5 mAh / g, the theoretical voltage platform is about 5.1 V, the actual voltage platform is 5.1-5.3 V, and the material belongs to a 5V high-voltage platform phosphate positive electrode material.

The application belongs to the technical field of water electrolysis hydrogen evolution in neutral solution, and provides a preparation method of copper@molybdenum modified nickel phosphate nanorod array. The material is a core-shell structure nanorod array obtained by depositing molybdenum modified nickel phosphate on copper nanowire. The nanorod array is prepared by combining the preparation processes of immersion method, electro-reduction method and electrodeposition method. The addition of molybdenum and the nanorod structure can effectively improve the conductivity of the catalyst, improve the electron transfer capacity, increase the number of exposed active sites of the catalyst, and promote the hydrogen evolution activity of the catalyst in the neutral solution. When the current density is 10 and 100 mA / cm 2 , the minimum overpotential required for water electrolysis hydrogen evolution is 35 and 195 mV, respectively, which is much lower than that of the hydrogen evolution electrocatalyst prepared by directly loading molybdenum modified nickel phosphate on the surface of the copper foam without molybdenum modification. At the same time, when the current density is -10 mA / cm 2 , the catalyst can be stably operated for at least 25 hours.

The present disclosure relates to the technical field of carrier copper foil, and in particular to a solution for preparing a carrier copper foil stripping layer and a method for preparing a carrier copper foil stripping layer. The solution for preparing the carrier copper foil stripping layer includes mutually isolated potions A and B, wherein the potion A includes phosphate, and the phosphate includes at least one of zinc dihydrogen phosphate, calcium dihydrogen phosphate, manganese dihydrogen phosphate, iron dihydrogen phosphate, ammonium dihydrogen phosphate, lithium dihydrogen phosphate, sodium dihydrogen phosphate and potassium dihydrogen phosphate; the potion B includes a phosphide metal, and the phosphide metal includes at least one of molybdenum phosphide, zinc phosphide, nickel phosphide, chromium phosphide and potassium phosphide. The solution for preparing the carrier copper foil stripping layer can form a stable stripping layer on the carrier layer, which is convenient for the subsequent deposition of ultra-thin copper foil. At the same time, after the ultra-thin copper foil is prepared, the stripping layer can show good stripping performance and is easy to strip from the carrier layer.

The present application discloses a preparation method of a cathode material with a coating layer, a lithium battery and an electric vehicle. The method includes: under the condition of the presence of a complexing agent, causing a soluble metal salt and an alkaline substance to undergo a coprecipitation reaction in a solvent; under the condition that the pH value is 9-13, causing the precipitate on the surface layer of the precursor precipitate to be in-situ converted into a phosphate precipitate, obtaining a precursor with a phosphate precipitate coating layer on the surface, and obtaining a second solid-liquid mixture; aging the second solid-liquid mixture to enable nickel phosphate, cobalt phosphate and manganese phosphate to be adsorbed on the outer layer of the precursor with a phosphate precipitate coating layer; mixing the precursor with a lithium source and performing a high-temperature sintering treatment to obtain a cathode material with a coating layer. In the embodiment of the application, a precursor with a coating layer is obtained through the conversion of a phosphate precipitate; and through aging, free metal salt ions are adsorbed on the outer layer of the precursor as a coating layer, achieving the purpose of improving the utilization rate of raw materials.

The present invention relates to a method for treating mechanical parts (2, 3) having a functional surface (8) made of NiP intended to be in frictional contact with another functional surface, the method comprising the step of oxidizing and / or phosphate-chloriding the functional surface (8) in order to artificially form an oxide layer (9) and / or a phosphate layer (10) on the functional surface (8), the phosphate layer (10) being a layer of nickel phosphate or zinc phosphate.

MULTI-COMPONENT CORROSION INHIBITOR MIXTURE FOR FILM-FORMING BINDERS INTENDED TO PROTECT METALLIC SUBSTRATES. A corrosion inhibitor composition comprises at least two metal polycarboxylate salts and at least one non-lithium metal phosphate salt. The metal polycarboxylate salts may be citrates and / or oxalates. The non-lithium metal phosphate salts may be nickel phosphate or aluminum phosphate.

The invention belongs to the technical field of catalyst preparation, and particularly relates to a method for in-situ synthesis of a nickel phosphate-molybdenum phosphide / nickel molybdenum oxide catalyst through a two-step method and application of the nickel phosphate-molybdenum phosphide / nickel molybdenum oxide catalyst. The preparation method comprises the following steps: by taking a nickel source and a molybdenum source as reactants and taking foamed nickel as a carrier, carrying out hydrothermal reaction to obtain foamed nickel on which Ni and Mo grow; a phosphorus source is used as a reactant, foamed nickel on which Ni and Mo grow is used as a growth substrate, phosphorus atoms are doped through chemical vapor deposition, and the nickel phosphate-molybdenum phosphide / nickel molybdenum oxide catalyst is obtained. The catalyst has extremely low hydrogen evolution overpotential (53 mV) under the current density of 10 mA cm <-2 >, has extremely excellent hydrogen evolution reaction kinetics, and has the characteristics of easiness in preparation, low cost, no pollution and the like.

The invention discloses a preparation method of a lithium nickel phosphate coated lithium nickel manganese oxide positive electrode material, which comprises the following steps: uniformly mixing a lithium nickel manganese oxide precursor and a lithium source, sintering to obtain lithium nickel manganese oxide single crystal particles, mixing the lithium nickel manganese oxide single crystal particles with a phosphate solution to form a nickel-containing phosphate sediment, and carrying out secondary sintering in a protective atmosphere to obtain the lithium nickel phosphate coated lithium nickel manganese oxide positive electrode material. The lithium nickel manganese oxide positive electrode material coated with the lithium nickel phosphate is obtained. According to the method, the initial capacity and the cycle performance of the lithium nickel phosphate coated lithium nickel manganese oxide positive electrode material can be improved, and the preparation method is simple in step, wide in material source, low in cost and more beneficial to popularization and application in production practice.

Provided in the present application are a composite-coated positive electrode material and a preparation method therefor, a positive electrode sheet, a lithium-ion battery and an electric device. The composite-coated positive electrode material comprises an inner core, a first coating layer that coats at least part of the surface of the inner core, and a second coating layer that coats at least part of the surface of the first coating layer, wherein the inner core comprises a lithium nickel manganese oxide; the first coating layer comprises a first coating material, the first coating material comprises one or more of nickel phosphate, manganese phosphate, lithium phosphate, lithium nickel phosphate and lithium manganese phosphate, the first coating material further comprises aluminum, and at least some aluminum atoms occupy nickel sites and / or manganese sites in the crystal structure of the lithium nickel manganese oxide; and the second coating layer comprises a second coating material, and the second coating material comprises lithium phosphate and at least one of lithium metaaluminate and aluminum oxide. The prepared positive electrode material has relatively high capacity and good cycle performance.

The invention discloses a preparation method and application of an Eu-doped Ni (PO3) 2 porous nanosheet electrocatalyst. According to the method, carbon cloth is taken as a substrate, europium inorganic salt is taken as a europium source, nickel inorganic salt is taken as a nickel source, amino acid is taken as a rare earth anchoring agent, ammonium fluoride is taken as a precipitator, urea is taken as a reducing agent, a carbon cloth-loaded Eu-doped Ni (OH) 2 precursor is synthesized through a hydrothermal reaction, and finally the catalyst is prepared through a low-temperature phosphorization process in an Ar / H2 atmosphere. Europium is doped in nickel metaphosphate, and the catalytic activity and stability of the catalyst are improved through the synergistic effect of europium and nickel; and the catalyst is good in morphology maintenance degree and high in selectivity for oxygen evolution reaction (OER), and has a good market prospect.

Corrosion inhibitor mixes comprising multiple salts. One mix includes zinc citrate, zinc oxalate and magnesium phosphate. A second mix includes the same two zinc salts, nickel oxalate and nickel phosphate. Either mix may be added to a film-forming binder such as a polymer suitable for a paint or primer, to inhibit corrosion, especially when used with a metallic substrate. The resulting product of the inhibitor mix and binder is especially useful in inhibiting corrosion when applied to an aircraft surface.

The invention discloses a cobalt nickel phosphate, indium zinc sulfide and cobalt oxide composite photocatalyst as well as a preparation method and application thereof, and belongs to the field of photocatalysis. The preparation process comprises the following steps: mixing an aqueous solution of a nickel source and a cobalt source with an aqueous solution of a phosphine source for reaction; calcining the solid to obtain Ni2CoPOx, and adding the Ni2CoPOx into the ZnIn2S4 precursor solution; and after the reaction is completed, Ni2CoPOx (at) ZnIn2S4 is obtained. The preparation method comprises the following steps: dissolving polyvinylpyrrolidone in a mixed solvent of distilled water and methanol, then adding Ni2CoPOx (at) ZnIn2S4, dropwise adding tributyl phosphorus, and stirring; dropwise adding a cobalt chloride solution, and stirring and reacting at normal temperature; and centrifuging, collecting solids, washing and drying to obtain the Ni2CoPOx (at) ZnIn2S4 (at) CoOx composite photocatalyst. Ni2CoPOx and CoOx can be used as water oxidation active sites to produce hydrogen peroxide. Meanwhile, due to the introduction of Ni2CoPOx and CoOx clusters, the separation efficiency of photon-generated carriers can be effectively improved, the light absorption capacity is enhanced, and the photocatalytic full-water decomposition performance is further remarkably improved. The hydrogen production rate of the Ni2CoPOx (at) ZnIn2S4 (at) CoOx composite photocatalyst is 1541.2 [mu] mol.g <-1 >. H <-1 >, and the hydrogen peroxide production rate of the Ni2CoPOx (at) ZnIn2S4 (at) CoOx composite photocatalyst reaches 1381.1 [mu] mol.g <-1 >. H <-1 >.

This invention discloses a high-voltage, high-rate lithium nickel manganese oxide cathode material and its preparation method, comprising the following steps: S1, weighing yttrium source, nickel source, and manganese source according to the stoichiometric ratio of Y:Ni:Mn, dissolving the three raw materials in water respectively, adding yttrium source aqueous solution, nickel source aqueous solution, and manganese source aqueous solution dropwise to citric acid aqueous solution, microwave-assisted heating to control the temperature of the solution at 60℃-80℃, stirring for a period of time, adding sodium bicarbonate aqueous solution and ammonia water to control the pH to 7-8, co-precipitating for a period of time, and then filtering, drying, and ball milling to obtain a preliminary yttrium-doped lithium nickel manganese oxide precursor; S2, mixing the precursor obtained in step S1 with a lithium source, and then calcining, annealing, and pulverizing to obtain a primary lithium nickel manganese oxide cathode material; S3, ball milling nickel phosphate and manganese phosphate into nanoparticles, uniformly coating the surface of the primary lithium nickel manganese oxide cathode material by spray drying, and then drying, calcining, annealing, pulverizing, sieving, and demagnetizing to obtain the lithium nickel manganese oxide cathode material.

The present disclosure relates to lithium nickel phosphate ternary glasses and to the method to obtain them. The disclosure also relates to the preparation and use of lithium nickel phosphate ternary glasses as active materials of positive electrodes, in particular of metal-ion accumulators, as well as the active materials and electrodes.

A positive active material characterized by comprising a core and a coating layer, the coating layer being disposed on the surface of the core, the core comprising lithium nickel manganese oxide, the coating layer comprising lithium nickel phosphate, and the particle size Dn50 of the core and the thickness “d” of the coating layer satisfy the following: 1.5nm / µm≤d / (Dn50)≤14nm / µm.

The invention discloses an anti-blue-light peep-proof film and a preparation process thereof, and relates to the technical field of anti-blue-light peep-proof films, and the anti-blue-light peep-proof film comprises a base material layer and a functional layer compounded on the surface of the base material layer; the thickness of the base material layer is 80-100 microns, and the thickness of the functional layer is 100-120 microns; the base material layer is prepared from composite nylon resin containing a nickel phosphate polymer; the functional layer is prepared from a functionalized carboxymethyl cellulose solution containing a functional graphene sheet.

The present invention relates to binary nickel phosphate glasses and a process for their production. The invention also relates to the preparation and use of said glasses as active materials for positive electrodes, particularly in metal-ion batteries, as well as to said active materials and electrodes per se. (no figure)

The present disclosure belongs to the field of battery materials, and discloses a coated nickel-rich ternary material and a preparation method and application thereof. The coated nickel-rich ternary material has a chemical formula of LiNixCoyMnzO2·a[M3(PO4)2·bH2O], Where 0.6≤x≤0.8, 0.1≤y≤0.2, 0.1≤z≤0.2, x+y+z=1, 0.01≤a≤0.03, 3≤b≤8, M3(PO4)2·bH2O is at least one selected from the group consisting of nickel phosphate, cobalt phosphate and manganese phosphate; the coated nickel-rich ternary material has a flower-like structure. The preparation method of the present disclosure provides phosphate ions through the prepared phosphate solution, performs coating in a liquid phase environment, and synthesizes the precursor simultaneously by microwave hydrothermal synthesis, which is beneficial to the full contact between the phosphates and the precursor, and ensures the surface of the nickel-rich ternary precursor is uniformly coated with the phosphates. The method is simple and has good coating effect.