Semiconducting light emitting material
A nano-luminescent material and semiconductor technology, applied in the direction of luminescent materials, semiconductor devices, organic chemistry, etc., can solve the problems that do not mention the ability of passivation traps, and achieve improved quantum yield stability, improved quantum yield stability, The effect of increased stability
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Embodiment approach 1
[0168] Embodiment 1: a semiconductor nanoluminescent material comprising a core, optionally one or more shells, and a ligand coated on the core or on the outermost surface of the shell or formed by the core, optionally One or more shells and a ligand coating the core or the outermost surface of the shells, wherein the ligand is at least one thiometalate salt.
Embodiment approach 2
[0169] Embodiment 2: The material according to Embodiment 1, wherein the ligand is represented by Formula (I)
[0170]
[0171] in,
[0172] M represents a divalent metal, preferably zinc, magnesium, copper or a mixture thereof;
[0173] X means -O- or -S- or -NR 2 -;
[0174] Y 1 Indicates -O- or -S-;
[0175] R 1 , R 2 independently of each other represent alkyl, alkenyl, alkynyl, aryl and / or aralkyl chains having 2 to 25 carbon atoms, optionally substituted by functional groups; or
[0176] Groups according to formula (II) and / or (III)
[0177] -(CHR 5 ) x O(CHR 5 ) y2 -NR 3 R 4 (II)
[0178] -CH 2 CHR 5 O) z R 6 (III)
[0179] R 3 , R 4 represent independently of each other straight or branched alkyl chains with 1 to 6 carbon atoms;
[0180] R 5 represents hydrogen or methyl;
[0181] R 6 represents an alkyl chain with 1-4 carbon atoms, optionally substituted by a functional group;
[0182] x, y2 independently represent an integer from 1 to 5...
Embodiment approach 3
[0184] Embodiment 3: The material according to Embodiment 1 or 2, wherein said ligand is represented by Formula (I), and wherein R 1 , R 2 independently of one another represent alkyl, alkenyl, alkynyl, aryl and / or aralkyl chains having 7 to 20 carbon atoms, which chains are optionally substituted by functional groups.
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