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Graphene oxide/zinc oxide antistatic polypropylene cast film

A technology of polypropylene casting and graphene, which is applied in the field of materials, can solve the problems that can only be applied in the field of insulation in industry or life, limit the use range of PP, burn or explode, etc., achieve good antistatic effect and reduce agglomeration Possibility, the effect of quality assurance

Active Publication Date: 2020-06-12
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, PP is a highly insulating material, and its volume resistivity is generally 10. 16 ~10 18 Ω·m, surface resistivity 10 16 ~10 17 Ω, due to the high surface resistivity and volume resistivity of PP itself, the electrostatic charge generated cannot be transferred. When the surface electrostatic charge accumulates to a certain extent, it will bring serious dangers, such as dust collection, discharge, breakdown, Even burn or explode, which greatly limits the scope of use of PP, so that it can only be used in the field of insulation in industry or life

Method used

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  • Graphene oxide/zinc oxide antistatic polypropylene cast film
  • Graphene oxide/zinc oxide antistatic polypropylene cast film
  • Graphene oxide/zinc oxide antistatic polypropylene cast film

Examples

Experimental program
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Effect test

Embodiment 1

[0027] A kind of graphene oxide / zinc oxide antistatic polypropylene casting film, it is that 100 weight parts of polypropylene resin and 5 weight parts of antistatic masterbatch are dropped into in the mixer, at 60 ℃ with 300r / min high-speed stirring to make it uniform, and then through extrusion casting, cooling, edge trimming, and pressure winding, the finished product is obtained.

[0028] The preparation method of the antistatic masterbatch used is to add polypropylene resin, composite antistatic agent OA / GO-g-ZnO and EVA resin to a high-speed mixer at a mass ratio of 5:2:3, and mix at 60°C and 300r / min at a high speed Stir to make it even, then pump it into a dehumidification dryer, dry it at 50~60°C for 4-6h, and then extrude it at 190°C to obtain antistatic masterbatch.

[0029] The preparation method of the composite antistatic agent OA / GO-g-ZnO is to dissolve 150g of graphene oxide and 450g of polypropylene pyrrolidone in 50mL of DMF, and in the presence of 0.5mL of t...

Embodiment 2

[0033] A graphene oxide / zinc oxide antistatic polypropylene casting film, which is to put 100 parts by weight of polypropylene resin and 10 parts by weight of antistatic masterbatch into a mixer, and stir it at a high speed of 300r / min at 60°C to make it uniform, and then through extrusion casting, cooling, edge trimming, and pressure winding, the finished product is obtained.

[0034] The preparation method of the antistatic masterbatch used is to add polypropylene resin, composite antistatic agent OA / GO-g-ZnO and EVA resin to a high-speed mixer at a mass ratio of 5:2:3, and mix at 60°C and 300r / min at a high speed Stir to make it even, then pump it into a dehumidification dryer, dry it at 50~60°C for 4-6h, and then extrude it at 190°C to obtain antistatic masterbatch.

[0035]The preparation method of the composite antistatic agent OA / GO-g-ZnO is to dissolve 150g of graphene oxide and 450g of polypropylene pyrrolidone in 50mL of DMF, and in the presence of 0.5mL of triethyla...

Embodiment 3

[0039] A graphene oxide / zinc oxide antistatic polypropylene casting film, which is to put 100 parts by weight of polypropylene resin and 15 parts by weight of antistatic masterbatch into a mixer, and stir it at a high speed of 300r / min at 60°C to make it uniform, and then through extrusion casting, cooling, edge trimming, and pressure winding, the finished product is obtained.

[0040] The preparation method of the antistatic masterbatch used is to add polypropylene resin, composite antistatic agent OA / GO-g-ZnO and EVA resin to a high-speed mixer at a mass ratio of 5:2:3, and mix at 60°C and 300r / min at a high speed Stir to make it even, then pump it into a dehumidification dryer, dry it at 50~60°C for 4-6h, and then extrude it at 190°C to obtain antistatic masterbatch.

[0041] The preparation method of the composite antistatic agent OA / GO-g-ZnO is to dissolve 150g of graphene oxide and 450g of polypropylene pyrrolidone in 50mL of DMF, and in the presence of 0.5mL of triethyl...

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Abstract

The invention discloses a graphene oxide / zinc oxide antistatic polypropylene cast film and a preparation method thereof, and belongs to the technical field of materials. The graphene oxide / zinc oxideantistatic polypropylene cast film is prepared from, by weight, 100 parts of polypropylene resin and 5-15 parts of antistatic master batch, wherein the antistatic master batch is prepared from polypropylene resin, a composite antistatic agent OA / GO-g-ZnO and EVA resin. The composite antistatic agent OA / GO-g-ZnO used in the antistatic master batch combines the antistatic properties of graphene oxide and oleic acid, and zinc oxide uniformly grows on oleic acid functionalized modified graphene oxide to avoid agglomeration, so that the obtained polypropylene cast film has a good antistatic effect.

Description

technical field [0001] The invention belongs to the technical field of materials, and in particular relates to a graphene oxide / zinc oxide antistatic polypropylene casting film and a preparation method thereof. Background technique [0002] Polypropylene (PP) is a semi-crystalline polymer with high stiffness, excellent mechanical properties, good heat resistance and chemical resistance. It is also non-toxic, easy to recycle, and environmentally friendly. So in recent years, it has been widely concerned by researchers at home and abroad. However, PP is a highly insulating material, and its volume resistivity is generally 10. 16 ~10 18 Ω·m, surface resistivity 10 16 ~10 17 Ω, due to the high surface resistivity and volume resistivity of PP itself, the electrostatic charge generated cannot be transferred. When the surface electrostatic charge accumulates to a certain extent, it will bring serious dangers, such as dust collection, discharge, breakdown, Even burn or explode,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08K9/08C08K9/04C08K3/04C08K3/22C08J5/18
CPCC08J5/18C08J2323/12C08K9/04C08K9/08C08K2003/2296C08K2201/017C08K3/042
Inventor 郑玉婴王禧
Owner FUZHOU UNIV
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