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Scratch-resistant black ink for matte insulating high-shading electronic film

A black ink, high shading technology, applied in the direction of ink, application, household appliances, etc., can solve the problems of easy anti-sticking, high viscosity, etc., to solve the effect of scratch resistance, less oil absorption, and good adhesion

Inactive Publication Date: 2020-08-07
BAUHINIA VARIEGATA INK ZHEJIANG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Strictly speaking, carbon black and silicon dioxide are not high insulating substances. The ink needs to achieve matte and high shading performance. The carbon black in the ink formula should basically reach more than 12%, and the silicon dioxide should basically reach more than 1%. Such a conventional formula It is impossible to achieve a resistance greater than 10 12 In order to achieve the corresponding covering rate, the thickness of the ink is generally 2 microns or above. Matt powder and carbon black are both high oil absorption powder substances. In order to balance the adhesion requirements of the ink formula to the PET printing substrate, a large amount must be added Polyurethane or polyester resin improves adhesion, polyester or polyurethane resin is more viscous, and it is easy to reverse stick when the printing ink layer is thicker than 2 microns

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A scratch-resistant matte insulating high-shading electronic film black ink, prepared from raw materials containing the following parts by weight: solvent 60, the solvent is ethyl acetate, n-propyl acetate, butyl acetate or isopropanol, Matting agent 1, the matting agent is kaolin or titanium dioxide, wetting and dispersing agent 1, the wetting and dispersing agent is an existing conventional product in the prior art, which can be purchased in the conventional market, such as: can be purchased from Lubrizol, trade name Wetting and dispersing agent, product number 24000, carbon black 3, polyurethane resin 10, heat-expandable microspheres 2, the expansion temperature of heat-expandable microspheres 2 is 80°C, heat-expandable microspheres are acrylonitrile polymer plastic materials, butyl glycidyl ether 3. Prepared by a method comprising the following steps:

[0021] The first step: fully mix and dissolve solvent 60, matting agent 1, and wetting and dispersing agent 1 by s...

Embodiment 2

[0026] A scratch-resistant matte insulating high-shading electronic film black ink, prepared from raw materials containing the following parts by weight: solvent 65, the solvent is ethyl acetate, n-propyl acetate, butyl acetate or isopropanol, Matting agent 1.5, matting agent is kaolin or titanium dioxide, wetting and dispersing agent 1.5, wetting and dispersing agent is existing conventional product in the prior art, can be purchased in conventional market, for example: can be purchased from Lubrizol Company, trade name Wetting and dispersing agent, product number 24000, carbon black 4.5, polyurethane resin 12, heat-expandable microspheres 2.5, the expansion temperature of heat-expandable microspheres 2.5 is 85°C, heat-expandable microspheres are acrylonitrile polymer plastic materials, butyl glycidol Ether 4.5, prepared by a method comprising the following steps:

[0027] The first step: fully mix and dissolve solvent 65, matting agent 1.5, and wetting and dispersing agent 1...

Embodiment 3

[0032] A kind of black ink for scratch-resistant matte insulating high light-shielding electronic film, prepared from the raw materials containing the following parts by weight: solvent 70, the solvent is ethyl acetate, n-propyl acetate, butyl acetate or isopropanol, Matting agent 2, the matting agent is kaolin or titanium dioxide, wetting and dispersing agent 2, the wetting and dispersing agent is an existing conventional product in the prior art, which can be purchased in the conventional market, such as: can be purchased from Lubrizol, trade name Wetting and dispersing agent, product number 24000, carbon black 6, polyurethane resin 15, heat-expandable microspheres 3, the expansion temperature of heat-expandable microspheres 3 is 90°C, heat-expandable microspheres are made of acrylonitrile polymer plastic material, butyl glycidol Ether 6, prepared by a method comprising the following steps:

[0033] Step 1: Fully mix and dissolve solvent 70, matting agent 2, and wetting and ...

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Abstract

The invention relates to the technical field of fine chemical engineering, in particular to scratch-resistant black ink for a matte insulating high-shading electronic film, which is prepared from thefollowing raw materials in parts by weight: 60-70 parts of solvent, 1-2 parts of delustering agent, 1-2 parts of wetting dispersant, 3-6 parts of carbon black, 10-15 parts of polyurethane resin, 2-3 parts of thermal expansion microspheres and 3-6 parts of butyl glycidyl ether. According to the invention, the use of matt powder in the formula can be greatly reduced, the part protruding out of the ink film layer has excellent scratch resistance, and the problem that matt insulating black ink is not scratch-resistant can be well solved. Relatively good adhesive force can be achieved by using relatively small amount of resin. The problems of low insulativity and easy reverse adhesion of the original scheme can be solved. The resistance of the printed electronic film can be effectively improveddue to the facts that a plurality of tiny holes are generated between the first ink layer and the second ink layer due to unevenness and a large number of tiny holes caused by expansion microspheresexist in the ink layer. The ink consumption of customers can be saved, and the cost is saved.

Description

technical field [0001] The invention relates to the technical field of fine chemicals, in particular to a black ink for a scratch-resistant matte insulating high-shading electronic film. Background technique [0002] The existing matte electronic insulating black ink uses a large amount of matte powder (silicon dioxide) in order to achieve a matte effect with a glossiness of 0 (tested at a 60-degree angle of the gloss meter). A large amount of matte powder causes more matte powder after ink film formation It floats on the surface of the ink layer and is not highly combined with the resin components of the ink. Lightly scratched by nails will cause obvious scratches. At the same time, in order to achieve high shading requirements, a large amount of carbon black is also added to the formula. Strictly speaking, carbon black and silicon dioxide are not high insulating substances. The ink needs to achieve matte and high shading performance. The carbon black in the ink formula sh...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/03C09D11/10
CPCC09D11/03C09D11/10
Inventor 施泓豪
Owner BAUHINIA VARIEGATA INK ZHEJIANG
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