Semi-interpenetrating network gel plugging material for oil and gas fields and preparation method thereof
A technology of semi-interpenetrating network and leak-stopping material, which is applied in the field of semi-interpenetrating network gel leak-stopping material and preparation field for oil and gas fields, can solve the problem of cracked and karst leakage without breakthrough progress, and the gel strength is difficult to achieve Effective plugging, difficult to control cross-linking time, etc., to achieve the effects of excellent penetration ability, improved jelly strength and shear toughness, improved success rate and pressure bearing capacity
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[0032] According to another aspect of the present application, there is also provided a method for preparing the above-mentioned plugging material, which includes the following steps: S1: dissolving the antioxidant in water to form solution A; S2: dissolving the polyacrylamide polymer , polyvinylpyrrolidone and cross-linking agent are dispersed into the solution A according to the proportion and mixed evenly to obtain the base liquid of the semi-IPN gel plugging material; S3: the base liquid of the semi-IPN gel plugging material After reacting for 8-12 hours, cross-link to obtain the semi-interpenetrating network gel plugging material.
[0033] In order to simulate the natural environment, fully dissolve the polyacrylamide polymer, polyvinylpyrrolidone and cross-linking agent, and mix them uniformly with the solution A, preferably, the polyacrylamide polymer, polyvinyl When the vinylpyrrolidone and cross-linking agent are dispersed into the solution A according to the proporti...
Embodiment 1
[0039] Dissolve 0.1wt% thiourea in water. Then, 4wt% of acrylamide and 2-acrylamide-2-methylpropanesulfonic acid copolymer (P(AM-co-AMPS)) with a molecular weight of 250,000 and a degree of hydrolysis of 10wt% and 0.2wt% of K90 polyvinylpyrrolidone, 0.5wt% water-soluble phenolic resin cross-linking agent, 0.1% chromium acetate are fully mixed and then dispersed into clear water, continuously stirred for 0.5-1h to fully dissolve, at 20-60°C circulation temperature, 8- After 12 hours, the semi-interpenetrating network gel plugging material was obtained by cross-linking.
Embodiment 2
[0041] Dissolve 0.2wt% sodium bisulfite in clear water. Then, 1 wt% of acrylamide with a molecular weight of 2 million and a degree of hydrolysis of 5 wt% was cross-linked with acrylic acid (P(AM-co-AA)), 5 wt% of K15 polyvinylpyrrolidone, and 0.3 wt% of water-soluble phenolic resin agent and 0.05% aluminum citrate cross-linking agent are mixed and dispersed into clean water, and continuously stirred for 0.5-1h to fully dissolve, and at a circulating temperature of 90-120°C, cross-link after 8-12h to obtain a semi-interpenetrating network gel plug Leakage material.
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