Alkali-free liquid accelerator and preparation method thereof
A technology of quick-setting agent and liquid, applied in the field of alkali-free liquid quick-setting agent and its preparation, can solve the problems of strong alkalinity, difficult preservation and high cost, and achieve the effects of easy preservation, low cost and early strength improvement
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Embodiment 1
[0023] An embodiment of the present invention is a non-alkali liquid quick-setting agent, comprising the following components in parts by weight: 300 grams of polyaluminum sulfate, 50 grams of ferrous sulfate, 1 gram of oxalic acid, 10 grams of triisopropanolamine, 10 grams of sodium fluoride, 1 gram of polyacrylamide and a reagent carrier, the above-mentioned components are mixed with the reagent carrier to form a solvent; wherein triisopropanolamine and sodium fluoride all have coagulation-promoting effects on concrete, but they have no effect on concrete. The coagulation-accelerating effects of soil are not all the same, and more importantly, they have different effects on the strength of concrete, so it should not be considered that every chemical substance can be used as a material for configuring accelerators.
[0024] Among them, polyaluminum sulfate is the main component of coagulation accelerator, because it contains the basic substance "aluminum ion" for coagulation a...
Embodiment 2
[0034] Based on the above-mentioned embodiment, an embodiment of the present invention is a non-alkali liquid quick-setting agent, comprising the following components in parts by weight: 350 grams of polyaluminum sulfate, 60 grams of ferrous sulfate, 5 grams of oxalic acid, triisopropyl 20 grams of alcohol amine, 20 grams of sodium fluoride, 5 grams of polyacrylamide and reagent carrier, and the rest is water.
[0035] Among them, the alcohol amine in triisopropanolamine can be miscible with water, and its molecule contains a nitrogen atom, and there is a lone pair of electrons on the nitrogen atom, thereby forming a covalent bond with some metal ions with empty orbitals, and complexing to form Stable soluble complex ion.
[0036] Appropriately increasing the content of triisopropanolamine will improve the grinding aid effect, and its triisopropanolamine can stimulate the chemical reaction between the substance and Ca, Si, Al, etc. At the same time, it causes the lattice defe...
Embodiment 3
[0039] Based on the above-mentioned embodiment, an embodiment of the present invention is a non-alkali liquid quick-setting agent, comprising the following components in parts by weight: 400 grams of polyaluminum sulfate, 70 grams of ferrous sulfate, 10 grams of oxalic acid, triisopropyl 30 grams of alcohol amine, 30 grams of sodium fluoride, 10 grams of polyacrylamide and reagent carrier, and the rest is water.
[0040] Among them, the amount of polyaluminum sulfate is the main cost, and its water-cement ratio is 0.3. The experiment is carried out on the influence of the setting time of the concrete paste. The experimental method is carried out in accordance with the standard of JC477-2005 "Accelerator for Shotcrete". The powdery raw materials are all ground with a mortar and passed through a 0.08mm square hole sieve. After accurate weighing, they are firstly mixed with concrete and then mixed with water; liquid raw materials are first mixed with weighed water and then mixed wit...
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