Composite biological degreasing agent and application thereof

A degreasing agent and biological technology, applied in the field of leather degreasing, can solve the problems of incomplete degreasing, oily frost on the leather surface, low degreasing rate of acid lipase, etc., and achieve the effect of reducing pollution and reducing dosage

Inactive Publication Date: 2020-08-28
SHANGHAI GOLD LION CHEM CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, for oil-rich animal skins such as sheep skin and pig skin, which have a large oil content, the previous degreasing treatment usually cannot completely degrease, resulting in a large amount of unremoved skin embryos in the state of sour skin and wet blue skin. Grease, if not supplemented with degreasing, it will lead to poor tanning quality, such as oily frost on the leather surface, uneven dyeing, etc., so it is necessary to supplement degreasing acid leather and wet blue leather under acidic conditions
[0003] The applicant has found that the prior art has at least the following technical problems: the current method of skin germ treatment in the state of sour leather and wet blue leather is to use a large amount of surfactants for degreasing, but the use of a large amount of surfactants in the tanning process will pollute the environment cause greater impact
However, the lipase preparations currently used in tanning are mainly used for degreasing under neutral and alkaline conditions, and are not suitable for acid leather and wet blue leather.
Although acid lipase can meet the supplementary degreasing treatment of acid hide and wet blue hide under acidic conditions, the degreasing rate of acid lipase alone is not high

Method used

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  • Composite biological degreasing agent and application thereof
  • Composite biological degreasing agent and application thereof
  • Composite biological degreasing agent and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] The preparation process of the composite biological degreasing agent of present embodiment 1 is as follows:

[0042] The compound biological degreasing agent of present embodiment 1 comprises the component of following weight portion:

[0043] 20 parts of acid lipase;

[0044] Nonionic surfactant: 20 parts of BASF TO-8;

[0045] Enzyme activator: 0.1 parts of calcium chloride;

[0046] Enzyme stabilizer: 8 parts of propylene glycol, 2.5 parts of 4-formylphenylboronic acid (4-FPBA);

[0047] pH stabilizer: 4.5 parts of sodium citrate;

[0048] Preservative: 0.1 parts of Kasong;

[0049] The rest is water.

[0050] Mix the above components uniformly to obtain the acid lipase-based composite biological degreasing agent of the present embodiment 1.

[0051] Table 1 shows the application of the compound biological degreasing agent prepared in Example 1 and the market product 1 as a comparative experiment to the degreasing treatment process of sheep wet blue hide rich i...

Embodiment 2

[0059] The preparation process of the composite biological degreasing agent of present embodiment 2 is as follows:

[0060] The compound biological degreasing agent of present embodiment 2 comprises the component of following weight portion:

[0061] 25 parts of acid lipase;

[0062] Nonionic surfactant: 20 parts of BASF XL-90;

[0063] Enzyme activator: 0.15 parts of calcium chloride;

[0064] Enzyme stabilizer: 8.5 parts of propylene glycol, 3.0 parts of 4-formylphenylboronic acid (4-FPBA);

[0065] pH stabilizer: 5 parts of sodium citrate;

[0066] Preservative: 0.1 parts of Kasong;

[0067] The rest is water.

[0068] Mix the above components evenly to obtain the acid lipase-based composite biological degreasing agent of the present embodiment 2.

[0069] Table 3 shows that the compound biological degreasing agent prepared in Example 2 and the market product 2 were used as a comparative experiment in the degreasing process of sheep wet blue hide rich in oil. Among the...

Embodiment 3

[0078] The preparation process of the composite biological degreasing agent of present embodiment 3 is as follows:

[0079] The composite biological degreasing agent of present embodiment 3 comprises the component of following weight portion:

[0080] 15 parts of acid lipase;

[0081] Nonionic surfactant: 25 parts of BASF AEO-9;

[0082] Enzyme activator: 0.1 parts of calcium chloride;

[0083] Enzyme stabilizer: 7.5 parts of propylene glycol, 2.0 parts of 4-formylphenylboronic acid (4-FPBA);

[0084] pH stabilizer: 4 parts of sodium citrate;

[0085] Preservative: 0.1 parts of Kasong;

[0086] The rest is water.

[0087] Mix the above components evenly to obtain the acid lipase-based composite biological degreasing agent of the present embodiment 3.

[0088] Table 5 shows that the composite biological degreasing agent prepared in Example 3 and the market product 3 were used as a comparative experiment in the degreasing process of wet blue sheep hides rich in oil. Among...

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Abstract

The invention provides a composite biological degreasing agent and application thereof, and relates to the technical field of leather degreasing. The composite biological degreasing agent comprises the following components in parts by weight: 15-35 parts of acidic lipase and 10 to 25 parts of a surfactant. The composite biological degreasing agent disclosed by the invention is mainly prepared fromthe acidic lipase; the grease degrading effect of the acid lipase under the acid condition and the emulsifying effect of the surfactant can be utilized; when pickled hide and wet blue leather are subjected to supplementary degreasing treatment, the synergistic effect of degreasing by a biological method and a chemical method is achieved, and the purpose of efficient degreasing under an acidic condition is achieved, so that crusts such as the pickled hide or the wet blue leather meet the requirements of subsequent tanning processing.

Description

technical field [0001] The invention relates to the technical field of leather degreasing, in particular to a composite biological degreasing agent and its application. Background technique [0002] Leather is denatured and non-perishable animal skin obtained through physical and chemical processing such as depilation and tanning. Degreasing is an essential process in tanning or fur processing. Only by removing the natural oil contained in animal skins to a certain extent can the collagen fibers in the leather be loosened, creating favorable conditions for the smooth progress of subsequent tanning and other processes. . However, for oil-rich animal skins such as sheep skin and pig skin, which have a large oil content, the previous degreasing treatment usually cannot completely degrease, resulting in a large amount of unremoved skin embryos in the state of sour skin and wet blue skin. Grease, if supplementary degreasing is not carried out, it will lead to poor quality of ta...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C11D1/72C11D3/386C11D3/04C11D3/20C11D3/34C11D3/60C14C5/00
CPCC11D1/008C11D1/72C11D3/046C11D3/166C11D3/2041C11D3/2086C11D3/349C11D3/38627C14C5/00
Inventor 严亚楠许冰斌刘淑萍
Owner SHANGHAI GOLD LION CHEM CO LTD
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