Conductive polymer hollow sphere PACP@ titanium carbide composite material and preparation method thereof

A technology of conductive polymers and composite materials, which is applied in the manufacture of hybrid/electric double layer capacitors and electrodes of hybrid capacitors. Effects of Particle Transport and Diffusion

Active Publication Date: 2020-09-04
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to overcome the shortcomings of the above-mentioned prior art, to provide a conductive p

Method used

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  • Conductive polymer hollow sphere PACP@ titanium carbide composite material and preparation method thereof
  • Conductive polymer hollow sphere PACP@ titanium carbide composite material and preparation method thereof
  • Conductive polymer hollow sphere PACP@ titanium carbide composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Step 1, Lamellar Ti 3 C 2 preparation of

[0038] Weigh 2g of LiF and 20mL of 9M HCl (specifically, 15mL of concentrated HCl+5mL of water with a mass concentration of 36% and 15mL of concentrated HCl+5mL of water) into a 50mL polytetrafluoroethylene beaker and stir for 10min to make the LiF disperse into hydrochloric acid solution, slowly add 2g of Ti 3 AlC 2 , magnetically stirred for 24 h to obtain reaction solution A. Wash the reaction solution A with ionic water until the pH>6, then centrifuge, dissolve the centrifuged precipitate in 300mL ultrapure water to obtain the dispersion B, carry out the vacuum deoxygenation of the dispersion B for 2 hours, and then ultrasonically treat it for 1 hour , centrifuged for 1 h, and the supernatant after centrifugation was freeze-dried to obtain sheet Ti 3 C 2 Powder.

[0039] Step 2, prepare PACP mixture

[0040] Weigh 0.38mL of aniline and 0.29mL of pyrrole and mix them in a beaker, add 60mL of deionized water and 0.06g...

Embodiment 2

[0046] Step 1, Lamellar Ti 3 C 2 preparation of

[0047] Weigh 2g of LiF and 20mL of 9M HCl (specifically, 15mL of concentrated HCl+5mL of water with a mass concentration of 36% and 15mL of concentrated HCl+5mL of water) into a 50mL polytetrafluoroethylene beaker and stir for 10min to make the LiF disperse into hydrochloric acid solution, slowly add 2g of Ti 3 AlC 2 , magnetically stirred for 24 h to obtain reaction solution A. Wash the reaction solution A with ionic water until the pH>6, then centrifuge, dissolve the centrifuged precipitate in 300mL of ultrapure water to obtain the dispersion B, carry out the vacuum deoxygenation of the dispersion B for 2 hours, and then ultrasonically treat it for 1 hour , centrifuged for 1 h, and the supernatant after centrifugation was freeze-dried to obtain sheet Ti 3 C 2 Powder.

[0048] Step 2, prepare PACP mixture

[0049] Weigh 0.38mL of aniline and 0.29mL of pyrrole and mix them in a beaker, add 60mL of deionized water and 0....

Embodiment 3

[0053] Step 1, Lamellar Ti 3 C 2 preparation of

[0054] Weigh 2g of LiF and 20mL of 9M HCl (specifically, 15mL of concentrated HCl+5mL of water with a mass concentration of 36% and 15mL of concentrated HCl+5mL of water) into a 50mL polytetrafluoroethylene beaker, and stir for 10min to make LiF evenly disperse into hydrochloric acid solution, slowly add 2g of Ti 3 AlC 2 , magnetically stirred for 24 h to obtain reaction solution A. Wash the reaction solution A with ionic water until the pH>6, then centrifuge, dissolve the centrifuged precipitate in 300mL ultrapure water to obtain the dispersion B, carry out the vacuum deoxygenation of the dispersion B for 2 hours, and then ultrasonically treat it for 1 hour , centrifuged for 1 h, and the supernatant after centrifugation was freeze-dried to obtain sheet Ti 3 C 2 Powder.

[0055] Step 2, prepare PACP mixture

[0056] Weigh 0.38mL of aniline and 0.29mL of pyrrole and mix them in a beaker, add 60mL of deionized water and 0...

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Abstract

The invention discloses a conductive polymer hollow sphere PACP@ titanium carbide composite material and a preparation method thereof. According to the preparation method, a PACP (a copolymer of polyaniline PANI and polypyrrole PPy) and ultrathin titanium carbide are compounded through a chemical oxidation method under a low-temperature condition to obtain a Ti3C2@ PACP hollow sphere nano composite material as an electrode material of a supercapacitor, an in-situ polymerization method is simple to operate, efficient and environment-friendly, and the hollow spherical PACP and the layered ultrathin Ti3C2 are compounded, so that the hollow spherical PACP and the layered ultrathin Ti3C2 can be in more sufficient contact, the specific surface area is larger, the particle transmission, diffusionand the like are better facilitated, and the energy storage performance of the conductive polymer hollow sphere PACP@ titanium carbide composite material used for the supercapacitor electrode is improved.

Description

【Technical field】 [0001] The invention belongs to the technical field of supercapacitor electrode material preparation, and in particular relates to a conductive polymer hollow sphere PACP@titanium carbide composite material and a preparation method thereof. 【Background technique】 [0002] The loss of global fossil energy and the aggravation of environmental problems have stimulated people's interest in developing green new energy. As a new type of energy storage device, supercapacitors have attracted widespread attention due to their outstanding advantages. Compared with traditional batteries, supercapacitors have many advantages such as short charging time, outstanding cycle stability, high safety, simple assembly, high power performance, and good reversibility, and have attracted extensive attention from scientific researchers. Undoubtedly, in the near future, supercapacitors will be found in all aspects of people's lives, ranging from clothing, housing and transportation...

Claims

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Application Information

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IPC IPC(8): H01G11/24H01G11/30H01G11/48H01G11/86
CPCH01G11/24H01G11/30H01G11/48H01G11/86Y02E60/13
Inventor 武文玲柴玉梅赵春辉王成威刘恬甜卫丹朱建锋方园
Owner SHAANXI UNIV OF SCI & TECH
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