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Polyamide material with excellent appearance, low water absorption and self-tapping slipping resistance, preparation method and application thereof

A low water absorption and polyamide technology, applied in the field of polymer materials, can solve the problems of not meeting the application requirements of electric kettle thermostats, not comprehensively considering the appearance of finished products, self-tapping slippery wire, and material fluidity decline, etc., to achieve reduction The risk of high torque self-tapping slippery wire, the improvement of serious appearance problems of floating fibers, and the effect of low water absorption

Active Publication Date: 2020-09-11
中广核俊尔(浙江)新材料有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The above-mentioned prior art is more effective in reducing the water absorption of polyamide materials, but the specific solutions are only suitable for special application fields, such as fiber reinforced and mineral-filled nylon, which will lead to a decrease in material toughness, especially when the water absorption rate is high when the glass fiber content is high. A phenomenon that decreases but causes apparent floating fibers in the material
However, through PP or ABS alloy, although the water absorption rate can be significantly reduced, it will cause the material to be soft, the modulus will decrease significantly, and the fluidity of the material will decrease, which will affect the appearance of the material.
In addition to the water absorption rate, the current material improvement plan does not comprehensively consider the appearance of the finished product and the self-tapping slippery wire when the polyamide material is assembled and locked, and there are no case reports that meet the application requirements in the field of electric kettle thermostats.

Method used

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  • Polyamide material with excellent appearance, low water absorption and self-tapping slipping resistance, preparation method and application thereof
  • Polyamide material with excellent appearance, low water absorption and self-tapping slipping resistance, preparation method and application thereof
  • Polyamide material with excellent appearance, low water absorption and self-tapping slipping resistance, preparation method and application thereof

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Embodiment Construction

[0031] Below in conjunction with specific embodiment, further illustrate the present invention. It should be understood that these examples are only used to illustrate the present invention and are not intended to limit the scope of the present invention. The operating methods not indicated in the following examples are generally in accordance with conventional conditions, or in accordance with the conditions suggested by the manufacturer.

[0032] The raw materials used in the following examples and comparative examples are as follows:

[0033] PA66: EPR24 China Shenma Group Co., Ltd.

[0034] PA6: M2000 Guangdong Xinhui Meida Nylon Co., Ltd.

[0035] Microencapsulated red phosphorus flame retardant masterbatch: RPM450 provided by China Blue Chenguang Chemical Research Institute Co., Ltd.

[0036] Glass fiber: ECS11--4.5--568H, Jushi Group Co., Ltd.

[0037] Compatibilizer:

[0038] Maleic anhydride grafted EPDM rubber (EPDM-g-MAH), commercially available

[0039] Malei...

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Abstract

The invention discloses a polyamide material with excellent appearance, low water absorption and self-tapping slipping resistance, a preparation method and application of the polyamide material to preparation of an electric kettle temperature controller. The polyamide material is prepared from the following raw materials by weight percentage: 25-35% of PA66, 0-15% of PA6, 30-40% of a reinforcing component, 5-15% of microencapsulated red phosphorus flame-retardant master batch, 3-8% of a compatilizer, 0.2-2% of a self-tapping slipping resistant aid and 3-8% of other aids; wherein the compatilizer is at least one of polypropylene grafted maleic anhydride and polyethylene grafted maleic anhydride, and the melt index of the compatilizer is 35-150g / 10min under the conditions of 190DEG C and 1.2kg; and the self-tapping slipping resistant aid is prepared from calcium aryl sulfonate and nano zirconium oxide. The preparation method comprises the following steps of: uniformly blending the raw material components except the reinforcing component according to a ratio to obtain a premix, adding the premix into a double-screw extruder from a feeding port, adding the reinforcing component from afirst exhaust port of the double-screw extruder, and carrying out melt extrusion, cooling, drying and pelletizing to obtain the polyamide material.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a polyamide material with excellent appearance, low water absorption and self-tapping slip resistance, and a preparation method and application thereof. Background technique [0002] Polyamide (PA), commonly known as nylon, can be prepared by ring-opening polymerization of lactam or by polymerization of dibasic acid monomer and diamine monomer. It has excellent mechanical properties, excellent barrier properties, high heat resistance, high resistance to Excellent comprehensive properties such as abrasion resistance and high chemical corrosion resistance, are widely used in automobiles, electric tools, electronic appliances, smart home appliances and other fields. However, polyamide also has disadvantages such as the decline of mechanical and electrical properties after water absorption, and the slippage of high-torque self-tapping screws after locking, so it is necessar...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/06C08L77/02C08L51/06C08L83/04C08K13/06C08K9/10C08K3/02C08K7/14C08K3/22C08K3/04C08K5/42
CPCC08L77/06C08L2205/08C08L2201/02C08L2310/00C08L2205/02C08L2205/035C08L2203/20C08K2201/011C08K2003/2244C08K2201/005C08K2003/2224C08K2003/026C08L77/02C08L51/06C08L83/04C08K13/06C08K9/10C08K3/02C08K7/14C08K3/22C08K3/04C08K5/42
Inventor 林立田际波郑友明陈佰全陈智文王金松
Owner 中广核俊尔(浙江)新材料有限公司
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