Photocurable thermosetting resin composition, dry film, cured product and printed wiring board
A technology of curable resin and photosensitive resin, applied in secondary processing of printed circuits, optics, opto-mechanical equipment, etc., can solve the problems of reduced alkali developability and brittleness of cured products, and achieve the effect of excellent insulation reliability
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[0156] Hereinafter, although an Example demonstrates this invention in more detail, this invention is not limited to an Example. In addition, the following "part" and "%" are all based on mass unless otherwise specified.
[0157] The radically polymerizable polymers of Synthesis Examples 1 to 7 shown below were synthesized. It should be noted that Synthesis Examples 6 and 7 are radically polymerizable polymers other than the radically polymerizable polymer contained in the (A) carboxyl group-containing photosensitive resin in the curable resin composition of the present invention, that is, It is a radically polymerizable polymer used in a comparative example.
Synthetic example 1
[0159] 81.5 parts of carbitol acetates were put into the detachable flask with the condenser used as a reaction tank, and it heated up to 80 degreeC after replacing with nitrogen. On the other hand, drop in respectively: 30 parts of N-phenylmaleimide and 120 parts of carbitol acetate were mixed in the dropping tank 1, and 29 parts of styrene were mixed in the dropping tank 2. 20 parts of 2-hydroxyethyl methacrylate, 21 parts of acrylic acid and 10.6 parts of carbitol acetate were mixed in the dropping tank 3, and the mixture was mixed in the dropping tank 4 as 10 parts of LUPEROX 11 (trade name; ARKEMA Yoshitomi, Ltd. product, hydrocarbon solution containing 70% tert-butyl peroxypivalate) and 21.2 parts of carbitol acetate as a polymerization initiator. While maintaining the reaction temperature at 80°C, it was added dropwise from the dropping tanks 1, 2, and 4 over 3 hours, and from the dropping tank 3 over 2.5 hours. After completion of the dropwise addition, the reaction w...
Synthetic example 2
[0163] 81.5 parts of propylene glycol monomethyl ether acetates were put into the detachable flask with the condenser used as a reaction tank, and it heated up to 80 degreeC after replacing with nitrogen. On the other hand, put in separately: 30 parts of N-phenylmaleimide and 120 parts of propylene glycol monomethyl ether acetate were mixed in the dropping tank 1, and styrene was mixed in the dropping tank 2. 28.5 parts, 20 parts of 2-hydroxyethyl methacrylate, mixed with 21.5 parts of acrylic acid, 10.6 parts of propylene glycol monomethyl ether acetate in the dropping tank 3, mixed with 10 parts of LUPEROX 11 as a polymerization initiator and 21.2 parts of propylene glycol monomethyl ether acetate. While maintaining the reaction temperature at 80°C, it was added dropwise from the dropping tanks 1, 2, and 4 over 3 hours, and from the dropping tank 3 over 2.5 hours. After completion of the dropwise addition, the reaction was further continued at 80° C. for 30 minutes. Therea...
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