625 results about "Epoxide Compound" patented technology

The invention discloses a preparation method of a crown ether functionalized anti-pollution nanofiltration membrane, which comprises the following steps: soaking a membrane of a commercial nanofiltration membrane in pure water, and coating the surface with a double-end epoxy compound ethanol solution; uniformly coating the surface of the membrane with an aza 12-crown-4 methanol solution; and drying the membrane in an atmosphere of 40-90 DEG C to obtain the crown ether functionalized anti-pollution nanofiltration membrane. The nano-filtration membrane is realized by chemically grafting aza 12-crown-4 on the membrane surface of a commercial nano-filtration membrane by utilizing a double-end epoxy compound; compared with a traditional nanofiltration membrane, the crown ether functionalized nanofiltration membrane provided by the invention has the advantages that the electronegativity of the surface is reduced, and the surface is similar to an aquatic plant molecular brush structure, so that the deposition of pollutants on the surface of the membrane can be effectively improved, and the anti-pollution performance of the membrane is enhanced; meanwhile, due to the complexing effect of 12-crown-4 molecules on lithium ions, the lithium ions can be effectively captured, concentration polarization of the lithium ions on the surface of the diaphragm is improved, and then the magnesium-lithium separation efficiency of the diaphragm is improved.

The invention provides highly phase-separated polyurethane as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials. The highly-phase-separated polyurethane is prepared from the following raw materials: hydrophilic modified polyether polyol, an isocyanate monomer, a catalyst and a chain extender, the hydrophilic modified polyether polyol is prepared from the following raw materials: a ring-opening initiator and an epoxy compound; the ring-opening initiator comprises dihydroxy carboxylic acid and / or dihydroxy sulfonate. The highly-phase-separated polyurethane is clear and stable in microphase structure and has excellent mechanical properties and water resistance.

The invention belongs to the technical field of flame-retardant polyether polyol, and particularly relates to a preparation method and application of multi-element synergistic reaction type anti-dripping flame-retardant polyether polyol. The preparation method of the multi-element synergistic reaction type anti-dripping flame-retardant polyether polyol comprises the following steps: taking phosphorus-containing polyether polyol and a nitrogen-containing compound as composite initiators, and carrying out polymerization reaction on the phosphorus-containing polyether polyol and the nitrogen-containing compound and an epoxy compound under the self-catalysis action to obtain the reaction type anti-dripping flame-retardant polyether polyol. According to the preparation method of the multi-element synergistic reaction type anti-dripping flame-retardant polyether polyol provided by the invention, phosphorus, nitrogen and chlorine elements are embedded into the polyether polyol by constructing a ternary synergistic system, so that the problems of poor compatibility, migration and precipitation of an externally added flame-retardant system are solved; in the preparation process, low-cost bio-based phytic acid is adopted as a raw material, no catalyst needs to be introduced, the operation is simple, the prepared polyether polyol is used for preparing a waterborne polyurethane film, the flame-retardant characteristic of the material is improved, and meanwhile, the good anti-dripping characteristic is achieved.

The invention discloses a fluorine-containing super-hydrophobic coating and a preparation process thereof, and relates to the technical field of hydrophobic coatings. The fluorine-containing super-hydrophobic coating is prepared from the following components in parts by mass: 60 to 80 parts of composite fluorine-containing resin, 5 to 15 parts of filler and 5 to 10 parts of curing agent, the composite fluorine-containing resin is obtained by blending epoxy resin and a fluorine-containing esterified epoxy compound. The preparation method comprises the following steps: blending epoxy resin and a fluorine-containing esterified epoxy compound to obtain composite fluorine-containing resin; the low surface energy of a fluorine-containing esterified epoxy compound and the good adhesiveness of epoxy resin are utilized, in the coating curing process, fluorine chain segments migrate to the surface of a coating, the surface energy of the coating is reduced, the epoxy resin is subjected to a cross-linking reaction under the action of a curing agent, and the problem that the adhesive force of the coating is poor is solved; after curing, a tighter and firmer three-dimensional network structure is formed, the cross-linking strength of the coating is improved, and the hydrophobicity and cracking resistance of the coating are comprehensively improved.

The invention discloses a thermoplastic epoxy polymer with a micro-cross-linked structure and a preparation method thereof.The preparation method comprises the steps that in the step-by-step polymerization reaction process of thermoplastic epoxy resin, firstly, epoxy or amino or hydroxyl-terminated thermoplastic epoxy resin is obtained by controlling the group molar ratio and the reaction time of raw materials; when the molecular weight of a reaction product reaches a certain degree, polyfunctional epoxy compounds, amines, acid anhydrides, phenols and other compounds are introduced, and the thermoplastic epoxy resin with a micro-crosslinking structure is obtained through chain extension. The glass transition temperature of the thermoplastic epoxy polymer with the micro-crosslinking structure is obviously higher than that of a linear thermoplastic epoxy polymer of the same type. Compared with thermoplastic epoxy polymers of the same type, the thermoplastic epoxy polymer with the micro-crosslinking structure prepared by the invention still has the characteristics of thermoplasticity, capability of being melted by heating, capability of being dissolved by a solvent and the like.

The invention provides an asphalt regenerant, application thereof and a regeneration method of waste asphalt, and belongs to the technical field of pavement materials. The asphalt regenerant comprises the following raw materials in parts by mass: 6-12 parts of an epoxy compound, 0.5-2 parts of an adhesion promoter, 2-5 parts of a curing agent and 83-92 parts of a diluent, wherein the epoxy compound comprises polyurethane modified epoxy resin. According to the invention, the flexible epoxy compound polyurethane modified epoxy resin is introduced and acts together with the curing agent, so that the warm mixing effect of the asphalt regenerant at low temperature (110-115 DEG C) is improved, the regeneration effect can be ensured, and meanwhile, the reinforcing and toughening effects can be achieved through curing of the epoxy group; the high-temperature performance, the low-temperature performance, the water stability and the durability of the recycled asphalt mixture can be effectively improved, and the energy consumption and the carbon emission in the production and construction process can be reduced.

An adhesive composition (100) comprises: a polyester resin (A) that includes an ester bond which bonds repeating units together and one or more functional groups selected from the group consisting of carboxy groups and carboxylic acid anhydride structures; an epoxy compound (B) in the amount of 1-50 parts by mass with respect to 100 parts by mass of the polyester resin (A); and a cyclic carbodiimide (C) in the amount of 0.1-20 parts by mass with respect to 100 parts by mass of the polyester resin (A).

To provide a resin composition capable of improving flowability of the resin composition and crack resistance of a cured product thereof.SOLUTION: A resin composition contains an epoxy compound (A), a liquid aromatic amine compound (B), and an inorganic filler (C). The epoxy compound (A) contains a liquid epoxy compound (A1) and a solid epoxy compound (A2). The solid epoxy compound (A2) contains a solid epoxy resin (a) which is at least one kind selected from a group consisting of an isocyanate modified epoxy resin, a naphthalene type epoxy resin, and a biphenyl type epoxy resin. The viscosity of the resin composition at 25°C is 400 Pa s or less.SELECTED DRAWING: Figure 1

The invention relates to the field of ion exchange resin, and discloses quaternary ammonium type anion exchange resin, a preparation method and application thereof, and a catalytic hydration reaction method of an epoxy-containing compound. The anion exchange resin comprises a resin matrix # imgabs 0 # and a quaternary ammonium group connected with the resin matrix # imgabs 1 # through an alkylene group; wherein the resin matrix # imgabs2 is a hydrogenated styrene-dienylbenzene copolymer, and the styrene-dienylbenzene copolymer contains a styrene structural unit as shown in a formula (1), a dienylbenzene structural unit as shown in a formula (2), a # imgabs3 # formula (1) and a # imgabs4 # formula (2); in the formula (1), R11 is alkyl or hydrogen, and R12 is alkyl or hydrogen; in the formula (2), n is an integer between 0 and 2. The quaternary ammonium type anion exchange resin provided by the invention has excellent swelling resistance.

The invention is applicable to the technical field of polymer biomedical hydrogel materials, and provides a preparation method and application of multifunctional agarose-based particle composite hydrogel based on liquid-liquid phase separation, and the agarose-based particle composite hydrogel is a product formed by introducing microsphere particles into an agarose hydrogel body matrix; the microsphere particles are formed by a prepolymer and sodium lignin sulfonate through phase separation mediated by a composite behavior based on non-covalent interaction; the prepolymer is obtained by carrying out amine-epoxy reaction on an amino compound and an epoxy compound in water. According to the prepared agarose-based particle composite hydrogel, a microsphere particle structure is formed on the surface of an agarose matrix while positively charged amino groups and sodium lignin sulfonate are introduced, so that the multifunctional agarose-based particle composite hydrogel is prepared.

The invention discloses a preparation method and application of a catalyst based on pyridine ionic liquid, and belongs to the technical field of catalyst preparation. According to the invention, a hydrolysis reaction of a silane coupling agent is utilized to prepare a silicon oxide nanotube containing a pyridine unit, and then a quaternization reaction is carried out to obtain the catalyst based on the pyridine ionic liquid. The catalyst has a high specific surface area and a rich pore channel structure, exposure of active sites and contact of the active sites and reactants are facilitated, and the catalytic rate is increased. Meanwhile, the silicon oxide nanotube contains hydroxyl, and can cooperate with a pyridine ionic liquid site to catalyze a carbon dioxide cycloaddition reaction. The obtained catalyst can catalyze the reaction of carbon dioxide and an epoxy compound to prepare cyclic carbonate under solvent-free and metal-free conditions, and the catalyst is easy to recover and simple in product purification, and has a good application prospect.

The invention discloses a hyperbranched polyether branching agent with an adjustable structure and a preparation method and application thereof.According to the branching agent, 3-butene-1-alcohol serves as an initiator, a hyperbranched skeleton is constructed through anion ring-opening polymerization reaction and diglycidyl ether, then esterification and end capping are conducted through anhydride, and the hyperbranched polyether branching agent with the adjustable structure is obtained. The tail end of the hyperbranched polyether contains vinyl double bonds, and the ester group structure of the hyperbranched polyether can be regulated and controlled. Different diepoxy compounds are selected to control a main chain structure, and different anhydrides are used for regulating and controlling the chemical composition of branched chains, so that accurate design of molecular weight, polarity and number of functional groups of the branching agent is realized. The branching agent has excellent dissolvability in common organic solvents, and solves the problem of poor dissolvability of the traditional polydiene branching agent. When the star-shaped branched butyl rubber is applied to the synthesis of star-shaped branched butyl rubber, the distribution and number of branched points can be accurately regulated and controlled, the weight-average molecular weight and molecular weight distribution index of the rubber are remarkably improved, and the side reaction of gel is avoided.

The invention provides application of a metal ion doped aminated graphene oxide membrane material in catalyzing CO2 to synthesize cyclic carbonate. The metal ion doped aminated graphene oxide membrane material has an acidic catalytic site and an alkaline catalytic site at the same time, and a two-dimensional interlayer channel of the metal ion doped aminated graphene oxide membrane material also has a confinement effect. In the process of catalyzing a CO2 / epoxy compound cycloaddition reaction, epoxy compound molecules entering a two-dimensional interlayer confinement channel of the metal ion doped aminated graphene oxide membrane material are subjected to efficient ring opening under the combined action of organic amine molecules and metal ions and react with CO2; and finally, realizing CO2 high-efficiency (the reaction time is less than or equal to 5 minutes, and the conversion rate of the epoxy compound is 75-100%) synthesis of the cyclic carbonate under the conditions of room temperature and low pressure (greater than 0.1 MPa and less than or equal to 1 MPa).

The invention relates to a gel electrolyte and a preparation method and application thereof. The gel electrolyte is prepared from the following raw materials: a nitrogen heterocyclic gel monomer, an electrolyte and an initiator, the nitrogen heterocyclic gel monomer is prepared from the following raw materials: a nucleophilic reagent and an epoxy compound. The gel electrolyte provided by the invention is high in conductivity and good in uniformity, can realize stable circulation under 5C multiplying power, and can be well applied to a quick-charge type gel battery.

An aspect of the present disclosure relates to a photosensitive resin composition containing (A) an acid-modified vinyl group-containing resin, (B) a thermosetting resin, (C) a photopolymerization initiator, (D) a photopolymerizable compound, and (E) an elastomer, in which (B) the thermosetting resin includes a bisphenol type epoxy compound having an average molecular weight of 360 or less and (E) the elastomer includes an acrylic elastomer.

This resin composition for an optical waveguide contains an epoxy compound (A). The epoxy compound (A) contains a first epoxy compound (a1) having a norbornane structure and a second epoxy compound (a2) having a silicon structure having 1 to 6 Si. The content of the second epoxy compound (a2) is 5 to 60 parts by mass per 100 parts by mass of the first epoxy compound (a1).

The invention discloses a colorless transparent yellowing-resistant glass fiber reinforced epoxy resin prepreg and a preparation method thereof. The preparation method comprises the following steps: reacting thiol with isocyanate to prepare a sulfydryl-terminated oligomer, adding an alkenylated epoxy compound to react to prepare a sulfydryl-terminated epoxy compound, adding epoxy resin and an anhydride compound to obtain an epoxy resin prepolymer, adding a thermal initiator, a light stabilizer and an ultraviolet light absorber, and reacting to obtain the heat-resistant polyurethane resin. And coating the colorless transparent anti-yellowing epoxy resin system, and compounding with glass fibers to obtain the glass fiber reinforced epoxy resin prepreg. The prepreg provided by the invention can be cured at medium temperature, the light transmittance of a cured product is greater than or equal to 89%, and the prepreg can not become yellow outdoors for a long time, has good impact performance, and can be applied to the field of replacing glass, such as a front panel and a back panel of a photovoltaic panel.

The invention relates to a preparation method and application of an ethylene sulfite compound, and the preparation method comprises the step of reacting an epoxy compound with sulfur dioxide under the action of an immobilized organic base catalyst to obtain the ethylene sulfite compound. The immobilized organic base catalyst is formed by connecting organic base and chloromethylated resin through chemical bonds, and has good catalytic activity and chemical stability. According to the preparation method provided by the invention, the raw material cost is low, the product is easy to purify, the yield is relatively high, continuous automatic production is easy to realize, and the prepared ethylene sulfite compound is added into the lithium battery electrolyte as an additive, so that the electrochemical window of an electrolyte system can be widened, and the high-voltage interface stability and the cycle performance of the battery can be improved.

The present application discloses a polymer, a leveler and a preparation method thereof, an electroplating solution and an electroplating method, and belongs to the field of electroplating technology. The polymer includes a plurality of repeating units, and the repeating units include: a binary epoxy compound residue group and a nitrogen-containing group; the binary epoxy compound residue group is a residue formed after the epoxy bond of the binary epoxy compound is ring-opened; the nitrogen-containing group includes: an alkyl group, a dimethylamine group and a nitrogen-containing heterocyclic group connected to both ends of the alkyl group, respectively, and the dimethylamine group is also connected to the binary epoxy compound residue group through a single bond. The polymer is conducive to obtaining a highly coplanar coating at a high current density, and is particularly suitable for use as a leveler in an electroplating solution.

The invention relates to the technical field of polycarbonate polyols, and discloses a preparation method of carbon dioxide-based polycarbonate polyols, which comprises the following steps: adding an epoxy compound, a carborane derivative catalyst, a chain initiator and a chain transfer agent into a reactor, introducing carbon dioxide to replace air in the reactor, and reacting to obtain the carbon dioxide-based polycarbonate polyols. Then pressurizing, heating and stirring to carry out polymerization reaction, adding acid to terminate the reaction after the reaction is completed, and then purifying and drying to obtain the polycarbonate polyol, wherein the carborane derivative catalyst is prepared by the following preparation method: adding different substituted alkynes, decaborane, ethyl sulfide and toluene into a reaction flask in proportion in a nitrogen atmosphere, sealing the reaction flask, and heating and stirring to enable the decaborane to react with the different substituted alkynes. According to the method, a specific catalyst is used for replacing a traditional catalyst, and the reaction efficiency and the product molecular weight can be improved.

The invention provides a curable resin composition excellent in curability at low temperature for obtaining a cured product high in heat resistance, a cured product thereof, and methods of producing the curable resin composition and the cured product. Also provided is a semiconductor device using the cured product as a sealant. In particular, the invention provides a curable resin composition comprising (A) a benzoxazine compound represented by a structure of formula (1), (B) an epoxy compound, and (C) a phenol-based curing agent, wherein a number of epoxy groups in the epoxy compound (B), a number of benzoxazine rings in the benzoxazine compound (A), and a number of hydroxyl groups in the phenol-based curing agent (C) satisfy formula (2), and a ratio of the benzoxazine equivalent in the benzoxazine compound (A) to the hydroxyl group equivalent in the phenol-based curing agent (C) is 1.1 to 8.0.

The invention discloses an amido amine-based asphalt regenerant as well as a preparation method and application thereof. The amido amine-based asphalt regenerant comprises the following components in parts by weight: 20-60 parts of amido amine, 10-60 parts of a monofunctional epoxy compound and 5-30 parts of a phenolic compound. The amido amines are based on polycondensates of polyaliphatic amines and single acids. The asphalt regenerant disclosed by the invention can be used for fully regenerating waste asphalt on a washing and throwing material in a large proportion, and a product obtained after mutual reaction of the regenerant has a function of enhancing the performance of the asphalt, so that the asphalt concrete using the regenerant does not need to be degraded, and the pavement reconstruction cost is greatly reduced.

The invention relates to the technical field of biological materials, in particular to collagen gel for injection, a preparation method of the collagen gel and an injection preparation. The method comprises the following steps: providing recombinant humanized collagen subjected to alkali resistance screening, and mixing the recombinant humanized collagen with a stabilizer to prepare a collagen dispersion liquid, which comprises the following steps: activating a cross-linking agent in an alkaline activating solution to obtain an activated cross-linking agent solution; wherein the cross-linking agent is a diepoxide compound; carrying out cross-linking reaction on the activated cross-linking agent solution and the collagen dispersion liquid to form gel; wherein the mass concentration of the collagen dispersion liquid is 5-10%, and the mass ratio of the cross-linking agent to the collagen is 5-10%; the total weight percentage of the collagen and the cross-linking agent is 5.5 to 10.5 percent. The gel with a stable structure can be effectively formed when the content of the cross-linking agent is within the content range, the residual amount of the cross-linking agent is low, and the storage modulus, the swelling degree and the pushing force of the gel are excellent.

The application discloses an alkali ion type covalent organic framework material and a preparation method and application thereof, wherein 2,4,6-tris(4-formylphenyl)-1,3,5-triazine, 1,4-diisocyanobenzene and 2-aminopyridine are used as building units, a covalent organic framework containing pyrimidine is obtained through a condensation reaction, and then a quaternary ammonium reaction and an ion exchange reaction are sequentially performed to obtain the alkali ion type covalent organic framework.The alkali ion type covalent organic framework material prepared by the application has rich alkali sites, developed pore structures and good chemical stability, exhibits good catalytic performance as a catalyst for one-pot preparation of dimethyl carbonate from CO2, an epoxide compound and methanol, and also shows good cycle stability.

A quartz crystal resonator unit that includes: a quartz crystal resonator including an excitation electrode and a connection electrode electrically connected to the excitation electrode; a base member including an electrode pad; an electrically conductive holding member that connects the connection electrode and the electrode pad to each other; and a lid member attached to the base member so as to form an internal space between the lid member and the base member in which the quartz crystal resonator is accommodated. The electrically conductive holding member is a cured product of an electrically conductive adhesive containing (1) a silicone resin as a main component and (2) an epoxy compound having two or more epoxy groups.

[Task] To provide a cationically curable composition that cures in both the exposed area and the unexposed area in a mold with a complex geometry and is suitable for application as an optical element or adhesive. [Solution] Providing a cationically curable composition comprising a fluorene skeleton-containing epoxy compound (A) containing naphthalenediyl groups which may have a substituent, a mono- or bifunctional alicyclic epoxy compound (B), a photoacid generator (C) and an acid multiplying agent (D) and curing even in the unexposed area in a mold having a complex geometry.

The application relates to the technical field of catalysts, and discloses a limited type iodine-based homogeneous immobilized catalyst as well as a preparation method and application thereof. The catalyst comprises a carrier and iodine ions, magnesium ions and quaternary ammonium ions loaded on the carrier, wherein the molar ratio of the magnesium ions, the quaternary ammonium ions, the iodine ions and the carrier is 0.01-1:4-15:1-30:1. The limited type iodine-based homogeneous immobilized catalyst disclosed by the application enhances the electrostatic interaction between iodine ions and quaternary ammonium ions through the molecular sieve limiting effect to construct a limited type structure. The catalyst has significantly enhanced CO2 adsorption and activation capacity, can activate an epoxide compound, and accelerates the ring opening of the epoxide compound. In a cycloaddition reaction catalyzed by the catalyst under the conditions of no solvent and no auxiliary agent, the conversion rate of propylene oxide can reach more than 73%, and the propylene carbonate selectivity can reach more than 85%.

The invention discloses a supercapacitor with a high specific surface area and a preparation method thereof, and relates to the technical field of supercapacitors. Comprising the following steps: performing layer-by-layer cladding forming on TC4 alloy powder to obtain a three-dimensional bionic curved surface structure with Gyandroid topology in a three-period minimal curved surface, and forming a randomly distributed microcosmic columnar bulge structure on the surface of the three-dimensional bionic curved surface structure as a metal current collector; polyaniline is continuously deposited to form a film along the three-dimensional bionic curved surface structure and the surface microcosmic columnar protrusion structure of the three-dimensional bionic curved surface structure in a pulse electrodeposition mode, and a TC4-coated PANI electrode is obtained; the preparation method comprises the following steps: preparing a three-dimensional bionic curved surface structure, performing grafting reaction on polyvinyl alcohol and an epoxy compound containing a quaternary ammonium group under an alkaline condition to prepare a PVA-g-TMAC polymer, preparing a PVA-g-TMAC hydrogel electrolyte, injecting the PVA-g-TMAC hydrogel electrolyte into a mold, arranging two TC4-coated PANI electrodes in the mold according to a preset interval, clamping the three-dimensional bionic curved surface structure, and performing freeze thawing and consolidation to obtain the supercapacitor with a sandwich structure.

The invention relates to the bonding of one or more strands of Glass-Resin composite, abbreviated to "CVR", characterized in that it comprises the following steps: a) a step of pre-adhesion of one or more strands of CVR composite is carried out by dipping the strand(s) in a first aqueous bath comprising a composition based on: - an epoxy compound; and - a blocked diisocyanate compound; b) a step of deposition on the strand(s) of CVR composite is carried out by dipping the strand(s) of CVR composite in a second bath comprising an aqueous adhesive composition based on: - at least one compound A1, the compound A1 comprising at least one aldehyde function, - at least one phenol A21;- at least one unsaturated elastomer latex comprising at least one elastomer chosen from the group consisting of butadiene copolymers, styrene-butadiene copolymers, vinylpyridine-styrene-butadiene terpolymers, natural rubber with the exception of chlorinated natural rubber, and mixtures of these elastomers;The content of blocked diisocyanate compound in the aqueous adhesive composition of the second bath is at a mass rate strictly less than 0.50%.;

The present invention uses a two-pack adhesive composition which is constituted from: a first agent containing at least one non-aromatic epoxy compound selected from among an aliphatic epoxy compound having a hydroxyl group and two or more epoxy groups and a cyclohexene oxide-based epoxy compound, an aromatic epoxy compound, rubber particles and an ionic liquid; and a second agent containing at least one curing agent selected from among an amine-based curing agent having two or more amino groups in the molecule, an acid anhydride-based curing agent, a phenol-based curing agent, a mercaptan-based curing agent and a polysulfide-based curing agent, and in which the ratio of the non-aromatic epoxy compound and the aromatic epoxy compound falls within a certain range.