Material for three-dimensional forming, three-dimensional object, and slice layer of three-dimensional object
A technology of three-dimensional objects and three-dimensional molding, which is applied in the direction of additive processing, etc., can solve the problems of mechanical properties of three-dimensional objects such as low tensile strength, and achieve the effects of improving the safety of preparation, improving the binding force, and improving the mechanical strength
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Embodiment 1
[0119] Weigh 116.12g of hydroxyethyl acrylate, 0.25g of p-hydroxyanisole, 0.25g of antioxidant 168, and 100g of succinic anhydride in a reaction flask, start stirring, gradually raise the temperature to 120°C and keep it warm. After 2 hours of heat preservation, the measured acid value was lower than 260 mgKOH / g, and the temperature was lowered to discharge to obtain the carboxyl group-containing acrylate monomer D-11.
Embodiment 2
[0121] Weigh 88.11g of ethylene glycol monovinyl ether, 0.24g of p-hydroxyanisole, 0.24g of antioxidant 1010, and 148.11g of phthalic anhydride (phthalic anhydride) in a reaction bottle, start stirring, and gradually raise the temperature to 118°C And keep warm. After 2 hours of heat preservation, the measured acid value was lower than 237mgKOH / g, and the temperature was lowered to discharge to obtain carboxyl group-containing vinyl ether monomer D-21.
Embodiment 3
[0123] Weigh 102.13 ethylene glycol monoallyl ether, 0.30 g p-hydroxyanisole, 0.26 g antioxidant 1010, 0.7 g p-toluenesulfonic acid, and 154.17 g hexahydrophthalic anhydride in a reaction flask, start stirring, and gradually heat up to 118°C and keep warm. After 2 hours of heat preservation, the measured acid value was lower than 218 mgKOH / g, and the temperature was lowered to discharge to obtain carboxyl group-containing allyl ether monomer D-31.
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