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Development and application of anti-skid technology for multifunctional polymer-based clean surfaces

A polymer-based, high-molecule technology, applied in the field of preparation of ground substrates, can solve the problems of easy accumulation of dust particles, large-scale deployment and use restrictions, affecting ground cleaning and indoor environmental safety, etc., to achieve excellent anti-skid effect, The effect of outstanding cost advantages

Active Publication Date: 2021-09-28
南京凯奕泽新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the high price and short service life of these products (≤2 months), large-scale deployment and use have great limitations
[0004] On the other hand, the etching type anti-slip technology causes damage to the ground substrate, and its rough surface is prone to accumulate dust particles and other pollutants, which seriously affects the cleanliness of the ground and the safety of the indoor environment.
According to relevant commodity inspection data, conventional etching anti-skid fluids on the market are currently only suitable for application scenarios with low environmental requirements such as industrial plants, and the problems caused by it, such as the increase of volatile organic compounds, are far from the normal residential and large public places. Environmental application requirements
[0005] In summary, the present invention needs to build a high-performance green anti-skid technology, and at the same time add corresponding components to make the surface of the anti-skid treated tiles have a self-cleaning function, fundamentally solve the problem of limited performance and high pollution of the existing anti-skid technology. question

Method used

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  • Development and application of anti-skid technology for multifunctional polymer-based clean surfaces
  • Development and application of anti-skid technology for multifunctional polymer-based clean surfaces
  • Development and application of anti-skid technology for multifunctional polymer-based clean surfaces

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Experimental program
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Effect test

Embodiment 1

[0030] The polymer-based anti-slip film was constructed on the surface of ceramic tiles by pretreatment process and in-situ polymerization segmented method ( figure 1 ): In the first step, the prepared pretreatment solution is evenly dispersed on the surface of the ceramic tile base by atomization and spraying, and the dosage is about 30-50mL / m2; then, the tile floor coated with the pretreatment solution is left to stand for 30 minutes, During the period, the pH value was used as a standard parameter to monitor the pretreatment process. The initial pH of fish tail is 2.5, when the pH rises to 3.5, the pre-treatment cleaning process ends. Rinse the ground with a large amount of pure water; use a Zeta potential instrument for characterization, and the surface of the tile is positively charged with high density, indicating that this method successfully removes the organic matter on the surface of the tile, and makes the surface have a strong interaction with the negatively charge...

Embodiment 2

[0035] Hydrogenated titanium dioxide in turn makes the non-slip film rich in surface charge. In this case, weakly polar liquids such as vegetable oil and liquid paraffin drop to its surface or are repelled and bounced, forming a strong oil-repellent property. On the contrary, strong polar liquids such as water and ethanol will be quickly adsorbed and spread on the surface, forming super-hydrophilic properties. This will give the non-slip film a remarkable self-cleaning effect. Before the anti-slip film treatment, the surface of the glass substrate is stained with dust, and the surface is washed with water solution, and the surface is dusty and watery, which is relatively dirty; but after the anti-slip film treatment, the stained dust is washed with aqueous solution, and it is very clean.

Embodiment 3

[0037] The hydrogenated titanium dioxide component makes the anti-slip film have a certain indoor environmental protection function. Titanium dioxide is a very common photocatalytic material. Many researches have shown that it can effectively degrade formaldehyde in the air through ultraviolet light irradiation; however, ultraviolet light source has significant biological toxicity, and it is not realistic to use it for a long time in the living environment. Through hydrogen plasma treatment, our team prepared a series of hydrogenated titanium dioxide with visible light absorption performance. This material can degrade formaldehyde under visible light irradiation. It is used as an added component of anti-slip film. The experimental results of the atmospheric simulation box show that 1 square meter of processed tiles can be exposed to simulated sunlight for 10 hours, and 2 cubic meters of indoor polluted air with a formaldehyde content of 0.5 mg / m3 can be degraded to meet the nat...

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Abstract

The invention relates to the technical fields of ground anti-slip and indoor environmental protection, and specifically discloses the development and application of multifunctional polymer-based cleaning surface anti-slip technology. A method for preparing ceramic tiles containing a polymer-based anti-slip film, wherein the polymer-based anti-slip liquid configuration: 15-30 parts of prepolymerized polymer, 5-10 parts of emulsifier, 0.1-1 part of photoinitiator, and 5-10 parts of hydrogenated titanium dioxide , 1‑5 parts of sodium carbonate and 50 to 100 parts of deionized water, the parts all refer to mass ratios. The anti-slip liquid is coated on the ceramic tile substrate, and under the irradiation of ultraviolet light, the pre-polymerized polymer is cross-linked and condensed to form a bionic porous film on the ceramic tile. Thus forming an excellent anti-slip effect. In addition, the hydrogenated titanium dioxide component makes the anti-slip film have rich surface charges, forming a super-hydrophilic self-cleaning effect; under visible light irradiation, the surface of the film can also effectively remove formaldehyde components in the indoor air.

Description

technical field [0001] The invention relates to the technical fields of floor anti-skid and indoor environmental protection, and specifically discloses a preparation method of a novel hydrogenated titanium dioxide / porous polymer composite film on a ground substrate and its application in three aspects of anti-skid, self-cleaning and indoor formaldehyde removal. Background technique [0002] Floor substrates such as ceramic tiles and tempered glass will become slippery when exposed to water, causing fractures, sprains and other hospitalizations accounted for 35% of all accidental injuries. Anti-skid floors have become a new public safety issue. Traditional safety anti-slip products such as anti-slip mats / anti-slip bricks have high cost and poor performance under water / oil wetting. Therefore, the development of efficient and general surface anti-slip treatment technology has extremely high application prospects and market demand. [0003] At present, the most common anti-slip...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D201/00C09D5/16C09D7/61C11D10/04B01J21/06B01D53/86B01D53/72B05D3/06B05D5/00B05D7/24
CPCC09D201/00C09D5/1687C11D10/04B01J21/063B01D53/8668B05D5/00B05D7/24B05D3/067C08K2003/262C08K2003/2241B05D2203/30B01J35/39C08K3/22C08K3/26
Inventor 严勇韩凯王鹏鹏
Owner 南京凯奕泽新材料有限公司