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Double-phase ceramic anti-attrition copper alloy and preparation method thereof

A technology of copper alloy and ceramics, which is applied in the field of dual-phase ceramic antifriction copper alloy and its preparation, can solve the problems of limited contribution of copper wear resistance, achieve low price, reduce laser energy consumption, and improve wear resistance

Active Publication Date: 2021-03-09
HUAIYIN INSTITUTE OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, at present, copper alloys are mostly reinforced with a single in-situ ceramic phase, which has a limited contribution to improving the wear resistance of copper.

Method used

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  • Double-phase ceramic anti-attrition copper alloy and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) After weighing aluminum powder and copper oxide powder with a molar ratio of 2:3, put them into a vacuum ball mill tank, and mix them by high-energy ball milling process. / CuO powder;

[0027] (2) Add silicon powder with a mass fraction of 3wt% to the Al / CuO powder in the above step (1), and continue ball milling and mixing to obtain a uniformly mixed composite material powder;

[0028] (3) Under the composite protective atmosphere of argon and nitrogen with a flow rate ratio of 99:1, the composite material powder in the above step (2) is scanned and sintered by using a high-energy laser beam with a power of 150W to obtain an in-situ dispersion on the copper alloy matrix. Anti-friction Al 2 o 3 Ceramic and lubricated Si 3 N 4 ceramic phase.

[0029] figure 1 It is the microstructure topography figure of the in-situ dual-phase ceramic anti-friction copper alloy formed in Example 1, and it can be found that the in-situ Al 2 o 3 with Si 3 N 4 The interface be...

Embodiment 2

[0031] (1) After weighing aluminum powder and copper oxide powder with a molar ratio of 2:3, put them into a vacuum ball mill tank, and mix them by high-energy ball milling process. The ball milling speed is 200rpm, and the ball milling time is 6h to obtain uniformly mixed / CuO powder;

[0032] (2) Add silicon powder with a mass fraction of 5wt% to the Al / CuO powder in the above step (1), and continue ball milling and mixing to obtain a uniformly mixed composite material powder;

[0033] (3) Under the composite protective atmosphere of argon and nitrogen with a flow ratio of 95:5, the composite material powder in the above step (2) is scanned and sintered by using a high-energy laser beam with a power of 250W, and the in-situ dispersion on the copper alloy matrix is ​​obtained. Anti-friction Al 2 o 3 Ceramic and lubricated Si 3 N 4 ceramic phase.

Embodiment 3

[0035] (1) After weighing the aluminum powder and the copper oxide powder with a molar ratio of 2:3, put them into a vacuum ball milling tank, and mix them using a high-energy ball milling process. The ball milling speed is 250rpm, and the ball milling time is 8h. / CuO powder;

[0036] (2) Add silicon powder with a mass fraction of 8wt% to the Al / CuO powder in the above step (1), and continue ball milling and mixing to obtain a uniformly mixed composite material powder;

[0037] (3) Under the composite protective atmosphere of argon and nitrogen with a flow ratio of 90:10, the composite material powder in the above step (2) is scanned and sintered by using a high-energy laser beam with a power of 350W, and the in-situ dispersion on the copper alloy matrix is ​​obtained. Anti-friction Al 2 o 3 Ceramic and lubricated Si 3 N 4 ceramic phase.

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Abstract

The invention discloses a double-phase ceramic anti-attrition copper alloy and a preparation method thereof. The anti-attrition copper alloy comprises a copper alloy matrix, and an Al2O3 ceramic phaseand an Si3N4 ceramic phase are distributed on the copper alloy matrix. According to the method, aluminum powder, silicon powder and copper oxide powder serve as raw materials, by means of a high-energy laser beam heat source, in the nitrogen and argon composite protective atmosphere, the in-situ anti-attrition Al2O3 ceramic phase is formed through an aluminothermic reaction between aluminum and copper oxide, and meanwhile, the lubricating Si3N4 ceramic phase is formed through the action of silicon and nitrogen. The in-situ anti-attrition ceramic phase formed by the method is strong in interface bonding with the matrix, an abrasion rate of the copper alloy in the service process can be effectively reduced, and the service life of the copper alloy is further prolonged.

Description

technical field [0001] The invention relates to a copper alloy and a preparation method thereof, in particular to a dual-phase ceramic friction-reducing copper alloy and a preparation method thereof. Background technique [0002] With the continuous development of the modern transportation industry, the performance requirements for vehicle component materials have also increased accordingly. Friction materials are important materials for manufacturing clutches, and their mechanical properties and wear resistance are crucial to the safe and smooth operation of vehicles. Copper is widely used as one of the important materials for manufacturing vehicle clutches because of its excellent electrical and thermal conductivity and good formability. Copper has good thermal conductivity, the temperature of the friction surface rises slowly, and it is not easy to adhere to the counterpart material, which prolongs the service life of the friction pair, and has better corrosion resistanc...

Claims

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Application Information

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IPC IPC(8): C22C9/00C22C32/00B22F3/105C22C1/05
CPCC22C1/05C22C9/00C22C32/0005
Inventor 李年莲林岳宾刘爱辉王华玲丁红燕
Owner HUAIYIN INSTITUTE OF TECHNOLOGY