Electrolyte and lithium ion battery using same

An electrolyte and lithium salt technology, applied in batteries, secondary batteries, organic electrolytes, etc., can solve problems such as deteriorating battery rate performance and low temperature performance, failing to improve battery high temperature performance, and affecting high temperature cycle and storage performance.

Active Publication Date: 2021-03-09
远景动力技术(湖北)有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The inventors found in the research that an interface reaction occurs between the positive electrode material and the electrolyte. Under high temperature and high pressure, the side reaction at the interface between the positive electrode and the electrolyte is intensified, which seriously affects the high temperature cycle and storage performance.
[0003] In the prior art, nitrile electrolyte additives are often used or combined with other additives to improve the high temperature performance of lithium cobalt oxide positive electrode lithium ion batteries. An invention patent application with the authorized announcement number

Method used

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  • Electrolyte and lithium ion battery using same
  • Electrolyte and lithium ion battery using same
  • Electrolyte and lithium ion battery using same

Examples

Experimental program
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Effect test

Embodiment 1

[0037] Under an inert gas (nitrogen) atmosphere with moisture lower than 5ppm, ethylene carbonate (EC) and ethyl methyl carbonate (EMC) were mixed in a mass ratio of 3:7 to prepare 1000 mL of a non-aqueous solvent, and the compound of formula I and lithium hexafluorophosphate were added to the aforementioned Mix well in the non-aqueous solvent to dissolve the added lithium salt completely. Then add vinylene carbonate (VC) and 1,3-propane sultone (PS) and mix well to obtain the electrolyte. In the obtained electrolyte, the mass percentage of the compound of formula I in the electrolyte is 1.75%, the mass percentage of lithium hexafluorophosphate is 11.25%; the mass percentage of vinylene carbonate (VC) is 1%, 1 , The mass percent content of 3-propane sultone (PS) in the electrolyte solution is 1%, and the balance is non-aqueous solvent.

[0038] Above-mentioned formula I compound is

[0039] Li-ion battery preparation

[0040] Preparation of the positive plate

[0041] Mi...

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Abstract

The invention discloses an electrolyte and a lithium ion battery using the same. The invention provides an electrolyte, which comprises a compound represented by a formula I in the description, an additive, a lithium salt and a non-aqueous solvent. The electrolyte disclosed by the invention is beneficial to reducing the interface impedance of the lithium ion battery, particularly a ternary lithiumion battery in the cycle process and reducing gas production, so that the high-temperature cycle life of the lithium ion battery is prolonged, the high-temperature storage capacity retention and recovery rate is increased, the low-temperature discharge retention rate is increased, and the volume expansion during high-temperature storage is reduced.

Description

technical field [0001] Embodiments of the present invention relate to an electrolyte solution and a lithium ion battery using the same. Background technique [0002] Lithium-ion batteries have the advantages of high voltage, high capacity, and long life, and are ideal energy sources for electric vehicles. Lithium-ion batteries mainly include: positive electrode, negative electrode, electrolyte and separator. The electrolyte is filled between the positive and negative plates and is the carrier of ion transmission in the battery. The inventors found in the research that an interface reaction occurs between the positive electrode material and the electrolyte. Under high temperature and high pressure, the side reaction at the interface between the positive electrode and the electrolyte is intensified, which seriously affects the high temperature cycle and storage performance. [0003] In the prior art, nitrile electrolyte additives are often used or combined with other additiv...

Claims

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Application Information

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IPC IPC(8): H01M10/0567H01M10/0525
CPCH01M10/0567H01M10/0525H01M2300/0025H01M2220/20Y02E60/10
Inventor 汪仕华余乐王仁和李轶
Owner 远景动力技术(湖北)有限公司
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