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Preparation method of composite piezoelectric material based on PVDF-TrFE

A technology of piezoelectric materials and piezoelectric ceramics is applied in the preparation of composite piezoelectric materials and the preparation of new piezoelectric composite materials, which can solve the problem of acoustic impedance ultrasonic loss, low piezoelectric strain constant and electromechanical coupling coefficient, and low acoustic impedance and other problems, to achieve the effect of improving performance and wide application prospects

Active Publication Date: 2021-03-26
ZHEJIANG LAB
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] Although traditional piezoelectric ceramics have the advantages of excellent piezoelectric performance, low cost, and mature preparation technology, they also have disadvantages such as brittleness and high acoustic impedance. The acoustic impedance of traditional piezoelectric ceramics is 30 Mrayl, and the acoustic impedance of human tissue is It is about 1.5 Mrayl. The mismatch of acoustic impedance will cause a large loss of ultrasonic waves during transmission, thus limiting the application prospects of piezoelectric ceramics. Piezoelectric polymers have high flexibility, low acoustic impedance, and are easy to large Area preparation, but its piezoelectric strain constant and electromechanical coupling coefficient are low, and it cannot meet the requirements of the transducer alone. Therefore, a single piezoelectric material will be subject to many restrictions in the use of transducers;

Method used

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  • Preparation method of composite piezoelectric material based on PVDF-TrFE
  • Preparation method of composite piezoelectric material based on PVDF-TrFE
  • Preparation method of composite piezoelectric material based on PVDF-TrFE

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Embodiment 1

[0026] For details, see figure 1 , an embodiment of the present invention provides a schematic diagram of a method for preparing a type 1-3 piezoelectric composite material.

[0027] A method for preparing a composite piezoelectric material is provided in this embodiment, comprising the following steps:

[0028] 1). Weigh an appropriate amount of polymer PVDF-TrFE powder, the powder quality can be determined according to the demand and the size of the mold.

[0029] 2).Will figure 1 The 9-hole mold liner is put into a tableting mold with a suitable diameter, and the diameter can be 10 in one embodiment, and then the weighed polymer powder is poured into the hot-pressing mold.

[0030] 3). Put the mold poured into the polymer powder into the hot-pressing device, and carry out hot-pressing preparation under appropriate temperature, pressure and holding time. In one embodiment, the hot pressing preparation conditions may be 120-250° C., 1-10 MPa, and heating for 30-120 minutes...

Embodiment 2

[0037] For details, see figure 2 , another embodiment of the present invention provides a schematic diagram of a method for preparing a type 1-3 piezoelectric composite material.

[0038] In another embodiment, a method for preparing a composite piezoelectric material is provided, comprising the following steps:

[0039] 1). Weigh an appropriate amount of polymer PVDF-TrFE powder, the powder quality can be determined according to the demand and the size of the mold.

[0040] 2).Will figure 2 The 9-hole die liner of the 1000 is placed into a tableting die of an appropriate diameter, which may be 10 in one embodiment. Then pour the weighed polymer powder into the hot pressing mold.

[0041] 3). Put the mold poured into the polymer powder into the hot-pressing device, and carry out hot-pressing preparation under appropriate temperature, pressure and holding time. In one embodiment, the hot pressing preparation conditions may be 120-250° C., 1-10 MPa, and heating for 30-120 ...

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Abstract

The invention relates to a preparation method of a composite piezoelectric material based on PVDF-TrFE. The preparation method comprises the following steps: weighing a polymer PVDF-TrFE powder; putting a mold liner into a tabletting mold, and pouring the weighed polymer PVDF-TrFE powder into a hot pressing mold; putting the prepared mold into a hot-pressing device, carrying out hot-pressing preparation, and then demolding to obtain a PVDF-TrFE matrix; carrying out hot-pressing shaping on the prepared composite piezoelectric material under a certain condition; cutting the prepared composite piezoelectric material by using a cutting machine, and carrying out hot-pressing shaping under the condition that a thickness is 0.5-2 mm; and using abrasive paper to carry out polishing, exposing a piezoelectric single crystal phase, and finally preparing a 1-3-type composite piezoelectric thin plate with certain flexibility. The performance of the PVDF-TrFE piezoelectric composite material is effectively improved, and therefore the composite material has wider application prospects in the aspects of transducers, energy collection and the like.

Description

technical field [0001] The invention relates to the field of functional materials, in particular to a method for preparing a novel piezoelectric composite material, in particular to a method for preparing a composite piezoelectric material based on PVDF-TrFE. Background technique [0002] Although traditional piezoelectric ceramics have the advantages of excellent piezoelectric performance, low cost, and mature preparation technology, they also have disadvantages such as brittleness and high acoustic impedance. The acoustic impedance of traditional piezoelectric ceramics is 30 Mrayl, and the acoustic impedance of human tissue is It is about 1.5 Mrayl. The mismatch of acoustic impedance will cause a large loss of ultrasonic waves during transmission, thus limiting the application prospects of piezoelectric ceramics. Piezoelectric polymers have high flexibility, low acoustic impedance, and are easy to large Area preparation, but its piezoelectric strain constant and electromec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L41/37H01L41/193H01L41/187H01L41/18B29C43/58B29C43/02H10N30/092H10N30/85H10N30/853H10N30/857
CPCB29C43/02B29C43/58B29C2043/5816B29C2043/5808H10N30/852H10N30/853H10N30/857H10N30/092
Inventor 任丹阳施钧辉尹永刚陈睿黾
Owner ZHEJIANG LAB
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